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Ahn, Jeong-Ae; Chang, Duck-Ho; Park, Young Jun; Yon, Ye Rim; Loupy, André; Jun, Chul-Ho
Advanced synthesis & catalysis, 01/2006, Letnik: 348, Številka: 1-2Journal Article
A highly efficient CC bond cleavage of unstrained aliphatic ketones bearing β‐hydrogens with olefins was achieved using a chelation‐assisted catalytic system consisting of (Ph3P)3RhCl and 2‐amino‐3‐picoline by microwave irradiation under solvent‐free conditions. The addition of cyclohexylamine catalyst accelerated the reaction rate dramatically under microwave irradiation compared with the classical heating method.
