Flexible risers are critical equipment for the production of oil and gas in offshore fields around the world. The annulus region may condense acidic water containing H2S exposing the tensile armour steel wires to a sour environment, which may promote sulphide stress cracking (SSC) and/or hydrogen-induced cracking (HIC). This work aims to evaluate through electrochemical and constant displacement tests the effectiveness of thermal spray aluminium (TSA) coating to mitigate SSC and HIC in high strength steel used to manufacture the tensile armour of a flexible riser. Electrochemical tests confirmed the anodic behaviour of the coating against the steel and estimated a service life of 2.5 years. The constant displacement test indicated that the non-coated samples failed by SSC although some cracks were also found in the samples mid-section due to HIC. For Al-coated samples, no signs of SSC and HIC were observed. The TSA coating showed a dual barrier effect, hindering either corrosion of steel or hydrogen up-taking, and neither SSC nor HIC was observed. Samples with a coating defect were cathodically protected and no HIC was observed. •Non-coated steel failured by sulphide stress cracking (SSC) and showed cracks associated to hydrogen-induced cracking (HIC);•Thermal spray aluminium (TSA) coating suppressed SSC due the barrier effect and the cathodic protection;•TSA limited the hydrogen diffusion which hindered the HIC.