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Yeung, Chi-Tung; Yim, King-Him; Wong, Ho-Yin; Pal, Robert; Lo, Wai-Sum; Yan, Siu-Cheong; Yee-Man Wong, Melody; Yufit, Dmitry; Smiles, Danil E.; McCormick, Laura J.; Teat, Simon J.; Shuh, David K.; Wong, Wing-Tak; Law, Ga-Lai
Nature communications, 10/2017, Letnik: 8, Številka: 1Journal Article
Abstract Predictable stereoselective formation of supramolecular assembly is generally believed to be an important but complicated process. Here, we show that point chirality of a ligand decisively influences its supramolecular assembly behavior. We designed three closely related chiral ligands with different point chiralities, and observe their self-assembly into europium (Eu) tetrametallic tetrahedral cages. One ligand exhibits a highly diastereoselective assembly into homochiral (either ΔΔΔΔ or ΛΛΛΛ) Eu tetrahedral cages whereas the two other ligands, with two different approaches of loosened point chirality, lead to a significant breakdown of the diastereoselectivity to generate a mixture of (ΔΔΔΔ and ΛΛΛΛ) isomers. The cages are highly emissive (luminescence quantum yields of 16(1) to 18(1)%) and exhibit impressive circularly polarized luminescence properties (| g lum |: up to 0.16). With in-depth studies, we present an example that correlates the nonlinear enhancement of the chiroptical response to the nonlinearity dependence on point chirality.
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