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  • Cu/chiral phosphoric acid-c... Cu/chiral phosphoric acid-catalyzed radical-initiated asymmetric aminosilylation of alkene with hydrosilane
    Zeng, Yang; Liu, Xiao-Dong; Guo, Xian-Qi ... Science China. Chemistry, 11/2019, Volume: 62, Issue: 11
    Journal Article
    Peer reviewed

    The catalytic radical-initiated asymmetric 1,2-aminosilylation of alkene with a hydrosilane under Cu(I)/CPA cooperative catalysis has been developed. This method features the use of hydrosilane as ...
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  • A general copper-catalyzed ... A general copper-catalyzed radical C(sp3)−C(sp2) cross-coupling to access 1,1-diarylalkanes under ambient conditions
    Su, Xiao-Long; Jiang, Sheng-Peng; Ye, Liu ... Tetrahedron, 06/2021, Volume: 89
    Journal Article
    Peer reviewed

    A general copper-catalyzed C(sp3)−C(sp2) cross-coupling of (hetero)benzyl bromides with the air- and moisture-stable aryl nucleophiles has been developed, providing a facile access to ...
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  • Copper‐Catalyzed Enantiosel... Copper‐Catalyzed Enantioselective C(sp3)−SCF3 Coupling of Carbon‐Centered Benzyl Radicals with (Me4N)SCF3
    Zhang, Wei; Tian, Yu; Liu, Xiao‐Dong ... Angewandte Chemie, March 11, 2024, Volume: 136, Issue: 11
    Journal Article
    Peer reviewed

    In contrast with the well‐established C(sp2)−SCF3 cross‐coupling to forge the Ar−SCF3 bond, the corresponding enantioselective coupling of readily available alkyl electrophiles to forge chiral ...
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  • Copper-Catalyzed Enantiocon... Copper-Catalyzed Enantioconvergent Radical C(sp3)–N Cross-Coupling to Access Chiral α‑Amino-β-lactams
    Zheng, Jing-Jing; Liu, Wei-Long; Gu, Qiang-Shuai ... Precision Chemistry, 12/2023, Volume: 1, Issue: 10
    Journal Article
    Peer reviewed
    Open access

    A copper-catalyzed enantioconvergent radical C­(sp3)–N cross-coupling of racemic tertiary α-bromo-β-lactams with aromatic amines is developed under mild thermal reaction conditions. The use of a ...
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  • Inside Cover: Achiral Pyrid... Inside Cover: Achiral Pyridine Ligand‐Enabled Enantioselective Radical Oxytrifluoromethylation of Alkenes with Alcohols (Angew. Chem. Int. Ed. 30/2017)
    Cheng, Yong‐Feng; Dong, Xiao‐Yang; Gu, Qiang‐Shuai ... Angewandte Chemie International Edition, July 17, 2017, 2017-07-17, 20170717, Volume: 56, Issue: 30
    Journal Article
    Peer reviewed

    The achiral ligand effect is utilized together with copper/phosphoric acid dual catalysis to achieve the first asymmetric radical oxytrifluoromethylation of alkene molecules with alcohols. In their ...
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  • Copper‐Catalyzed Enantiocon... Copper‐Catalyzed Enantioconvergent Radical C(sp3)−N Cross‐Coupling: Access to α,α‐Disubstituted Amino Acids
    Zhang, Yu‐Feng; Wang, Jia‐Huan; Yang, Ning‐Yuan ... Angewandte Chemie, July 3, 2023, Volume: 135, Issue: 27
    Journal Article
    Peer reviewed

    Transition‐metal catalyzed enantioconvergent cross‐coupling of tertiary alkyl halides with ammonia offers a rapid avenue to chiral unnatural α,α‐disubstituted amino acids. However, the construction ...
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  • Enantioselective Copper(I)/... Enantioselective Copper(I)/Chiral Phosphoric Acid Catalyzed Intramolecular Amination of Allylic and Benzylic C−H Bonds
    Ye, Liu; Tian, Yu; Meng, Xiang ... Angewandte Chemie, January 13, 2020, Volume: 132, Issue: 3
    Journal Article
    Peer reviewed

    Radical‐involved enantioselective oxidative C−H bond functionalization by a hydrogen‐atom transfer (HAT) process has emerged as a promising method for accessing functionally diverse enantioenriched ...
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  • Copper‐Catalyzed Chemo‐ and... Copper‐Catalyzed Chemo‐ and Enantioselective Radical 1,2‐Carbophosphonylation of Styrenes
    Zhou, Huan; Fan, Li‐Wen; Ren, Yang‐Qing ... Angewandte Chemie, March 20, 2023, Volume: 135, Issue: 13
    Journal Article
    Peer reviewed
    Open access

    The copper‐catalyzed enantioselective radical difunctionalization of alkenes from readily available alkyl halides and organophosphorus reagents possessing a P−H bond provides an appealing approach ...
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