Planet-forming disks are not isolated systems. Their interaction with the surrounding medium affects their mass budget and chemical content. In the context of the ALMA-DOT program, we obtained ...high-resolution maps of assorted lines from six disks that are still partly embedded in their natal envelope. In this work, we examine the SO and SO2 emission that is detected from four sources: DG Tau, HL Tau, IRAS 04302+2247, and T Tau. The comparison with CO, HCO+, and CS maps reveals that the SO and SO2 emission originates at the intersection between extended streamers and the planet-forming disk. Two targets, DG Tau and HL Tau, offer clear cases of inflowing material inducing an accretion shock on the disk material. The measured rotational temperatures and radial velocities are consistent with this view. In contrast to younger Class 0 sources, these shocks are confined to the specific disk region impacted by the streamer. In HL Tau, the known accreting streamer induces a shock in the disk outskirts, and the released SO and SO2 molecules spiral toward the star in a few hundred years. These results suggest that shocks induced by late accreting material may be common in the disks of young star-forming regions with possible consequences for the chemical composition and mass content of the disk. They also highlight the importance of SO and SO2 line observations in probing accretion shocks from a larger sample.
In this study, recycling of spent coffee grounds (SCG) as a potential feedstock for alternative fuel production and compounds of added value in Turkey was assessed. The average oil content was found ...(≈ 13% w/w). All samples (before and after extraction) were tested for scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), X-ray diffraction (XRD), calorific value, surface analysis and porosity, Fourier transform infrared (FT-IR), and elemental analysis to assess their potential towards fuel properties. Elemental analysis indicated that carbon represents the highest percentages (49.59% and 46.42%, respectively), followed by nitrogen (16.7% and 15.5%), hydrogen (6.74% and 6.04%), and sulfur (0.851% and 0.561%). These results indicate that SCG can be utilized as compost, as it is rich in nitrogen. Properties of the extracted oil were examined, followed by biodiesel production. The quality of biodiesel was compared with American Society for Testing and Materials (ASTM) D6751 standards, and all the properties complied with standard specifications. The fatty acid compositions were analyzed by gas chromatography. It was observed that coffee waste methyl ester (CWME) is mainly composed of palmitic (35.8%) and arachidic (44.6%) acids, which are saturated fatty acids. The low degree of unsaturation provides an excellent oxidation stability (10.4 hr). CWME has also excellent cetane number, higher heating value, and iodine value with poor cold flow properties. The studies also investigated blending of biodiesel with Euro diesel and butanol. Following this, a remarkable improvement in cloud and pour points of biodiesel was obtained. Spent coffee grounds after oil extraction is an ideal material for garden fertilizer, feedstock for ethanol, biogas production, and as fuel pellets. The outcome of such research work produces valuable insights on the recycling importance of SCG in Turkey.
Coffee is a huge industry, and coffee has been widely used due to its refreshing properties. This industry generates large quantities of waste. Therefore, recycling of spent coffee grounds for producing alternative fuels and compounds of added value is crucial. Elemental analysis indicated that coffee waste can be utilized as compost, as it is rich in nitrogen. Coffee waste after oil extraction is an ideal feedstock for ethanol and biogas production, garden fertilizer, and as fuel pellets. The low degree of unsaturation provides excellent oxidation stability. Its biodiesel has also excellent cetane number, higher heating value, and lower iodine value.
Context.
Class I protostars are a bridge between Class 0 protostars (≤10
5
yr old), and Class II (≥10
6
yr) protoplanetary disks. Recent studies show gaps and rings in the dust distribution of disks ...younger than 1 Myr, suggesting that planet formation may start already at the Class I stage. To understand what chemistry planets will inherit, it is crucial to characterize the chemistry of Class I sources and to investigate how chemical complexity evolves from Class 0 protostars to protoplanetary disks.
Aims.
There are two goals: (i) to perform a census of the molecular complexity in a sample of four Class I protostars, and (ii) to compare the data with the chemical compositions of earlier and later phases of the Sun-like star formation process.
Methods.
We performed IRAM-30 m observations at 1.3 mm towards four Class I objects (L1489-IRS, B5-IRS1, L1455-IRS1, and L1551-IRS5). The column densities of the detected species were derived assuming local thermodynamic equilibrium (LTE) or large velocity gradients (LVGs).
Results.
We detected 27 species: C-chains, N-bearing species, S-bearing species, Si-bearing species, deuterated molecules, and interstellar complex organic molecules (iCOMs; CH
3
OH, CH
3
CN, CH
3
CHO, and HCOOCH
3
). Among the members of the observed sample, L1551-IRS5 is the most chemically rich source. Different spectral profiles are observed: (i) narrow lines (~1 km s
−1
) towards all the sources, (ii) broader lines (~4 km s
−1
) towards L1551-IRS5, and (iii) line wings due to outflows (in B5-IRS1, L1455-IRS1, and L1551-IRS5). Narrow c-C
3
H
2
emission originates from the envelope with temperatures of 5–25 K and sizes of ~2′′−10′′. The iCOMs in L1551-IRS5 reveal the occurrence of hot corino chemistry, with CH
3
OH and CH
3
CN lines originating from a compact (~0.′′15) and warm (
T
> 50 K) region. Finally, OCS and H
2
S seem to probe the circumbinary disks in the L1455-IRS1 and L1551-IRS5 binary systems. The deuteration in terms of elemental D/H in the molecular envelopes is: ~10−70% (D
2
CO/H
2
CO), ~5−15% (HDCS/H
2
CS), and ~1−23% (CH
2
DOH/CH
3
OH). For the L1551-IRS5 hot corino we derive D/H ~2% (CH
2
DOH/CH
3
OH).
Conclusions.
Carbon chain chemistry in extended envelopes is revealed towards all the sources. In addition, B5-IRS1, L1455-IRS1, and L1551-IRS5 show a low-excitation methanol line that is narrow and centered at systemic velocity, suggesting an origin from an extended structure, plausibly UV-illuminated. The abundance ratios of CH
3
CN, CH
3
CHO, and HCOOCH
3
with respect to CH
3
OH measured towards the L1551-IRS5 hot corino are comparable to that estimated at earlier stages (prestellar cores, Class 0 protostars), and to that found in comets. The deuteration in our sample is also consistent with the values estimated for sources at earlier stages. These findings support the inheritance scenario from prestellar cores to the Class I phase when planets start forming.
Context.
Star-forming molecular clouds are characterised by the ubiquity of intertwined filaments. The filaments have been observed in both high- and low-mass star-forming regions, and they are ...thought to split into collections of sonic fibres. The locations where filaments converge are termed hubs, and these are associated with the young stellar clusters. However, the observations of filamentary structures within hubs at distances of 75–300 pc require a high angular resolution <2″ (~ 150–600 au) that limits the number of such studies conducted so far.
Aims.
The integral shaped filament (ISF) of the Orion A molecular cloud is noted for harbouring several hubs within which no filamentary structures have been observed so far. The goal of our study is to investigate the nature of the filamentary structures within one of these hubs, which is the chemically rich hub OMC-2 FIR 4, and to analyse their emission with high density and shock tracers.
Methods.
We observed the OMC-2 FIR 4 proto-cluster using Band 6 of the Atacama Large (sub-)Millimetre Array (ALMA) in Cycle 4 with an angular resolution of ~0.26″ (100 au). We analysed the spatial distribution of dust, the shock tracer SiO, and dense gas tracers (i.e., CH
3
OH, CS, and H
13
CN). We also studied the gas kinematics using SiO and CH
3
OH maps.
Results.
Our observations for the first time reveal interwoven filamentary structures within OMC-2 FIR 4 that are probed by several tracers. Each filamentary structure is characterised by a distinct velocity as seen from the emission peak of CH
3
OH lines. They also show transonic and supersonic motions. SiO is associated with filaments and also with multiple bow-shock features. The bow-shock features have sizes between ~500 and 2700 au and are likely produced by the outflow from HOPS-370. Their dynamical ages are <800 yr. In addition, for the first time, we reveal a highly collimated SiO jet (~1°) with a projected length of ~5200 au from the embedded protostar VLA 15.
Conclusions.
Our study unveiled the previously unresolved filamentary structures as well as the shocks within OMC-2 FIR 4. The kinematics of the filamentary structures might be altered by external and/or internal mechanisms such as the wind from H II regions, the precessing jet from the protostellar source HOPS-370, or the jet from VLA 15. While the complexity of the region, coupled with the limited number of molecular lines in our dataset, makes any clear association with these mechanisms challenging, our study shows that multi-scale observations of these regions are crucial for understanding the accretion processes and flow of material that shape star formation.
Context.
Hot corinos are compact regions around solar-mass protostellar objects that are very rich in interstellar Complex Organic Molecules (iCOMs). How the abundance of these molecules is affected ...by the environmental physical conditions is still an open question. More specifically, addressing this point is key to understand our own chemical origins since the Solar System formed in a large cluster of low- to high-mass stars and was therefore subject to external heating and ultraviolet irradiation which may have shaped the chemistry of its early formation stages.
Aims.
The goal of this high resolution study is to determine the abundance ratios of iCOMs in HOPS-108, which is a Class 0 protostar and a hot corino candidate located in the nearest Solar System analogue, the protostellar cluster OMC-2 FIR 4, in Orion. We aim to compare the abundance ratios to those found in other hot corinos, which are all located in less crowded environments, in order to understand the impact of environmental conditions on hot corinos’ chemistry.
Methods.
We observed the OMC-2 FIR 4 proto-cluster using the Band 6 of the Atacama Large (sub-)Millimetre Array in Cycle 4 with an angular resolution of ~0.′′28 (110 au). We determined the abundances and temperature of the species using local thermodynamic equilibrium (LTE) and non-LTE analysis.
Results.
Our results reveal a rich organic chemistry towards HOPS-108, asserting that it is a hot corino where the following iCOMs are detected: CH
3
OH, HCOOCH
3
, CH
3
OCH
3
, CH
3
18
OH, CH
2
DOH, CH
3
COCH
3
, CH
3
CHO, CH
3
CN,
13
CH
3
CN, C
2
H
5
CN, and NH
2
CHO. Remarkably, we find a possible enhancement in the HCOOCH
3
abundance with respect to other known hot corinos. Indeed, the CH
3
OCH
3
/HCOOCH
3
abundance ratio in this source is ~0.2 and, within the uncertainties, it deviates from the known correlation marginally where CH
3
OCH
3
/HCOOCH
3
~1. A relatively low CH
2
DOH/CH
3
OH abundance ratio of ~0.02 is also obtained, which is in agreement with that found in another Orion source, HH212, suggesting a higher gas temperature during the early phases of ice mantle formation.
Conclusions.
The CH
3
OCH
3
/HCOOCH
3
and CH
2
DOH/CH
3
OH abundance ratios in HOPS-108 might result from different physical conditions in the Orion molecular complex compared to other regions. The former ratio cannot be reproduced with current chemical models, highlighting the importance of improving the chemical networks with theoretical calculations. More hot corinos located in heavily clustered regions such as Orion should be targeted in order to measure these ratios and evaluate whether they are an environmental product or whether HOPS-108 is an exceptional hot corino overall.
ABSTRACT
The ALMA (Atacama Large Millimeter Array) interferometer, with its unprecedented combination of high sensitivity and high angular resolution, allows for (sub-)mm wavelength mapping of ...protostellar systems at Solar system scales. Astrochemistry has benefitted from imaging interstellar complex organic molecules in these jet–disc systems. Here, we report the first detection of methanol (CH3OH) and methyl formate (HCOOCH3) emission towards the triple protostellar system VLA1623−2417 A1+A2+B, obtained in the context of the ALMA Large Programme FAUST (Fifty AU STudy of the chemistry in the disc/envelope system of solar-like protostars). Compact methanol emission is detected in lines from Eu = 45 K up to 61 K and 537 K towards components A1 and B, respectively. Large velocity gradient analysis of the CH3OH lines towards VLA1623−2417 B indicates a size of 0.11–0.34 arcsec (14–45 au), a column density $N_{\rm CH_3OH}$ = 1016–1017 cm−2, kinetic temperature ≥ 170 K, and volume density ≥ 108 cm−3. A local thermodynamic equilibrium approach is used for VLA1623−2417 A1, given the limited Eu range, and yields Trot ≤ 135 K. The methanol emission around both VLA1623−2417 A1 and B shows velocity gradients along the main axis of each disc. Although the axial geometry of the two discs is similar, the observed velocity gradients are reversed. The CH3OH spectra from B show two broad (4–5 km s−1) peaks, which are red- and blueshifted by ∼ 6–7 km s−1 from the systemic velocity. Assuming a chemically enriched ring within the accretion disc, close to the centrifugal barrier, its radius is calculated to be 33 au. The methanol spectra towards A1 are somewhat narrower (∼ 4 km s−1), implying a radius of 12–24 au.
The study of hot corinos in solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests ...that planet formation starts already during Class I phase, which therefore represents a crucial step in the future planetary system chemical composition. Hence, the study of hot corinos in Class I protostars has become of paramount importance. Here, we report the discovery of a hot corino towards the prototypical Class I protostar L1551 IRS5, obtained within the ALMA (Atacama Large Millimeter/submillimeter Array) Large Program FAUST (Fifty AU STudy of the chemistry in the disc/envelope system of solar-like protostars). We detected several lines from methanol and its isotopologues (13CH3OH and CH2DOH), methyl formate, and ethanol. Lines are bright towards the north component of the IRS5 binary system, and a possible second hot corino may be associated with the south component. The methanol lines' non-LTE analysis constrains the gas temperature (∼100 K), density (≥1.5 × 10^8 per cu.cm), and emitting size (∼10 au in radius). All CH3OH and 13CH3OH lines are optically thick, preventing a reliable measure of the deuteration. The methyl formate and ethanol relative abundances are compatible with those measured in Class 0 hot corinos. Thus, based on this work, little chemical evolution from Class 0 to I hot corinos occurs.
ABSTRACT
More than 50 per cent of solar-mass stars form in multiple systems. It is therefore crucial to investigate how multiplicity affects the star and planet formation processes at the ...protostellar stage. We report continuum and C18O (2–1) observations of the VLA 1623–2417 protostellar system at 50 au angular resolution as part of the ALMA (Atacama Large Millimeter/submillimeter Array) Large Program FAUST. The 1.3 mm continuum probes the discs of VLA 1623A, B, and W, and the circumbinary disc of the A1 + A2 binary. The C18O emission reveals, for the first time, the gas in the disc envelope of VLA 1623W. We estimate the dynamical mass of VLA 1623W, Mdyn = 0.45 ± 0.08 M⊙, and the mass of its disc, Mdisc ∼ 6 × 10−3 M⊙. C18O also reveals streamers that extend up to 1000 au, spatially and kinematically connecting the envelope and outflow cavities of the A1 + A2 + B system with the disc of VLA 1623W. The presence of the streamers, as well as the spatial (∼1300 au) and velocity (∼2.2 km s−1) offsets of VLA 1623W, suggests that either sources W and A + B formed in different cores, interacting between them, or source W has been ejected from the VLA 1623 multiple system during its formation. In the latter case, the streamers may funnel material from the envelope and cavities of VLA 1623AB on to VLA 1623W, thus concurring to set its final mass and chemical content.
ABSTRACT
The ALMA interferometer has played a key role in revealing a new component of the Sun-like star forming process: the molecular streamers, i.e. structures up to thousands of au long ...funnelling material non-axisymmetrically to discs. In the context of the FAUST ALMA LP, the archetypical VLA1623-2417 protostellar cluster has been imaged at 1.3 mm in the SO(56–45), SO(66–55), and SiO(5–4) line emission at the spatial resolution of 50 au. We detect extended SO emission, peaking towards the A and B protostars. Emission blue-shifted down to 6.6 km s−1 reveals for the first time a long (∼ 2000 au) accelerating streamer plausibly feeding the VLA1623 B protostar. Using SO, we derive for the first time an estimate of the excitation temperature of an accreting streamer: 33 ± 9 K. The SO column density is ∼ 1014 cm−2, and the SO/H2 abundance ratio is ∼ 10−8. The total mass of the streamer is 3 × 10−3M⊙, while its accretion rate is 3–5 × 10−7M⊙ yr−1. This is close to the mass accretion rate of VLA1623 B, in the 0.6–3 × 10−7M⊙ yr−1 range, showing the importance of the streamer in contributing to the mass of protostellar discs. The highest blue- and red-shifted SO velocities behave as the SiO(5–4) emission, the latter species detected for the first time in VLA1623-2417: the emission is compact (100–200 au), and associated only with the B protostar. The SO excitation temperature is ∼ 100 K, supporting the occurrence of shocks associated with the jet, traced by SiO.
We present an overview of the ALMA chemical survey of disk-outflow sources in Taurus (ALMA-DOT), a campaign devoted to the characterization of the molecular emission from partly embedded young stars. ...The project is aimed at attaining a better understanding of the gaseous products delivered to planets by means of high-resolution maps of the assorted lines probing disks at the time of planet formation (≲1 Myr). Nine different molecules are surveyed through our observations of six Class I/flat-spectrum sources. As part of a series of articles analyzing specific targets and molecules, in this work we describe the sample and provide a general overview of the results, focusing specifically on the spatial distribution, column densities, and abundance ratios of H2CO, CS, and CN. In these embedded sources, the 12CO emission is dominated by envelope and outflow emission while the CS and, especially, the H2CO are good tracers of the gaseous disk structure. The spatial distribution and brightness of the o-H2CO 31,2−21,1 and CS 5−4 lines are very similar to each other and across all targets. The CN 2−1 line emission is fainter and distributed over radii larger than the dust continuum. The H2CO and CS emission is always dimmed in the inner ~50 au. While the suppression by the dusty disk and absorption by the line-of-sight material significantly contributes to this inner depression, an actual decrease in the column density is plausible in most cases, making the observed ring-like morphology realistic. We also found that the gaseous disk extent, when traced by H2CO (150−390 au), is always 60% larger than the dust disk. This systematic discrepancy may, in principle, be explained by the different optical depth of continuum and line emission without invoking any dust radial drift. Finally, the o-H2CS 71,6−61,5 and CH3OH 50,5−40,4 line emission are detected in two disks and one disk, respectively, while the HDO is never detected. The H2CO column densities are 12−50 times larger than those inferred for Class II sources while they are in line with those of other Class 0/I. The CS column densities are lower than those of H2CO, which is an opposite trend with regard to Class II objects. We also inferred abundance ratios between the various molecular species finding, among others, a H2CS/H2CO ratio that is systematically lower than unity (0.4−0.7 in HL Tau, 0.1 − 0.2 in IRAS 04302+2247, and <0.4 in all other sources), as well as a CH3OH/H2CO ratio (<0.7 in HL Tau and 0.5−0.7 in IRAS 04302+2247) that is lower than the only available estimate in a protoplanetary disks (1.3 in TW Hya) and between one and two orders of magnitude lower than those of the hot corinos around Class 0 protostars. These results are a first step toward the characterization of the disk’s chemical evolution, which ought to be complemented by subsequent observations of less exceptional disks and customized thermo-chemical modeling.
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