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Cheah, Mun Hon; Chernev, Petko
Scientific reports, 11/2021, Letnik: 11, Številka: 1Journal Article
We report the electrochemical oxidation of ferricyanide, Fe (CN) and characterised the oxidation product by in-situ FTIR and XAS spectroelectrochemistry methods. Oxidation of Fe (CN) is proposed to proceed via a tentative Fe(IV) intermediate that undergoes reduction elimination to give cis-Fe (CN) (CH CN) as stable product in acetonitrile. Speciation of the oxidation product by DFT calculations is underpinned by good agreement to experimental data.
