In previous multi-dimensional modeling on spray dynamics and vapor formation, single component fuel with pure substrance has been analyzed to assess the mixture formation process. Then it shold be expected that the evaporation process could be performed for the multi-component fuel such as actual Gasoline and Diesel gas oil. In this study, vapor liquid equilibrium prediction was conducted for multi component fuels such as 3 and 10 components mixed solution with ideal solution analysis and non ideal solution analysis. And the computation of distillation characteristics was conducted for the steady state fuel conditions to understand the evaporation process. As a result, calculated distillation characteristics is consistent well with experiment results. Further the vapor concentration was measured for the analysis of the binary fuel spray using IR absorption measurement method.