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  • Polycyclic aromatic hydroca...
    Lakhmanov, Dmitry E.; Kozhevnikov, Aleksandr Yu; Pokryshkin, Sergey A.; Semiletov, Igor P.; Kosyakov, Dmitry S.

    Marine pollution bulletin, 07/2022, Letnik: 180
    Journal Article

    Polycyclic Aromatic Hydrocarbons (PAHs) are among the main persistent organic pollutants in the Arcticwhich enter the polar region from lower latitudes by air transport and ocean currents and accumulate in marine sediments. This work represents the first study in 25 years of the least studied and hard-to-reach areas of Siberian arctic seas. Sixteen priority PAHs as well as 1- and 2-methylnaphthalenes were analyzed by gas chromatography – tandem mass spectrometry in the twenty-four sediment samples taken from Kara, Laptev and East Siberian Seas in October 2020. The obtained sum concentrations ranged from 31 to 223 ng/ g with the greatest contribution of phenanthrene, benzobfluoranthene, benzokfluoranthene, as well as naphthalene and its methyl derivatives while the greatest PAH levels were observed in Laptev Sea. No correlations between sum PAH concentration, total organic carbon and black carbon contents were found. The toxic equivalent in benzoapyrene units was from 2.2–18.2 ng/ g that shows the general safe environmental situation in the region. The overall PAH level is comparable with the data obtained in 1990s which indicates a long-term persistence of pollution despite an overall decline in global PAH emissions. The main sources of PAHs involve mainly coal/biomass and liquid fuel combustion with weaker contribution of petroleum sources. Display omitted •Priority PAHs and methylnaphthalenes from Kara, Laptev and East Siberian Seas in 2020.•No correlation between PAHs and total organic carbon•The origin of PAHs in arctic marine sediments