Precise control over doping of photocatalysts is required to modulate their photocatalytic activity in visible light‐driven reactions. Here, a single precursor‐employing bottom‐up approach is ...developed to produce different heteroatom‐doped graphene quantum dots (GQDs) with unique photocatalytic activities. The solvothermal reaction of a norepinephrine precursor with redox active and condensable moieties effectively produces both nitrogen/sulfur codoped GQDs (NS‐GQDs) and nitrogen‐doped GQDs (N‐GQDs) by simply varying solvents (from dimethyl sulfoxide to water) under microwave irradiation. As‐prepared NS‐GQDs and N‐GQDs show similar lateral sizes (3–4 nm) and heights (1–2 nm), but they include different dopant types and doping constitution and content, which lead to changes in photocatalytic activity in aerobic oxidative coupling reactions of various amines. NS‐GQDs exhibit much higher photocatalytic activity in reactions under visible light than N‐GQDs and oxygen‐doped GQDs (O‐GQDs). The mechanism responsible for the outstanding photocatalytic activity of NS‐GQDs in visible light‐driven oxidative coupling reactions of amines is also fully investigated.
Modulation of the photocatalytic activity of heteroatom‐doped graphene quantum dots (GQDs) is reported. A single precursor, norepinephrine, is used to effectively produce N,S‐co‐doped GQDs and N‐doped GQDs under microwave irradiation. Tailoring dopant types, constitution, and content imparts much higher photocatalytic activity to N,S‐codoped GQDs than N‐doped GQDs and O‐doped GQDs in the visible‐light‐driven oxidative coupling reaction of various amines.
With the growing use of fossil fuels and industrial activity, the amount of carbon dioxide (CO2) emission is continuously increasing and is considered a primary contributor to climate change. CO2 ...emissions from stationary resources (coal fire, cement plants, and other industry) can be reduced by using various carbon capture and sequestration (CCS) technologies. In this article, recent advancements in various biological methods (i.e., carbonic anhydrase (CA), hydrogenation of CO2 to formate, reduction of CO2 to methane, CO2 conversion into methanol by enzyme cascade, and the role of RuBisCo enzyme) that have been reported for CO2 capture are discussed, along with their advantages and limitations. A brief overview of other physicochemical (absorption, adsorption, cryogenic, and membrane) technologies is also provided. Although biological methods are ecofriendly and can be performed under ambient conditions, these approaches are still not cost effective, as the reactions require cofactors, and the enzymes lose activity when exposed to hot flue gas and ionic liquids. Most captured CO2 is stored by mineralization using a geological and ocean storage method without providing any economic benefit. It is a question of interest as to how we can utilize CO2 and generate revenue. Utilization of CO2 as a feedstock to produce bioenergy is a possible approach. Various microbes capable of utilizing CO2 as feedstock and producing biofuels (biodiesel and bioalcohol) have been reported. These two technologies, i.e., CO2 capture and bioconversion of CO2 into bioenergy, can be integrated to develop a process that not only mitigates CO2 effects on the environment but also solves energy problems while generating revenue.
•Carbon dioxide (CO2) is contributing in global warming.•CO2 can be used as a resource for bioenergy production.•Electro-biological and integrated system are efficient methods for CO2 to bioenergy conversion.
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•Biodiesel is a renewable and ecofriendly biofuel.•It can be produced using transesterification, emulsification and pyrolysis process etc.•Enzyme catalyzed and biomass derived ...catalysts reactions are economic and ecofriendly.•Process intensification technology results in higher yield with lower wastes.
Biodiesel is a non-toxic renewable energy source that is gaining attention globally owing to its direct applicability in preexisting engines without any modification. Various technologies from laboratory scale to industrial scale have been developed, and many plants have been established for biodiesel production using various feedstocks. Using biobased technology in biodiesel production is advantageous as these methods generate less waste and are considered ecofriendly. This article mainly discusses the availability of various oil resources (edible, non-edible, waste cooking oils (WCO)) and the advancements in technology related to oil extraction. Specifically, biobased methods, such as immobilized enzymes (matrix) and heterogeneous catalysts (derived from biomass), reported to catalyze the transesterification reaction for biodiesel production are discussed in detail. Biodiesel production using conventional technologies results in low yield and purity and is time-consuming. Newly introduced process intensification technologies (microreactor, membrane reactor, microwave, reactive distillation, and centrifugal contractor) to overcome these issues are also discussed. The need to develop integrated process technologies for biodiesel production to make the process more economical is emphasized.
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•PHA production from biowaste is an economic and ecofriendly approach.•Microbes are able to recover resource from waste and produce PHA.•C, N, P and dissolved oxygen are the main ...factors that affect PHA production.•The downstream process has a big impact on whole cost of PHA production.•Functionalization of PHA has potential to improve their applications.
Biowaste management is a challenging job as it is high in nutrient content and its disposal in open may cause a serious environmental and health risk. Traditional technologies such as landfill, bio-composting, and incineration are used for biowaste management. To gain revenue from biowaste researchers around the world focusing on the integration of biowaste management with other commercial products such as volatile fatty acids (VFA), biohydrogen, and bioplastic (polyhydroxyalkanoates (PHA)), etc. PHA production from various biowastes such as lignocellulosic biomass, municipal waste, waste cooking oils, biodiesel industry waste, and syngas has been reported successfully. Various nutrient factors i.e., carbon and nitrogen source concentration and availability of dissolved oxygen are crucial factors for PHA production. This review is an attempt to summarize the recent advancements in PHA production from various biowaste, its downstream processing, and other challenges that need to overcome making bioplastic an alternate for synthetic plastic.
The ability to control the dimensions and properties of nanomaterials is fundamental to the creation of new functions and improvement of their performances in the applications of interest. Herein, we ...report a strategy based on glucan multivalent interactions for the simultaneous exfoliation and functionalization of two-dimensional transition metal dichalcogenides (TMDs) in an aqueous solution. The multivalent hydrogen bonding of dextran with bulk TMDs (WS
, WSe
, and MoSe
) in liquid exfoliation effectively produces TMD monolayers with binding multivalency for pathogenic bacteria. Density functional theory simulation reveals that the multivalent hydrogen bonding between dextran and TMD monolayers is very strong and thermodynamically favored (ΔE
= -0.52 eV). The resulting dextran/TMD hybrids (dex-TMDs) exhibit a stronger affinity (K
= 11 nM) to Escherichia coli O157:H7 (E. coli) than E. coli-specific antibodies and aptamers. The dex-TMDs can effectively detect a single copy of E. coli based on their Raman signal.
Acetic acid is an abundant material that can be used as a carbon source by microorganisms. Despite its abundance, its toxicity and low energy content make it hard to utilize as a sole carbon source ...for biochemical production. To increase acetate utilization and isobutanol production with engineered Escherichia coli, the feasibility of utilizing acetate and metabolic engineering was investigated. The expression of acs, pckA, and maeB increased isobutanol production by up to 26%, and the addition of TCA cycle intermediates indicated that the intermediates can enhance isobutanol production. For isobutanol production from acetate, acetate uptake rates and the NADPH pool were not limiting factors compared to glucose as a carbon source. This work represents the first approach to produce isobutanol from acetate with pyruvate flux optimization to extend the applicability of acetate. This technique suggests a strategy for biochemical production utilizing acetate as the sole carbon source.
Metabolic engineering was conducted to replenish pyruvate for isobutanol production using acetate. By using this approach, pathway balancing was achieved to increase isobutanol production from combinatorial expression of maeB, acs, pckA.
Abstract
Despite highly promising characteristics of three-dimensionally (3D) nanostructured catalysts for the oxygen evolution reaction (OER) in polymer electrolyte membrane water electrolyzers ...(PEMWEs), universal design rules for maximizing their performance have not been explored. Here we show that woodpile (WP)-structured Ir, consisting of 3D-printed, highly-ordered Ir nanowire building blocks, improve OER mass activity markedly. The WP structure secures the electrochemically active surface area (ECSA) through enhanced utilization efficiency of the extended surface area of 3D WP catalysts. Moreover, systematic control of the 3D geometry combined with theoretical calculations and various electrochemical analyses reveals that facile transport of evolved O
2
gas bubbles is an important contributor to the improved ECSA-specific activity. The 3D nanostructuring-based improvement of ECSA and ECSA-specific activity enables our well-controlled geometry to afford a 30-fold higher mass activity of the OER catalyst when used in a single-cell PEMWE than conventional nanoparticle-based catalysts.
Arctic psychrotrophic bacterium Pseudomonas sp. PAMC 28620 was found to produce a distinctive medium-chain-length polyhydroxyalkanoate (MCL-PHA) copolymer when grown on structurally unrelated carbon ...sources including glycerol. The maximum MCL-PHA copolymer yield was obtained about 52.18±4.12% from 7.95±0.66g/L of biomass at 144h of fermentation when 3% glycerol was used as sole carbon and energy source during the laboratory-scale bioreactor process. Characterization of the copolymer was carried out using fourier transform infrared spectroscopy (FTIR), gas chromatography–mass spectrometry (GC–MS), proton (1H) and carbon (13C) nuclear magnetic resonance spectroscopy (NMR), gel permeation chromatography (GPC), differential scanning calorimeter (DSC) and thermo-gravimetric analysis (TGA). The copolymer produced by Pseudomonas sp. PAMC 28620 consisting of four PHA monomers and identified as 3-hydroxyoctanoate (3HO), 3-hydroxydecanoate (3HD), 3-hydroxydodecanoate (3HDD) and 3-hydroxytetradecanoate (3HTD). An average molecular weight of the copolymer was found approximately 30.244kDa with polydispersity index (PDI) value of 2.05. Thermal analysis showed the produced MCL-PHA copolymer to be low-crystalline (43.73%) polymer with great thermal stability, having the thermal decomposition temperature of 230°C–280°C, endothermic melting temperature (Tm) of 172.84°C, glass transition (Tg) temperature of 3.99°C, and apparent melting enthalpy fusion (ΔHm) about 63.85Jg−1.
Organic–inorganic hybrid perovskite nanoparticles (NPs) are a very strong candidate emitter that can meet the high luminescence efficiency and high color standard of Rec.2020. However, the ...instability of perovskite NPs is the most critical unsolved problem that limits their practical application. Here, an extremely stable crosslinked perovskite NP (CPN) is reported that maintains high photoluminescence quantum yield for 1.5 years (>600 d) in air and in harsher liquid environments (e.g., in water, acid, or base solutions, and in various polar solvents), and for more than 100 d under 85 °C and 85% relative humidity without additional encapsulation. Unsaturated hydrocarbons in both the acid and base ligands of NPs are chemically crosslinked with a methacrylate‐functionalized matrix, which prevents decomposition of the perovskite crystals. Counterintuitively, water vapor permeating through the crosslinked matrix chemically passivates surface defects in the NPs and reduces nonradiative recombination. Green‐emitting and white‐emitting flexible large‐area displays are demonstrated, which are stable for >400 d in air and in water. The high stability of the CPN in water enables biocompatible cell proliferation which is usually impossible when toxic Pb elements are present. The stable materials design strategies provide a breakthrough toward commercialization of perovskite NPs in displays and bio‐related applications.
An extraordinarily long stability, exceeding 1.5 years, for crosslinked perovskite nanoparticles (NPs) under harsh environments, by a novel materials design strategy, is reported. Surprisingly, the photoluminescence of the perovskite NPs is significantly increased under air, moisture, and chemicals, overcoming their instability in oxygen, water, and polar chemicals.
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