Titan's lower atmosphere has long been known to harbor organic aerosols (tholins) presumed to have been formed from simple molecules, such as methane and nitrogen (CH₄ and N₂). Up to now, it has been ...assumed that tholins were formed at altitudes of several hundred kilometers by processes as yet unobserved. Using measurements from a combination of mass/charge and energy/charge spectrometers on the Cassini spacecraft, we have obtained evidence for tholin formation at high altitudes (~1000 kilometers) in Titan's atmosphere. The observed chemical mix strongly implies a series of chemical reactions and physical processes that lead from simple molecules (CH₄ and N₂) to larger, more complex molecules (80 to 350 daltons) to negatively charged massive molecules (~8000 daltons), which we identify as tholins. That the process involves massive negatively charged molecules and aerosols is completely unexpected.
High charge-separation efficiency combined with the reduced fabrication costs associated with solution processing and the potential for implementation on flexible substrates make 'plastic' solar ...cells a compelling option for tomorrow's photovoltaics. Attempts to control the donor/acceptor morphology in bulk heterojunction materials as required for achieving high power-conversion efficiency have, however, met with limited success. By incorporating a few volume per cent of alkanedithiols in the solution used to spin-cast films comprising a low-bandgap polymer and a fullerene derivative, the power-conversion efficiency of photovoltaic cells (air-mass 1.5 global conditions) is increased from 2.8% to 5.5% through altering the bulk heterojunction morphology. This discovery can potentially enable morphological control in bulk heterojunction materials where thermal annealing is either undesirable or ineffective.
We infer the evolution of magnetopause reconnection from simultaneous in situ magnetopause crossings and auroral observations by Cassini on 19 July 2008. Depending on the magnetosheath field, it ...proceeds from (i) the high‐latitude lobe, producing a cusp spot in the aurora, to (ii) lower latitude but north of Cassini, evidenced by an enhancement of the pre‐noon auroral arc and escape of magnetospheric electrons during a long boundary layer traversal, to (iii) bursts of reconnection south of Cassini, resulting in bifurcations of the near‐noon auroral oval, escape of magnetospheric electrons, and a short boundary layer encounter. The conditions under which the auroral bifurcations associated with this bursty reconnection were observed were examined for this and three other examples. The magnetosphere was strongly compressed with a high magnetosheath field strength in every case. We conclude that reconnection can proceed at different locations on the magnetopause, depending on the local magnetic shear and plasma β conditions, and bursty reconnection occurs when the magnetosphere is strongly compressed and can result in significant solar wind‐driven flux transport in Saturn's outer magnetosphere.
Key Points
Bursty reconnection occurs when the magnetosphere is strongly compressed
A dependence on plasma beta and magnetic shear is also evident
Significant solar wind‐driven flows will be present under these conditions
The prevalence of psoriatic arthritis (PsA) is the same in men and women; however, the latter experience a higher burden of disease and are affected more frequently by polyarthritis. Here, we ...performed an early PsA cohort analysis to assess sex-related differences in demographics, disease characteristics, and evolution over 1 year including applied treatment strategies.
Our study is embedded in the Dutch south-west Early Psoriatic Arthritis cohoRt. We described patient characteristics and treatment decisions. For the comparison across sexes and baseline and 1 year follow-up, appropriate tests depending on the distribution were used.
Two hundred seventy-three men and 294 women with no significant differences in age and ethnicity were included. Women reported significantly longer duration of symptoms before diagnosis and significantly higher tender joint count, a higher disease activity, higher levels of pain, and lower functional capacity. Although minimal disease activity (MDA) rates increased over time for both sexes, MDA remained significantly more prevalent among men at 1 year (58.1% vs 35.7%, p < 0.00). Initially, treatment strategies were similar in both sexes with methotrexate being the most frequently used drug during the first year. Women received methotrexate for a shorter period 196 (93-364) vs 306 (157-365), p < 0.00 and therefore received a lower cumulative dose compared to men. Retention time was shorter for all DMARDs, and women had a delayed start on b-DMARDs.
After 1 year of standard-of-care treatment, women did not surpass their baseline disadvantages. Despite the overall improvement, they still presented higher disease activity, higher levels of pain, and lower functional capacity score than men. The nature of these findings may advocate a need for sex specific adjustment of treatment strategies and evaluation in early PsA patients.
Titan's ionosphere contains a rich positive ion population including organic molecules. Here, using CAPS electron spectrometer data from sixteen Titan encounters, we reveal the existence of negative ...ions. These ions, with densities up to ∼100 cm−3, are in mass groups of 10–30, 30–50, 50–80, 80–110, 110–200 and 200+ amu/charge. During one low encounter, negative ions with mass per charge as high as 10,000 amu/q are seen. Due to their unexpectedly high densities at ∼950 km altitude, these negative ions must play a key role in the ion chemistry and they may be important in the formation of organic‐rich aerosols (tholins) eventually falling to the surface.
We explore the paradigm that Saturn's plasmapause marks the boundary between the magnetic flux tubes that have been circulating around the planet for some time, accumulating a dense load of ...Enceladus‐sourced material, and those that have recently undergone tail reconnection, shedding the bulk of the cold plasma and retaining a more tenuous, heated population. A centrifugally driven interchange instability should develop at this boundary, producing fingers of outward propagating dense plasma and of inward propagating hot, tenuous plasma. The plasmapause should thus be identifiable as a transition from mostly‐dense‐with‐some‐tenuous to mostly‐tenuous‐with‐some‐dense plasma populations. Electron densities from the Cassini Plasma Spectrometer/Electron Spectrometer (CAPS/ELS) instrument are used to identify the location of this transition for all of the low‐latitude (<5° from the magnetic equator) passes through Saturn's inner/middle magnetosphere. The boundary is typically found near and somewhat beyond L=10 (i.e., at ~10 Rs from the planet), with a local time asymmetry such that it is closer to the planet on the night side than on the day side.
Plain Language Summary
In Saturn's inner magnetosphere, cold dense plasma originating from the moon Enceladus is transported outward into the outer magnetosphere, where Saturn's rapid rotation causes the magnetic field to become strongly distended and to pinch off in the nightside tail region, releasing cold plasma downtail, and returning hot, tenuous plasma on shortened, more‐dipolar magnetic field lines back toward the inner magnetosphere. The boundary separating the returning tenuous plasma from the dense cold plasma that has not yet pinched off is the plasmapause. An interchange instability forms at this boundary, producing fingers of outward‐propagating dense plasma and of inward‐propagating hot, tenuous plasma. The plasmapause should thus be identifiable as a transition from mostly‐dense‐with‐some‐tenuous to mostly‐tenuous‐with‐some‐dense plasma populations. Electron densities from the Cassini Plasma Spectrometer/Electron Spectrometer (CAPS/ELS) instrument are used to identify the location of this transition for all of the low‐latitude (<5° from the magnetic equator) passes through Saturn's inner/middle magnetosphere. The boundary is typically found near and somewhat beyond ~10 Rs from the planet, and it is closer to the planet on the night side than on the day side.
Key Points
Plasmapause separates flux tubes of dense cold plasma from those that have undergone tail reconnection, leaving a tenuous, heated population
Plasmapause is identified as transition from mostly‐dense‐with‐some‐tenuous to mostly‐tenuous‐with‐some‐dense plasma electron populations
Boundary is typically found near and slightly beyond 10 Rs from the planet and is closer to the planet on the night side than on the dayside
The damaging effect of ionising radiation on cellular structure is one of the prime limiting factors on the survival of life in potential astrobiological habitats. Here we model the propagation of ...solar energetic protons and galactic cosmic ray particles through the Martian atmosphere and three different surface scenarios: dry regolith, water ice, and regolith with layered permafrost. Particle energy spectra and absorbed radiation dose are determined for the surface and at regular depths underground, allowing the calculation of microbial survival times. Bacteria or spores held dormant by freezing conditions cannot metabolise and become inactivated by accumulating radiation damage. We find that at 2 m depth, the reach of the ExoMars drill, a population of radioresistant cells would need to have reanimated within the last 450,000 years to still be viable. Recovery of viable cells cryopreserved within the putative Cerberus pack‐ice requires a drill depth of at least 7.5 m.
The shape and location of a planetary magnetopause can be determined by balancing the solar wind dynamic pressure with the magnetic and thermal pressures found inside the boundary. Previous studies ...have found the kronian magnetosphere to show rigidity (like that of Earth) as well as compressibility (like that of Jupiter) in terms of its dynamics. In this paper we expand on previous work and present a new model of Saturn's magnetopause. Using a Newtonian form of the pressure balance equation, we estimate the solar wind dynamic pressure at each magnetopause crossing by the Cassini spacecraft between Saturn Orbit Insertion in June 2004 and January 2006. We build on previous findings by including an improved estimate for the solar wind thermal pressure and include low‐energy particle pressures from the Cassini plasma spectrometer's electron spectrometer and high‐energy particle pressures from the Cassini magnetospheric imaging instrument. Our improved model has a size‐pressure dependence described by a power law DP−1/5.0 ± 0.8. This exponent is consistent with that derived from numerical magnetohydrodynamic simulations.
Observations with the Venus Express magnetometer and low-energy particle detector revealed magnetic field and plasma behavior in the near-Venus wake that is symptomatic of magnetic reconnection, a ...process that occurs in Earth's magnetotail but is not expected in the magnetotail of a nonmagnetized planet such as Venus. On 15 May 2006, the plasma flow in this region was toward the planet, and the magnetic field component transverse to the flow was reversed. Magnetic reconnection is a plasma process that changes the topology of the magnetic field and results in energy exchange between the magnetic field and the plasma. Thus, the energetics of the Venus magnetotail resembles that of the terrestrial tail, where energy is stored and later released from the magnetic field to the plasma.
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