Women entrepreneurs in Bucharest, Romania, increased by six times (compared to five times for men) between the 1992 and 2002 censuses, during a period of transition from a centrally planned to a market economy. A study of over 150 territory referential units shows a concentration of business women in central, high income areas and a correlation between the entrepreneurial status and education. Data from 50 telephone interviews show that women with university degrees are more likely to operate at a city-wide or national scale, in fields such as cosmeticology, consultancy, law, design, art, and manufacturing. Women without higher education tend to operate at a local, smaller scale. Both spatial concentration and education have an impact upon business behaviour.