Display omitted •Photocatalysts are reviewed from the perspective of historical development.•Development of photocatalysts is divided into four historical stages.•The main progress and direction of each historical stage are summarized.•The future development direction of photocatalysis technology is proposed.•The development of photocatalysis provides references for other technical fields. Photocatalysis, as a low-cost and environment friendly technology, has demonstrated a significant potential for water pollution purification; it has received extensive attention in recent decades. The key is the photocatalyst; a large number of photocatalysts have been developed. To better understand and further develop the photocatalysis technology for water treatment, this review summarizes its development over time. The development period is divided into four stages (1960s-1993, 1994-2000, 2001-2010, and 2011-present) to provide readers with a better understanding of the development characteristics, and causes and consequences of each historical stage. This review expounds the origin and development of photocatalysis and the obstacles encountered and overcome. It describes the development of mechanisms and methods to solve these problems in each time period. Moreover, it reviews the recent development of new photocatalysts, the concept of designing photocatalysts, and photocatalytic-coupling systems. Finally, it enumerates the problems that continue to exist in the application of photocatalysis technology, and highlights the key issues that must be addressed in future research. The review is aimed at providing the researchers with a deeper understanding of photocatalysis technology and encourage further development of the application of photocatalysis to water treatment.