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vomStein, Thorsten; denHartog, Tim; Buendia, Julien; Stoychev, Spas; Mottweiler, Jakob; Bolm, Carsten; Klankermayer, Jurgen; Leitner, Walter
Angewandte Chemie (International ed.), 05/2015, Letnik: 54, Številka: 20Journal Article
Ruthenium-triphos complexes exhibited unprecedented catalytic activity and selectivity in the redox-neutral CC bond cleavage of the beta-O-4 lignin linkage of 1,3-dilignol model compounds. A mechanistic pathway involving a dehydrogenation-initiated retro-aldol reaction for the CC bond cleavage was proposed in line with experimental data and DFT calculations.
