Oxidative deterioration of vegetable oils is of great importance in the food industry. In China, vegetable oils produced via thermal pretreatment are popular owing to their strong oil flavor and ...enhanced yield. Here, we review: (i) the currently employed thermal treatment methods of oilseeds before oil extraction; (ii) effects of thermal treatments on the physicochemical properties, contents of minor lipid components, and oxidative stability of vegetable oils; and (iii) Maillard model systems that are related to oil and oilseed chemistry. Among the thermal pretreatment technologies, microwave and infrared radiations are promising, but these are not performed on the same large production scales as roasting. For most oilseeds, thermal treatments increase the yield of extracted oil and content of minor lipid compounds in the oil, such as polyphenols, tocopherols, and phytosterols. In addition, some Maillard reaction products (MRPs) generated by heating oilseeds have been extracted. The presence of both minor lipids and MRPs in the oil confers improved oxidative stability. However, the mechanism or relationship between thermal treatment and oxidative stability is yet to be clearly elucidated because vegetable oil oxidation is dependent on variables such as unsaturation, concentration and types of minor lipid components, MRPs, and the potential synergistic effects of these components. Recently, several Maillard reaction models related to thermally treated oilseeds have been established, suggesting that MRPs play a critical role during oxidation. However, comprehensive identification of antioxidants and the mechanism by which they inhibit oxidation are lacking. Future research can be performed to establish models that would help elucidate the antioxidative mechanisms of MRPs for more oilseeds. Using these models, it will be possible to predict the oil quality after processing, based on the presence of MRPs and oil chemistry.
Conservation biology emerged as a crisis discipline in the twentieth century amongst an increasing awareness of pollution and habitat loss. Since the early 2000s, societal and monetary benefits of ...nature were added to the narrative for biodiversity conservation. Using text mining, we show that authors now favour ecosystem-services over a crisis framing in scientific publications on coastal habitats. This may signal a shift in conservation science from a crisis to a services discipline despite continuing habitat loss. We discuss whether authors should more critically assess what conservation narrative they deploy and what consequences this may have for conservation action.
The western tropical Pacific gives birth to 23 tropical cyclones annually, bringing torrential rainfall to mountainous islands across Oceania resulting in a global sediment production hotspot, in ...which many rivers have great hyperpycnal potential. By using a temperature (T) and salinity (S) profiler, we observed anomalously warm, low salinity turbid water at 3000–3700 m depths in seas ∼180 km off southwestern Taiwan immediately after Typhoon Morakot in 2009. This 250m‐thick bottom‐hugging water occupies ∼2400 km2, and contains 0.15% freshwater, suggesting a remarkably high fraction (6–10%) of event rainfall from southwestern Taiwan. These characteristics indicate the turbid water originated from shallow coastal waters via hyperpycnal flow. Apparently, sediment produced from the land during tropical cyclones open an “express gate” to convey heat and freshwater vertically to the deep ocean basin subsequently warming the deep water from the bottom up.
We report new limits on cosmic neutrino fluxes from the test flight of the Antarctic Impulsive Transient Antenna (ANITA) experiment, which completed an 18.4 day flight of a prototype long-duration ...balloon payload, called ANITA-lite, in early 2004. We search for impulsive events that could be associated with ultrahigh energy neutrino interactions in the ice and derive limits that constrain several models for ultrahigh energy neutrino fluxes and rule out the long-standing -burst model.
The process e^{+}e^{-}→D_{s}^{*+}D_{s}^{*-} is studied with a semi-inclusive method using data samples at center-of-mass energies from threshold to 4.95 GeV collected with the BESIII detector ...operating at the Beijing Electron Positron Collider. The Born cross sections of the process are measured for the first time with high precision in this energy region. Two resonance structures are observed in the energy-dependent cross sections around 4.2 and 4.4 GeV. By fitting the cross sections with a coherent sum of three Breit-Wigner amplitudes and one phase-space amplitude, the two significant structures are assigned masses of (4186.8±8.7±30) and (4414.6±3.4±6.1) MeV/c^{2}, widths of (55±15±53) and (122.5±7.5±8.1) MeV, where the first errors are statistical and the second ones are systematic. The inclusion of a third Breit-Wigner amplitude is necessary to describe a structure around 4.79 GeV.
Systemic lupus erythematosus (SLE) is a complex disease trait of unknown aetiology. Genome-wide linkage studies in human SLE identified several linkage regions, including one at 1q23, which contains ...multiple susceptibility genes, including the members of the signalling lymphocyte activation molecule (SLAM) locus. In mice there is a syntenic linkage region, Sle1. The SLAM genes are functionally related cell-surface receptors, which regulate signal transduction of cells in the immune system. Family-based association study in UK and Canadian SLE families identified variants in the promoter and coding region of SLAMF7 and LY9 contributing to SLE disease susceptibility. The strongest association was from rs509749, in exon 8 of LY9 (P=0.00209). rs509749 encodes a Val/Met nonsynonymous change in amino acid 602 in the cytoplasmic domain of LY9. In the parents and affected individuals from the Canadian SLE families, the risk allele of rs509049 skews the T-cell population by increasing the number of CD8+ memory T cells, while decreasing the proportion of CD4+ naïve T cells and activated T cells. Since rs509749 lies within the consensus binding site for SAP/SH2D1a, which influences downstream signalling events from LY9, the mechanism for increased CD8+ memory T cells may include differential binding SAP/SH2D1a to the cytoplasmic domain of LY9.
Coastal wetlands, such as saltmarshes, are globally widespread and highly effective at capturing and storing ‘blue carbon’ and have the potential to regulate climate over varying timescales. Yet only ...Australia and the United States of America have national inventories of organic carbon held within saltmarsh habitats, hindering the development of policies and management strategies to protect and preserve these organic carbon stores. Here we couple a new observational dataset with 4,797 samples from 26 saltmarshes across Great Britain to spatially model organic carbon stored in the soil and the above and belowground biomass of Great British saltmarshes. Using average values derived from the 26 marshes, we deliver first-order estimates of organic carbon stocks across Great Britain’s 448 saltmarshes (451.66 km
2
). The saltmarshes of Great Britain contain 5.20 ± 0.65 Mt of organic carbon, 93% of which is in the soil. On average, the saltmarshes store 11.55 ± 1.56 kg C m
-2
with values ranging between 2.24 kg C m
-2
and 40.51 kg C m
-2
depending on interlinked factors such as geomorphology, organic carbon source, sediment type (mud vs sand), sediment supply, and relative sea level history. These findings affirm that saltmarshes represent the largest intertidal blue carbon store in Great Britain, yet remain an unaccounted for component of the United Kingdom’s natural carbon stores.
The Sudbury Neutrino Observatory (SNO) used an array of 3He proportional counters to measure the rate of neutral-current interactions in heavy water and precisely determined the total active (nu_x) ...8B solar neutrino flux. This technique is independent of previous methods employed by SNO. The total flux is found to be 5.54_-0.31;+0.33(stat)-0.34+0.36(syst)x10(6) cm(-2) s(-1), in agreement with previous measurements and standard solar models. A global analysis of solar and reactor neutrino results yields Deltam2=7.59_-0.21;+0.19x10(-5) eV2 and theta=34.4_-1.2;+1.3 degrees. The uncertainty on the mixing angle has been reduced from SNO's previous results.
Abstract
The origins of spin lifetimes in quantum systems is a matter of importance in several areas of quantum information. Spectrally mapping spin relaxation processes provides insight into their ...origin and motivates methods to mitigate them. In this paper, we map nuclear relaxation in a prototypical system of
$^{13}{\rm{C}}$$
13
C
nuclei in diamond coupled to Nitrogen Vacancy (NV) centers over a wide field range (1 mT-7 T). Nuclear hyperpolarization through optically pumped NV electrons allows signal measurement savings exceeding million-fold over conventional methods. Through a systematic study with varying substitutional electron (P1 center) and
$^{13}{\rm{C}}$$
13
C
concentrations, we identify the operational relaxation channels for the nuclei at different fields as well as the dominant role played by
$^{13}{\rm{C}}$$
13
C
coupling to the interacting P1 electronic spin bath. These results motivate quantum control techniques for dissipation engineering to boost spin lifetimes in diamond, with applications including engineered quantum memories and hyperpolarized
$^{13}{\rm{C}}$$
13
C
imaging.
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•Oxidation status of LOs are monitor via phenyl-hexyl based LC column.•Number of Trp and Met residue is critical for oxidative stability of Los.•L-AP is effective in suppressing ...oxidation of both Trp- and non-Trp containing LOs.
Linusorbs (LOs, cyclolinopeptides) are a class of naturally occurring cyclic hydrophobic peptides found in flaxseed oil, whose oxidation states indicate the oxidative stability and bitterness of flaxseed oil. Subjected to 63 °C accelerated oxidation, most Met-containing LOs in cold-pressed flaxseed oil entirely depleted by the 6th day except CLP, and MetO2-containing LOs became the dominant ones. However, no MetO2 form of Trp-containing LOs, such as CLD, CLF and CLG, were detected. Given their oxidative kinetics, methionine sulfoxide (MetO) residue in some LOs was less sensitive toward oxidation in the presence of Trp (Tryptophan) group, and the oxidative stability of Met-containing LOs was CLP < CLB < CLL ≈ CLM < CLO, as compared to MetO-containing LOs: CLD < CLE < CLC < CLF ≈ CLG. When antioxidant was added into cold-pressed flaxseed oil to assess the additives’ antioxidant effect, no significant difference was observed on oil oxidative indices in early stage except α-tocopherol, where they vary dramatically in suppressing Met oxidation of LOs: L-AP (L-ascorbyl palmitate) > TBHQ (tert-butyl hydroquinone) > γ-tocopherol > carnosic acid > α-tocopherol. Besides its ability to suppress oxidation of Trp-containing LOs, L-AP also exhibits superior antioxidant effect on non-Trp-containing LOs due to its amphiphilic property. Due to the prooxidative effects of both α- and γ-tocopherol on LOs that contain Trp, it has been suggested that tocopherols may repair Trp residue on LOs, leading to increased tendency of MetO residues to oxidize. The findings of this research are critical for elucidating the antioxidative mechanism of LOs, which can further lead to the establishment of strategies in suppressing bitter after taste to produce high-quality flaxseed oil.
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