Self‐assembly of colloidal microspheres or nanospheres is an effective strategy for fabrication of ordered nanostructures. By combination of colloidal self‐assembly with nanofabrication techniques, ...two‐dimensional (2D) colloidal crystals have been employed as masks or templates for evaporation, deposition, etching, and imprinting, etc. These methods are defined as “colloidal lithography”, which is now recognized as a facile, inexpensive, and repeatable nanofabrication technique. This paper presents an overview of 2D colloidal crystals and nanostructure arrays fabricated by colloidal lithography. First, different methods for fabricating self‐assembled 2D colloidal crystals and complex 2D colloidal crystal structures are summarized. After that, according to the nanofabrication strategy employed in colloidal lithography, related works are reviewed as colloidal‐crystal‐assisted evaporation, deposition, etching, imprinting, and dewetting, respectively.
This review article presents an overview of two‐dimensional (2D) colloidal crystals and nanostructure arrays fabricated by colloidal lithography. First, methods for fabricating self‐assembled 2D colloidal crystals and complex 2D colloidal crystal structures are presented. Then, according to the nanofabrication strategy employed in colloidal lithography, related works are reviewed as colloidal‐crystal‐assisted evaporation, deposition, etching, imprinting, and dewetting, respectively.
Holey ultrathin g‐C3N4 nanosheets (CNHS) with abundant micro‐, meso‐, and macropores are fabricated by thermal “etching” of bulk g‐C3N4. The prepared CNHS possess a unique ultralight characteristic, ...high specific surface area, more catalytic active sites, and enhanced electron transport ability, leading to a much superior activity in hydrogen generation and photodegradation of pollutant.
Novel polymeric g-C3N4 photocatalysts loaded with noble metal Ag nanoparticles were prepared via a facile heating method. The obtained Ag/g-C3N4 composite products were characterized by X-ray ...diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), UV--vis diffuse reflection spectra (DRS) and photoluminescence spectra (PL). The photocatalytic activities of Ag/g-C3N4 samples were investigated based on the decomposition of methyl orange and hydrogen evolution under visible light irradiation. The XPS results revealed that it was the metallic Ag0 deposited on polymeric g-C3N4 samples. The Ag/g-C3N4 photocatalysts exhibited significantly enhanced photocatalytic performance for the degradation of methyl orange and hydrogen production compared with pure g-C3N4. The optimal Ag content was determined to be 1.0 wt%, and the corresponding hydrogen evolution rate was 10.105 Delta *mmol h-1, which exceeded that of pure g-C3N4 by more than 11.7 times. The enhanced photocatalytic performance could be attributed to the synergic effect between Ag and g-C3N4, which promoted the migration efficiency of photo-generated carriers. The proposed mechanism for the enhanced visible light photocatalytic activity of g-C3N4 modified by a small amount of Ag was further confirmed by photoluminescence spectroscopy.
Ferroptosis plays an important role in traumatic brain injury (TBI). The p53 protein is a major mediator of ferroptosis. However, the role of p53-mediated ferroptosis in TBI has not been studied. ...Sirtuin 2 (SIRT2) exerts a protective effects role in TBI, although the underlying mechanism of this protection remains unclear. In the present study, we tested the hypothesis that that SIRT2 mitigates TBI by regulating p53-mediated ferroptosis.
To model TBI in mice, we used the controlled cortical impact (CCI) injury method. We found that ferroptosis was significantly activated by CCI, and peaked 3 days following CCI, as evidenced by upregulation of GPX4 and SLC7A11, increased content of decreases glutathione, lipid peroxidation, malondialdehyde and ferrous ion. Inhibition of ferroptosis significantly alleviated neurological indications and brain edema. In addition, knockout of p53 significantly blocked ferroptosis following CCI. Furthermore, we found that inhibition of SIRT2 upregulated the acetylation of p53, as well as p53 expression, and exacerbated ferroptosis following CCI. Interestingly, knockout of p53 rescued the SIRT2 inhibition-induced exacerbation of ferroptosis.
These findings indicate that p53-mediated ferroptosis contributes to the pathogenesis of TBI. Furthermore, we demonstrate that SIRT2 exerts a neuroprotective effect against TBI by suppressing p53-mediated ferroptosis.
The bandgap in graphene‐based materials can be tuned from 0 eV to that of benzene by changing size and/or surface chemistry, making it a rising carbon‐based fluorescent material. Here, the surface ...chemistry of small size graphene (graphene quantum dots, GQDs) is tuned programmably through modification or reduction and green luminescent GQDs are changed to blue luminescent GQDs. Several tools are employed to characterize the composition and morphology of resultants. More importantly, using this system, the luminescence mechanism (the competition between both the defect state emission and intrinsic state emission) is explored in detail. Experiments demonstrate that the chemical structure changes during modification or reduction suppresses non‐radiative recombination of localized electron‐hole pairs and/or enhances the integrity of surface π electron network. Therefore the intrinsic state emission plays a leading role, as opposed to defect state emission in GQDs. The results of time‐resolved measurements are consistent with the suggested PL mechanism. Up‐conversion PL of GQDs is successfully applied in near‐IR excitation for bioimaging.
The preparation of controllable fluorescent graphene quantum dots (GQDs) using a new surface chemistry tuning method is reported. The photoluminescence (PL) mechanism is investigated and the competition between both the defect state emission and intrinsic state emission are analyzed in detail. Moreover, the up‐conversion PL of GQDs is successfully used in multiphoton luminescent biolabeling under near‐IR excitation.
A generic small-signal model of modular multilevel converter (MMC) based DC grid is established and a DC virtual impedance damping control to suppress the resonance and instability is proposed. The ...averaged-value model (AVM) of MMC is employed to derive the Thévenin equivalent model of the converter from its DC side using the power-balancing principle considering the dynamics of phase-locked loop (PLL) of the interconnected ac system. The single section π-typed line model is selected to develop the nodal admittance equations of the DC network in s domain. The stability criterion of the DC grid is given after establishing the generic linearization model. The key factors affecting the DC grid's stability are identified using the root locus method and participation factors analysis. The parameters and the performances of the damping controller are designed and studied. Electromagnetic transient simulation model and RT-LAB real-time simulation are used to validate that the proposed damping control can suppress the instability of the DC grid and improve its operating performance.
This study aims to evaluate the accuracy of virtual surgical planning in two-jaw orthognathic surgery via quantitative comparison of preoperative planned and postoperative actual skull models.
Thirty ...consecutive patients who required two-jaw orthognathic surgery were included. A composite skull model was reconstructed by using Digital Imaging and Communications in Medicine (DICOM) data from spiral computed tomography (CT) and STL (stereolithography) data from surface scanning of the dental arch. LeFort I osteotomy of the maxilla and bilateral sagittal split ramus osteotomy (of the mandible were simulated by using Dolphin Imaging 11.7 Premium (Dolphin Imaging and Management Solutions, Chatsworth, CA). Genioplasty was performed, if indicated. The virtual plan was then transferred to the operation room by using three-dimensional (3-D)-printed surgical templates. Linear and angular differences between virtually simulated and postoperative skull models were evaluated.
The virtual surgical planning was successfully transferred to actual surgery with the help of 3-D-printed surgical templates. All patients were satisfied with the postoperative facial profile and occlusion. The overall mean linear difference was 0.81 mm (0.71 mm for the maxilla and 0.91 mm for the mandible); and the overall mean angular difference was 0.95 degrees.
Virtual surgical planning and 3-D-printed surgical templates facilitated the diagnosis, treatment planning, and accurate repositioning of bony segments in two-jaw orthognathic surgery.
This review highlights recent advances in the development of nanocomposite hydrogels from CDs and polymers.
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Nanocomposite hydrogels based on carbon dots (CDs) and polymers have ...emerged as new materials with integrated properties of individual components, leading to their important applications in the field of soft nanomaterials. This perspective highlights recent advances in the development of nanocomposite hydrogels from CDs and polymers. We review the preparation methods of nanocomposite hydrogels based on CDs and polymers, and emerging applications of these nanocomposite hydrogels such as environmental remediation, energy storage, sensing, drug delivery and bioimaging. We conclude with the discussion of new research directions in the development of new type of nanocomposite hydrogels based on CDs and polymers.
Strongly fluorescent graphene quantum dots (GQDs) have been prepared by one-step solvothermal method with PL quantum yield as high as 11.4%. The GQDs have high stability and can be dissolved in most ...polar solvents. Because of fine biocompatibility and low toxicity, GQDs are demonstrated to be excellent bioimaging agents.
