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•Fabrication of an inkjet-printed paper-based SERS platform.•An effective AuSph Ink was developed with high stability over 1 year of storage.•Improvement of SERS capabilities by a ...hydrophobic modification of the paper.•Ultrasensitive quantification of thiram at 10−11 M with low sample volume (2 μL).•Reliable, robust and ultralow-cost SERS substrates (less than $ 0.01 per spot).
We report the fabrication of a low-cost paper-based SERS platform with enhanced sensing capabilities. The sensor consists of a highly concentrated glycerol/ethanol dispersion of ca. 77 nm Au nanospheres (AuSph) inkjet-printed on hydrophobic chromatographic paper forming circular sensing spots of 1 mm in diameter. The AuSph ink exhibits high stability for 1 year. Interestingly, we demonstrate that the modification of the paper surface with hydrophobic ligands improve the sensing capabilities by confining the analyte solution in the AuSph sensing platform. It contributes to both concentrate the analyte, as well as, to decrease the sample volume to just a few μl. We also analyze the effect of the amount of the nanoparticles, tunable by the number of printing cycles, in the SERS performance of the plasmonic spots. The results show that 5 printing cycles give rise to sensing platforms with great SERS response in terms of intensity and uniformity. The spot-to-spot reproducibility is also analyzed observing good results even for AuSph spots from different printed papers. The paper-based SERS platform was tested towards the detection of crystal violet (CV) and the fungicide thiram. Additionally, applying a digital protocol for SERS analysis, a good linear correlation between the digital counts (or positive events) and the analyte concentration was obtained at the single-molecule SERS regime. In both cases, the quantification region threshold was 10−11 M. The great sensitivity performance of the inkjet-printed SERS substrate is reflected by the low sample volume needed (only 2 μL). The inkjet-printed SERS substrate and the fabrication method demonstrated to be efficient, reliable, reproducible and robust, with a cost less than $ 0.01 per spot.
Context.
The quadruple lensed system WGD2038-4008 (
z
s
= 0.777 ± 0.001) has recently been discovered with the help of new techniques and observations. Black hole masses have been estimated for ...lensed quasars, but they have mostly been calculated for one broad emission line of one image. However, the images could be affected by microlensing, which changes the results.
Aims.
We present black hole mass (
M
BH
) estimations for images A and B of WGD2038-4008 using the three most prominent broad emission lines (H
α
, H
β
, and Mg
II
) obtained in one single-epoch spectra. This is the first time the mass has been estimated in a lensed quasar in two images, allowing us to disentangle the effects of microlensing. The high S/N of our spectra allows us to get reliable results that can be compared with the existing data in the literature.
Methods.
We used the X-shooter instrument mounted on the Very Large Telescope at Paranal Observatory to observe this system, taking advantage of its wide spectral range (UVB, VIS, and NIR). The sky emission correction was performed using principal component analysis as the nodding was small compared to the image separation. We compared the lines profiles to identify the microlensing in the broad-line region and corrected each spectra by the image magification. Using the flux ratio of the continuum to the core of the emission lines, we analyzed whether microlensing was present in the continuum source.
Results.
We obtained
M
BH
using the single-epoch method with the H
α
and H
β
emission lines from the monochromatic luminosity and the velocity width. The luminosity at 3000 Å was obtained using the spectral energy distribution of image A, while the luminosity at 5100 Å was estimated directly from the spectra. The average
M
BH
between the images obtained was log
10
(
M
BH
/
M
⊙
) = 8.27 ± 1.05, 8.25 ± 0.32, and 8.59 ± 0.35 for Mg
II
, H
β
, and H
α
, respectively. We find Eddington ratios similar to those measured in the literature for unlensed low-luminosity quasars. Microlensing of −0.16 ± 0.06 mag in the continuum was found, but the induced error in the
M
BH
is minor compared to that associated with the macromodel magnification. We also obtained the accretion disk size using the
M
BH
for the three emission lines, obtaining an average value of log
10
(
r
s
/cm)=15.3 ± 0.63, which is in agreement with theoretical estimates.
ABSTRACT
In spite of their importance for modern astronomy, we do not fully understand how close binary stars containing at least one white dwarf form from main-sequence binary stars. The discovery ...of EL CVn binaries, close pre-white dwarfs with A/F main-sequence star companions, offers now the unique possibility to test models of close compact binary star formation. Binary evolution theories predict that these EL CVn stars descend from very close main-sequence binaries with orbital periods shorter than 3 d. If this is correct, nearly all EL CVn stars should be inner binaries of hierarchical triples because more than 95 per cent of very close main-sequence binaries (the alleged progenitor systems) are found to be hierarchical triples. We here present SPHERE/IRDIS observations of five EL CVn binaries, finding in all of them tertiary objects, as predicted. We conclude that EL CVn systems are inner binaries of hierarchical triples and indeed descend from very close main-sequence binaries that experience stable mass transfer.
Due to its youth, proximity and richness, the Orion nebula cloud (ONC) is an ideal testbed to obtain a comprehensive view on the initial mass function (IMF) down to the planetary mass regime. Using ...the HAWK-I camera at the VLT, we have obtained an unprecedented deep and wide near-infrared JHK mosaic of the ONC (90 per cent completeness at K ∼ 19.0 mag, 22 × 28 arcmin2). Applying the most recent isochrones and accounting for the contamination of background stars and galaxies, we find that ONC's IMF is bimodal with distinct peaks at about 0.25 and 0.025 M⊙ separated by a pronounced dip at the hydrogen burning limit (0.08 M⊙), with a depth of about a factor of 2–3 below the log-normal distribution. Apart from ∼920 low-mass stars (M < 1.4 M⊙) the IMF contains ∼760 brown dwarf candidates and ∼160 isolated planetary mass object candidates with M > 0.005 M⊙, hence about 10 times more substellar candidates than known before. The substellar IMF peak at 0.025 M⊙ could be caused by brown dwarfs and isolated planetary mass objects which have been ejected from multiple systems during the early star formation process or from circumstellar discs.
Urbanization negatively affects biodiversity worldwide. Consequently, alternative urban development styles are required for an eco-friendlier urbanization process. Thus, two development styles have ...been suggested: land-sharing (buildings mixed with dispersed green space) and land-sparing (buildings interspersed with large green patches). We assessed differences in species diversity and composition of bird assemblages between both development styles in two Argentinian cities: Santa Fe and Buenos Aires. We surveyed birds in land-sharing and land-sparing areas during the breeding and non-breeding seasons. As a control, we also surveyed birds in areas dominated by impervious surfaces. At a local scale, we also measured the environmental noise and pedestrian traffic. At a landscape scale, we measured the percent vegetation cover surrounding development styles and their distance to the main river. In Buenos Aires, species richness was higher in land-sparing than in land-sharing. However, the Shannon diversity and Simpson diversity were higher in land-sharing. In Santa Fe, both urban development styles supported similar species richness and diversity. Species composition varied between land-sharing and land-sparing in both cities during the breeding season. The pedestrian traffic was negatively associated with species diversity. Therefore, both development styles and strategies to reduce pedestrian traffic should be taken into account to enhance different components of species diversity and composition within the urban matrix.
HIP 65426 b is a recently discovered exoplanet imaged during the course of the SPHERE-SHINE survey. Here we present new L′ and M′ observations of the planet from the NACO instrument at the VLT from ...the NACO-ISPY survey, as well as a new Y –H spectrum and K-band photometry from SPHERE-SHINE. Using these data, we confirm the nature of the companion as a warm, dusty planet with a mid-L spectral type. From comparison of its SED with the BT-Settl atmospheric models, we derive a best-fit effective temperature of Teff = 1618 ± 7 K, surface gravity log g = 3.78−0.03+0.04 $\log g\,{=}\,3.78^{+0.04}_{-0.03}$logg = 3.78−0.03+0.04 and radius R = 1.17 ± 0.04RJ (statistical uncertainties only). Using the DUSTY and COND isochrones we estimate a mass of 8 ± 1MJ. Combining the astrometric measurements from our new datasets and from the literature, we show the first indications of orbital motion of the companion (2.6σ significance)and derive preliminary orbital constraints. We find a highly inclined orbit ( i = 1.07−10+13 $i\,{=}\,107^{+13}_{-10}$i = 107−10+13 deg) with an orbital period of 800−400+1200 $800^{+1200}_{-400}$800−400+1200 yr. We also report SPHERE sparse aperture masking observations that investigate the possibility that HIP 65426 b was scattered onto its current orbit by an additional companion at a smaller orbital separation. From this data we rule out the presence of brown dwarf companions with masses greater than 16 MJ at separations larger than 3 AU, significantly narrowing the parameter space for such a companion.
Urbanization is among the main factors of ecosystem transformation and threats to global biodiversity. Urban green spaces provide multiple services, being important for biodiversity and human ...well-being. However, the relationship between green spaces and forest birds has been scarcely studied in the Global South. In this work, we used citizen science data (eBird) to assess the variation in the species richness and composition of forest birds in two types of public urban green spaces characterized by different vegetation composition and management: parks and reserves. In general, reserves had more native and unmanaged vegetation than parks. We selected parks and reserves located in the coastal area of the Metropolitan Area of Buenos Aires, Argentina. Sampling effort was considered as the number of checklists for each site. The database allowed information to be extracted from 12 sites and 33 species. The most common species were the Green-barred Woodpecker (
), the Narrow-billed Woodcreeper (
), and the White-crested Tyrannulet (
). Bird species richness was higher in reserves than in parks and was positively related to sampling effort. The forest bird species composition varied according to the type of green area and sampling effort. Species composition showed a significant nestedness, with the least rich sites being a subset of species from the richest sites. Reserves and sites with the highest sampling effort concentrated all species. The results obtained show the importance of urban reserves in the conservation of forest birds.
Context.
HD 72946 is a bright and nearby solar-type star hosting a low-mass companion at long period (
P
∼ 16 yr) detected with the radial velocity (RV) method. The companion has a minimum mass of ...60.4 ± 2.2
M
J
and might be a brown dwarf. Its expected semi-major axis of ∼243 mas makes it a suitable target for further characterization with high-contrast imaging, in particular to measure its inclination, mass, and spectrum and thus definitely establish its substellar nature.
Aims.
We aim to further characterize the orbit, atmosphere, and physical nature of HD 72946B.
Methods.
We present high-contrast imaging data in the near-infrared with the Spectro-Polarimetric High-contrast Exoplanet REsearch (SPHERE) instrument. We also use proper motion measurements of the star from H
IPPARCOS
and
Gaia
.
Results.
The SPHERE data reveal a point source with a contrast of ∼9 mag at a projected separation of ∼235 mas. No other point sources are detected in the field of view. By jointly fitting the RV, imaging, and proper motion data, we constrain all the orbital parameters of HD 72946B and assess a dynamical mass of 72.4 ± 1.6
M
J
and a semi-major axis of 6.456.45
+0.08
−0.07
au. Empirical comparison of its SPHERE spectrum to template dwarfs indicates a spectral type of L5.0 ± 1.5. The
J
–
H
3 color is close to the expectations of the DUSTY models and suggests a cloudy atmosphere. Comparison with atmospheric models of the spectrophotometry suggests an effective temperature of ∼1700 K. The bolometric luminosity (log(
L
/
L
⊙
) = −4.11 ± 0.10 dex) and dynamical mass of HD 72946B are more compatible with evolutionary models for an age range of ∼0.9−3 Gyr. The formation mechanism of the companion is currently unclear as the object appears slightly away from the bulk of model predictions. HD 72946B is currently the closest benchmark brown dwarf companion to a solar-type star with imaging, RV, and proper motion measurements.
Widespread adoption of MON 87701 × MON 89788 soybean, expressing Cry1Ac Bt protein and glyphosate tolerance, has been observed in Brazil. A proactive program was implemented to phenotypically and ...genotypically monitor Cry1Ac resistance in Chrysodeixis includens (Walker). Recent cases of unexpected injury in MON 87701 × MON 89788 soybean were investigated and a large-scale sampling of larvae on commercial soybean fields was performed to assess the efficacy of this technology and the distribution of lepidopteran pests in Brazil. No significant shift in C. includens susceptibility to Cry1Ac was observed eight years after commercial introduction of this technology in Brazil. F
screen results confirmed that the frequency of Cry1Ac resistance alleles remains low and stable in C. includens. Unexpected injury caused by Rachiplusia nu (Guenée) and Crocidosema aporema (Walsingham) in MON 87701 × MON 89788 soybean was detected during the 2020/21 season, and studies confirmed a genetically based alteration in their susceptibility to Cry1Ac. MON 87701 × MON 89788 soybean remains effective against Anticarsia gemmatalis (Hübner), C. includens, Chloridea virescents (Fabricius) and Helicoverpa armigera (Hübner) in Brazil. However, there is evidence of field-evolved resistance to MON 87701 × MON 89788 soybean by the secondary soybean pests R. nu and C. aporema.
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