The stress-strain state of ZrB2-SiC ultra-high-temperature ceramics, produced using commercial powders with different impurity levels, was investigated by X-ray diffraction. Upon analysis of ZrB2 and SiC diffraction lines shift, the level of thermal stresses (strains) of the different phases was determined. An increase of internal stresses in ceramics with rising viscous-brittle transition temperatures, Tve, was attributed to increased grain boundary strength. Ceramics, for which high Tve and high level of internal stresses were estimated, exhibited high strength, up to 700 MPa at 1400 °C. A field of compressive thermal stresses in the matrix phase resulted to be necessary for achieving high strength at low-temperatures. On the contrary, the presence of low-melting impurities at the grain boundaries negatively impacted on the stress level in ZrB2 boundaries in the high temperature regime.