1. Protected areas are one of the most common strategies for wildlife conservation world-wide. However, their effectiveness is rarely evaluated. In Europe, after the outbreak of bovine spongiform ...encephalopathy, a restrictive sanitary regulation (EC 1774/2002) prohibited the abandonment of dead livestock in extensive farming (extensive livestock) in the field, which led to negative consequences for scavengers. As an attempt to mitigate this negative impact, a new regulation was approved (EC 142/2011) to allow farmers to leave extensive livestock carcasses in the so-called 'Protection areas for the feeding of necrophagous species of European interest' (PAFs). 2. Our general aims were to quantify (i) the proportion of breeding distribution of targeted scavenger species overlapping PAFs; (ii) the extensive livestock carrion biomass available inside PAFs; (iii) the proportion of breeding distribution of non-targeted scavenger species falling within PAFs; (iv) the overlap between the home range of vultures and PAFs, as well as the extent to which vultures move through different administrative units; and (v) the savings in greenhouse gas (GHG) emissions in relation to the pre-PAF scenario. 3. After assessing the status of PAF implementation in every region of peninsular Spain, we analysed the large-scale spatial information of extensive livestock carrion availability and scavenger breeding distribution, movement data of GPS-tracked vultures, and the annual GHG emissions associated with the transport of livestock carcasses. 4. Most regions established PAFs in their territories, although design criteria were variable. The breeding distribution of targeted species was better represented within PAFs than that of non-targeted species. The extensive livestock carrion biomass potentially available for scavengers within PAFs represented 34·9% of the annual extensive livestock biomass generated in peninsular Spain. The overlap between the home range of GPS-marked vulture populations and PAFs ranged between 63·4% and 100%. The minimum convex polygon of these and other GPS-tracked vulture populations in peninsular Spain encompassed 3-14 Spanish regions and 1-4 countries. Post-PAF there was a potential reduction of c. 55-7% of GHG emissions compared to pre-PAF. 5. Synthesis and applications. The implementation of the new sanitary regulation by means of areas for the feeding of scavengers could mean an important improvement in scavenger conservation and a noteworthy reduction in greenhouse gas emissions: in Spain, extensive livestock carrion availability might increase to 33 474 t yr⁻¹, and 43 344 t of CO₂ eq. might be saved annually. However, we identified some gaps related to the distribution of endangered facultative scavengers. Moreover, given that vultures are highly mobile organisms, the design and management of these feeding areas should be coordinated at both the supra-regional and supra-national scales.
We describe herein the state of the art following the last 8 years of research into aromatic polyamides, wholly aromatic polyamides or aramids. These polymers belong to the family of high performance ...materials because of their exceptional thermal and mechanical behavior. Commercially, they have been transformed into fibers mainly for production of advanced composites, paper, and cut and fire protective garments. Huge research efforts have been carried out to take advantage of the mentioned characteristics in advanced fields related to transport applications, optically active materials, electroactive materials, smart materials, or materials with even better mechanical and thermal behavior.
Slope failures pose a substantial threat to mining activity due to their destructive potential and high probability of occurrence on steep slopes close to limit equilibrium conditions, which are ...often found both in open pits and in waste and tailing disposal facilities. The development of slope monitoring and modeling programs usually entails the exploitation of in situ and remote sensing data, together with the application of numerical modeling, and it plays an important role in the definition of prevention and mitigation measures aimed at minimizing the impact of slope failures in mining areas. In this paper, a new methodology is presented; one that combines satellite radar interferometry and 2D finite element modeling for slope stability analysis at a regional scale, and applied within slope unit polygons. Although the literature includes many studies applying radar interferometry and modeling for slope stability analysis, the addition of slope units as input data for radar interferometry and modeling purposes has, to our knowledge, not previously been reported. A former mining area in southeast Spain was studied, and the method proved useful for detecting and characterizing a large number of unstable slopes. Out of the 1959 slope units used for the spatial analysis of the radar interferometry data, 43 were unstable, with varying values of safety factor and landslide size. Out of the 43 active slope units, 21 exhibited line of sight velocities greater than the maximum error obtained through validation analysis (2.5 cm/year). Finally, this work discusses the possibility of using the results of the proposed approach to devise a proxy for landslide hazard. The proposed methodology can help to provide non-expert final users with intelligible, clear, and easily comparable information to analyze slope instabilities in different settings, and not limited to mining areas.
High entropy alloys (HEAs) of the type CrCuFeNiTi-Alx were processed through mechanical alloying. The aluminum concentration was varied in the alloy, to determine its effect on the HEAs' ...microstructure, phase formation, and chemical behavior. X-ray diffraction studies performed on the pressureless sintered samples revealed the presence of structures composed of face centered cubic (FCC) and body centered cubic (BCC) solid-solution phases. Since the valences of the elements that form the alloy are different, a nearly stoichiometric compound was obtained, increasing the final entropy of the alloy. The aluminum was partly responsible for this situation, which also favored transforming part of the FCC phase into BCC phase on the sintered bodies. X-ray diffraction also indicated the formation of different compounds with the alloy's metals. Bulk samples exhibited microstructures with different phases. The presence of these phases and the results of the chemical analyses revealed the formation of alloying elements that, in turn, formed a solid solution and, consequently, had a high entropy. From the corrosion tests, it could be concluded that the samples with a lower aluminum content were the most resistant to corrosion.
The chemical synthesis of nanographene molecules constitutes the bottom-up approach toward graphene, simultaneously providing rational chemical design, structure-property control and exploitation of ...their semiconducting and luminescence properties. Here, we report nanographene-based lasers from three zigzag-edged polycyclic aromatics. The devices consist of a passive polymer film hosting the nanographenes and a top-layer polymeric distributed feedback resonator. Both the active material and the laser resonator are processed from solution, key for the purpose of obtaining low-cost devices with mechanical flexibility. The prepared lasers show narrow linewidth ( < 0.13 nm) emission at different spectral regions covering a large segment of the visible spectrum, and up to the vicinity of the near-infrared. They show outstandingly long operational lifetimes (above 10
pump pulses) and very low thresholds. These results represent a significant step forward in the field of graphene and broaden its versatility in low-cost devices implying light emission, such as lasers.
The impact of human immunodeficiency virus (HIV) coinfection on the survival of patients with hepatitis C virus (HCV)-related end-stage liver disease (ESLD) is unknown. Because HIV infection is no ...longer considered an absolute contraindication for liver transplantation in some countries, it has become a priority to address this topic. The objective of this study was to compare the survival of HIV-infected and HIV-uninfected patients with decompensated cirrhosis due to HCV. In a retrospective cohort study, the survival of 1,037 HCV monoinfected and 180 HCV/HIV-coinfected patients with cirrhosis after the first hepatic decompensation was analyzed. Of the group, 386 (37%) HCV-monoinfected and 100 (56%) HCV/HIV-coinfected subjects died during the follow-up. The median survival time of HIV-infected and HIV-uninfected patients was 16 and 48 months, respectively (P < .001). The relative risk (95% CI) of death for HIV-infected patients was 2.26 (1.51-3.38). Other independent predictors of survival were age older than 63 years (2.25 1.53-3.31); Child-Turcotte-Pugh class B versus class A (1.95 1.41-2.68) and class C versus class A (2.78 1.66-4.70); hepatitis D virus infection (1.56 1.12-4.77); model for end-stage liver disease score, (1.05 1.01-1-11); more than one simultaneous decompensation (1.23 1.12-3.33); and the type of the first hepatic decompensation, with a poorer prognosis associated with encephalopathy compared with portal hypertensive gastrointestinal bleeding (2.03 1.26-3.10). In conclusion, HIV coinfection reduces considerably the survival of patients with HCV-related ESLD independently of other markers of poor prognosis. This fact must be taken into account to establish the adequate timing of liver transplantation in HIV-coinfected subjects.
Abstract Objective The purpose of this meta-analysis was to examine the effect of flywheel (FW) resistance training with Eccentric Overload (FW-EOT) on muscle size and functional capacities (i.e. ...strength and power) in athletes and healthy subjects, and to compare FW-induced adaptations with those triggered by traditional resistance exercise interventions. Design A systematic review and meta-analysis of randomised controlled trials. Methods A search of electronic databases PubMed, MEDLINE (SportDiscus), Web of Science, Scopus and PEDro was conducted to identify all publications employing FW-EOT up to April 30, 2016. Outcomes were analyzed as continuous outcomes using a random effects model to calculate a standardized mean difference (SMD) and 95% CI. A total of 9 studies with 276 subjects and 92 effect sizes met the inclusion criteria and were included in the statistical analyses. Results The overall pooled estimate from the main effects analysis was 0.63 (95% CI 0.49 to 0.76) with a significant ( p < 0.001) Z overall effect of 9.17. No significant heterogeneity ( p value = 0.78) was found. The meta-analysis showed significant differences between FW-EOT vs. conventional resistance training in concentric and eccentric strength, muscle power, muscle hypertrophy, vertical jump height and running speed, favoring FW-EOT. Conclusion This meta-analysis provides evidence supporting the superiority of FW-EOT, compared with traditional weight-stack exercise, to promote skeletal muscle adaptations in terms of strength, power and size in healthy subjects and athletes.
The reaction of mid to late lanthanide ions with the N,N′-dimethyl-N,N′-bis(2-hydroxy-3-formyl-5-bromobenzyl)ethylene-diamine organic ligand and monolacunary Keggin type α-SiW11O398– anion affords ...a series of isostructural compounds, namely, K5LnIII(α-SiW11O39)(C20H22Br2N2O4)·14H2O (1-Ln, Ln = Sm to Lu). The molecular structure of these sandwich-type complexes is formed by the LnIII ion in a biaugmented trigonal prismatic geometry, which occupies the external O4 site of the organic ligand and the vacant site of the lacunary polyoxometalate (POM) unit. The empty N2O2 coordination site of the organic ligand allows its unprecedented folding, which displays a relative perpendicular arrangement of aromatic groups. Weak Br···Br and π–π interactions established between adjacent molecular units govern the crystal packing, which results in the formation of assemblies containing six hybrid species assembled in a chairlike conformation. 1-Gd and 1-Yb display slow relaxation of the magnetization after the application of an external magnetic field with maxima in the out-of-phase magnetic susceptibility plots below ∼5–6 K, which is ascribed to the presence of various relaxation mechanisms. Moreover, photoluminescent emission is sensitized for 1-Sm and 1-Eu in the visible region and 1-Er and 1-Yb in the NIR. In contrast, the quenching of metal-centered luminescence in the 1-Tb derivative has been attributed to the out-of-pocket coordination mode of the lanthanide center within the POM fragment. It is demonstrated that the 1-Yb dual magneto-luminescent material represents the first lanthanide-containing POM reported to date with simultaneous slow magnetic relaxation and NIR emission. Solution stability of the hybrid molecular species in water is also confirmed by ESI-mass spectrometry experiments carried out for 1-Tb and 1-Tm.
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