The composition of cometary ices Bockelée-Morvan, D.; Biver, N.
Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences,
07/2017, Volume:
375, Issue:
2097
Journal Article
Peer reviewed
Open access
The chemical composition of cometary ices provides clues for the conditions of formation and evolution of the early Solar System. A large number of molecules have been identified in cometary ...atmospheres, from both ground-based observations and space, including in situ investigations. This includes large organic molecules, which are also observed in star-forming regions. This paper presents a review of molecular abundances measured in cometary atmospheres from remote sensing observations with ground-based and space-based telescopes. The diversity of composition observed in comet populations is presented and discussed.
This article is part of the themed issue ‘Cometary science after Rosetta’.
We present a multi-wavelength study of comet C/2016 R2 (PanSTARRS). This comet was observed on 23 and 24 January 2018 with the IRAM 30 m telescope, and in January to March 2018 with the Nançay radio ...telescope. Visible spectroscopy was performed in December 2017 and February 2018 with small amateur telescopes. We report on measurements of CO, CH3OH, H2CO and HCN production rates, and on the determination of the N2/CO abundance ratio. Several other species, especially OH, were searched for but not detected. The inferred relative abundances, including upper limits for sulfur species, are compared to those measured in other comets at about the same heliocentric distance of ~2.8 AU. The coma composition of comet C/2016 R2 is very different from all other comets observed so far, being rich in N2 and CO and dust poor. This suggests that this comet might belong to a very rare group of comets formed beyond the N2 ice line. Alternatively, comet C/2016 R2 (PanSTARRS) could be the fragment of a large and differentiated transneptunian object, with properties characteristic of volatile-enriched layers.
We present the analysis of ≈100 molecular maps of the coma of comet 67P/Churyumov-Gerasimenko that were obtained with the MIRO submillimeter radiotelescope on board the Rosetta spacecraft. From the ...spectral line mapping of H 216 $_2^{16}$ 216 O, H 218 $_2^{18}$218 O, H 217 $_2^{17}$217 O, CH3OH, NH3, and CO and some fixed nadir pointings, we retrieved the outgassing pattern and total production rates for these species. The analysis covers the period from July 2014, inbound to perihelion, to June 2016, outbound, and heliocentric distances rh = 1.24–3.65 AU. A steep evolution of the outgassing rates with heliocentric distance is observed, typically in rh−16 $r_{\textrm{h}}^{-6}$rh−6 , with significant differences between molecules (e.g. steeper variation for H2O post-perihelion than for methanol). As a consequence, the abundances relative to water in the coma vary. The CH3OH and CO abundances increase after perihelion, while the NH3 abundance peaks around perihelion and then decreases. Outgassing patterns have been modeled as 2D Gaussian jets. The width of these jets is maximum around the equinoxes when the bulk of the outgassing is located near the equator. From July 2014 to February 2015, the outgassing is mostly restricted to a narrower jet (full width at half-maximum ≈80°) originating from high northern latitudes, while around perihelion, most of the gaseous production comes from the southernmost regions ( − 80 ± 5° cometocentric latitude) and forms a 100°–130° (full width at half-maximum) wide fan. We find a peak production of water of 0.8 × 1028 molec. s−1, 2.5 times lower than measured by the ROSINA experiment, and place an upper limit to a 50% additional production that could come from the sublimation of icy grains. We estimate the total loss of ices during this perihelion passage to be 4.18 ± 0.18 × 109 kg. We derive a dust-to-gas ratio in the lost material of 0.7–2.3 (including all sources of errors) based on the nucleus mass loss of 10.5 ± 3.4 × 109 kg estimated by the RSI experiment. We also obtain an estimate of the H 218 $_2^{18}$218 O/H 217 $_2^{17}$217 O ratio of 5.6 ± 0.8.
Most of the gaseous molecules that are detected in cometary atmospheres are produced through sublimation of nucleus ices. Distributed sources may also occur, that is, production within the coma, from ...the solid component of dust particles that are ejected from the nucleus. Glycine, the simplest amino acid, was observed episodically in the atmosphere of comet 67P/Churyumov-Gerasimenko (67P) by the ROSINA mass spectrometer on board the Rosetta probe. A series of measurements on 28 March 2015 revealed a distributed density profile at between 14 and 26 km away from the nucleus. We here present and discuss three study cases: (i) glycine emitted directly and only from the nucleus, (ii) glycine emitted from the sublimation of solid-state glycine on the dust particles that are ejected from the nucleus, and (iii) glycine molecules embedded in water ice that are emitted from the sublimation of this ice from the dust particles that are ejected from the nucleus. A numerical model was developed to calculate the abundance of glycine in the atmosphere of comet 67P as a function of the distance from the nucleus, and to derive its initial abundance in the lifted dust particles. We show that a good fit to the observations corresponds to a distributed source of glycine that is embedded in sublimating water ice from dust particles that are ejected from the nucleus (iii). The few hundred ppb of glycine embedded in water ice on dust particles (nominally 170 ppb by mass) agree well with the observed distribution.
Gas-phase molecules in cometary atmospheres (comae) originate primarily from (1) outgassing by the nucleus, (2) sublimation of icy grains in the near-nucleus coma, and (3) coma (photo)chemical ...processes. However, the majority of cometary gases observed at radio wavelengths have yet to be mapped, so their production/release mechanisms remain uncertain. Here we present observations of six molecular species toward comet 46P/Wirtanen, obtained using the Atacama Large Millimeter/submillimeter Array during the comet's unusually close (∼0.1 au) approach to Earth in 2018 December. Interferometric maps of HCN, CH3OH, CH3CN, H2CO, CS, and HNC were obtained at an unprecedented sky-projected spatial resolution of up to 25 km, enabling the nucleus and coma sources of these molecules to be accurately quantified. The HCN, CH3OH, and CH3CN spatial distributions are consistent with production by direct outgassing from (or very close to) the nucleus, with a significant proportion of the observed CH3OH originating from sublimation of icy grains in the near-nucleus coma (at a scale length Lp = 36 ± 7 km). On the other hand, H2CO, CS, and HNC originate primarily from distributed coma sources (with Lp values in the range 550–16,000 km), the identities of which remain to be established. The HCN, CH3OH, and HNC abundances in 46P are consistent with the average values previously observed in comets, whereas the H2CO, CH3CN, and CS abundances are relatively low.
Context. The recently announced Oort-cloud comet C/2014 UN271 (Bernardinelli-Bernstein) is remarkable in at least three respects: (i) it was discovered inbound as far as ∼29 au from the Sun (with ...prediscovery images up to ∼34 au); (ii) it already showed cometary activity at almost 24 au; and (iii) its nuclear magnitude (Hr ∼ 8.0) indicates an exceptionally large object. Detection of gases is expected in the upcoming years as the comet heads toward a perihelion of ∼11 au in 2031.Aims. The goal is to determine the object’s diameter and albedo from thermal measurements.Methods. We used ALMA in extended configuration (resolution ∼0.064″) to measure the 1287 μm (233 GHz) continuum flux of the comet. Observations were performed on August 8, 2021, at a 20.0 au distance from the Sun. The high spatial resolution was chosen in order to filter out any dust contribution. We also used a recently published Afρ value to estimate the dust production rate and the expected dust thermal signal for various assumptions on particle size distribution.Results. We detected the thermal emission of the object at ∼10σ, with a flux of 0.128 ± 0.012 mJy. Based on observational constraints and our theoretical estimates of the dust contribution, the entirety of the measured flux can be attributed to the nucleus. From NEATM modeling combined with the Hr magnitude, we determine a surface-equivalent diameter of 137 ± 17 km and a red geometric albedo of 5.3 ± 1.2%. This confirms that C/2014 UN271 is by far the largest Oort-cloud object ever found (almost twice as large as comet C/1995 O1 Hale-Bopp) and, except for the Centaur 95P/Chiron, which shows outburst-like activity, the largest known comet in the Solar System. On the other hand, the C/2014 UN271 albedo is typical of comets, adding credence to a “universal” comet nucleus albedo.Conclusions. With its distant perihelion and uniquely large size, C/2014 UN271 (Bernardinelli-Bernstein) is the prominent archetype of distant comets whose activity is driven by hypervolatiles. Monitoring of dust and gas emission as the comet approaches and passes perihelion will permit its activity time pattern to be studied and compared to the distant (outbound) activity of Hale-Bopp. Post-perihelion thermal measurements will permit the study of possible albedo changes, such as a surface brightening compared to pre-perihelion, as was observed for Hale-Bopp.
Aims. Using spectroscopic and continuum data measured by the MIRO instrument on board Rosetta of comet 67P/Churyumov-Gerasimenko, it is possible to derive and track the change in the water production ...rate, to learn how the outgassing evolves with heliocentric distance. The MIRO data are well suited to investigate the evolution of 67P, in unprecedented spatial and temporal detail. Methods. To obtain estimates of the local effective Haser production rates we developed an efficient and reliable retrieval approach with precalculated lookup tables. We employed line area ratios (H216O/H218O) from pure nadir observations as the key variable, along with the Doppler shift velocity, and continuum temperature. This method was applied to the MIRO data from August 2014 until April 2016. Perihelion occurred on August 13, 2015 when the comet was 1.24 AU from the Sun. Results. During the perihelion approach, the water production rates increased by an order of magnitude, and from the observations, the derived maximum for a single observation on August 29, 2015 is (1.42 ± 0.51) ×1028. Modeling the data indicates that there is an offset in the peak outgassing, occurring 34 ± 10 days after perihelion. During the pre-perihelion phase, the production rate changes with heliocentric distance as rh−3.8±0.2; during post-perihelion, the dependence is rh−4.3±0.2. The comet is calculated to have lost 0.12 ± 0.06 % of its mass during the perihelion passage, considering only water ice sublimation. Additionally, this method provides well sampled data to determine the spatial distribution of outgassing versus heliocentric distance. The time evolution is definitely not uniform across the surface. Pre- and post-perihelion, the surface temperature on the southern hemisphere changes rapidly, as does the sublimation rate with an exponent of ~−6. There is a strong latitudinal dependence on the rh exponent with significant variation between northern and southern hemispheres, and so the average over the comet surface may only be of limited importance. We present more detailed regional variation in the outgassing, demonstrating that the highest derived production rates originate from the Wosret, Neith and Bes regions during perihelion.
A spectral survey in the 1 mm wavelength range was undertaken in the long-period comets C/2012 F6 (Lemmon) and C/2013 R1 (Lovejoy) using the 30 m telescope of the Institut de radioastronomie ...millimétrique (IRAM) in April and November−December 2013. We report the detection of ethylene glycol (CH2OH)2 (aGg’ conformer) and formamide (NH2CHO) in the two comets. The abundances relative to water of ethylene glycol and formamide are 0.2–0.3% and 0.02% in the two comets, similar to the values measured in comet C/1995 O1 (Hale-Bopp). We also report the detection of HCOOH and CH3CHO in comet C/2013 R1 (Lovejoy), and a search for other complex species (methyl formate, glycolaldehyde).
Aims. We present the spatial and diurnal variation of water outgassing on comet 67P/Churyumov-Gerasimenko using the H216O rotational transition line at 556.936 GHz observed from Rosetta/MIRO in ...August 2014. Methods. The water line was analyzed with a non-LTE radiative transfer model and an optimal estimation method to retrieve the H216O outgassing intensity, expansion velocity, and gas kinetic temperature. On August 7−9, 2014 and August 18−19, 2014, MIRO performed long steady nadir-pointing observations of the nucleus while it was rotating around its spin axis. The ground track of the MIRO beam during the observation was mostly on the northern hemisphere of comet 67P, covering its three distinct parts: the so-called head, body, and neck areas. Results. The MIRO spectral observation data show that the water-outgassing intensity varies by a factor of 30, from 0.1 × 1025 molecules s-1 sr-1 to 3.0 × 1025 molecules s-1 sr-1, the terminal gas expansion velocity varies by 0.17 km s-1 from 0.61 km s-1 to 0.78 km s-1, and the terminal gas temperature varies by 27 K from 47 K to 74 K. The retrieved coma parameters are co-registered with local environment variables such as the subsurface temperatures, measured in the MIRO continuum bands, the local solar time, illumination condition, and beam location on nucleus. The spatial variation of the outgassing activity is very noticeable, and the largest outgassing activity in August 2014 occurs near the neck region of the nucleus. The outgassing activity in the neck region is also found to be correlated with the local solar hour, which is related to the local illumination condition.
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