Invited for the cover of this issue are two collaborating groups: one at the Universidad Autónoma de Madrid and the other at the Instituto de Ciencia de Materiales de Madrid. The image depicts ...Cucurbit8uril adsorbed on a transition metal dichalcogenide surface letting the cavity open for complex formation with melatonin and allowing efficient electrochemical sensing. Read the full text of the article at 10.1002/chem.202203244.
“We realized that the theory predicted that complex formation on graphene would be hampered, and then proved that this was the case.” This and more about the story behind the front cover can be found in the article at 10.1002/chem.202203244).
On‐surface synthesis is an emerging approach to obtain, in a single step, precisely defined chemical species that cannot be obtained by other synthetic routes. The control of the electronic structure ...of organic/metal interfaces is crucial for defining the performance of many optoelectronic devices. A facile on‐surface chemistry route has now been used to synthesize the strong electron‐acceptor organic molecule quinoneazine directly on a Cu(110) surface, via thermally activated covalent coupling of para‐aminophenol precursors. The mechanism is described using a combination of in situ surface characterization techniques and theoretical methods. Owing to a strong surface‐molecule interaction, the quinoneazine molecule accommodates 1.2 electrons at its carbonyl ends, inducing an intramolecular charge redistribution and leading to partial conjugation of the rings, conferring azo‐character at the nitrogen sites.
A facile on‐surface route was used to synthesize the strong electron‐acceptor organic molecule quinoneazine directly on a Cu(110) surface, via thermally activated covalent coupling of para‐aminophenol precursors. The mechanism is described using in situ surface characterization and theoretical methods. Owing to a strong surface‐molecule interaction, the quinoneazine molecule accommodates 1.2 electrons at its carbonyl ends.
There exists strong circumstantial evidence from their eccentric orbits that most of the known extra-solar planetary systems are the survivors of violent dynamical instabilities. Here we explore the ...effect of giant planet instabilities on the formation and survival of terrestrial planets. We numerically simulate the evolution of planetary systems around Sun-like stars that include three components: (i) an inner disk of planetesimals and planetary embryos; (ii) three giant planets at Jupiter-Saturn distances; and (iii) an outer disk of planetesimals comparable to estimates of the primitive Kuiper belt. We calculate the dust production and spectral energy distribution of each system by assuming that each planetesimal particle represents an ensemble of smaller bodies in collisional equilibrium. Our main result is a strong correlation between the evolution of the inner and outer parts of planetary systems, i.e. between the presence of terrestrial planets and debris disks. Strong giant planet instabilities – that produce very eccentric surviving planets – destroy all rocky material in the system, including fully-formed terrestrial planets if the instabilities occur late, and also destroy the icy planetesimal population. Stable or weakly unstable systems allow terrestrial planets to accrete in their inner regions and significant dust to be produced in their outer regions, detectable at mid-infrared wavelengths as debris disks. Stars older than ~100 Myr with bright cold dust emission (in particular at λ ~ 70 μm) signpost dynamically calm environments that were conducive to efficient terrestrial accretion. Such emission is present around ~16% of billion-year old Solar-type stars. Our simulations yield numerous secondary results: 1) the typical eccentricities of as-yet undetected terrestrial planets are ~0.1 but there exists a novel class of terrestrial planet system whose single planet undergoes large amplitude oscillations in orbital eccentricity and inclination; 2) by scaling our systems to match the observed semimajor axis distribution of giant exoplanets, we predict that terrestrial exoplanets in the same systems should be a few times more abundant at ~0.5 AU than giant or terrestrial exoplanets at 1 AU; 3) the Solar System appears to be unusual in terms of its combination of a rich terrestrial planet system and a low dust content. This may be explained by the weak, outward-directed instability that is thought to have caused the late heavy bombardment.
This paper describes Herschel observations of the nearby (8.5pc) G5V multi-exoplanet host star 61Vir at 70, 100, 160, 250, 350 and 500m carried out as part of the DEBRIS survey. These observations ...reveal emission that is significantly extended out to a distance of >15arcsec with a morphology that can be fitted by a nearly edge-on (77° inclination) radially broad (from 30au out to at least 100au) debris disc of fractional luminosity 2.7 × 10-5, with two additional (presumably unrelated) sources nearby that become more prominent at longer wavelengths. Chance alignment with a background object seen at 1.4GHz provides potential for confusion, however, the star's 1.4arcsecyr-1 proper motion allows archival Spitzer 70m images to confirm that what we are interpreting as disc emission really is circumstellar. Although the exact shape of the disc's inner edge is not well constrained, the region inside 30au must be significantly depleted in planetesimals. This is readily explained if there are additional planets outside those already known (i.e. in the 0.5-30au region), but is also consistent with collisional erosion. We also find tentative evidence that the presence of detectable debris around nearby stars correlates with the presence of the lowest mass planets that are detectable in current radial velocity surveys. Out of an unbiased sample of the nearest 60G stars, 11 are known to have planets, of which six (including 61Vir) have planets that are all less massive than Saturn, and four of these have evidence for debris. The debris towards one of these planet hosts (HD20794) is reported here for the first time. This fraction (4/6) is higher than that expected for nearby field stars (15per cent), and implies that systems that form low-mass planets are also able to retain bright debris discs. We suggest that this correlation could arise because such planetary systems are dynamically stable and include regions that are populated with planetesimals in the formation process where the planetesimals can remain unperturbed over Gyr time-scales. PUBLICATION ABSTRACT
ABSTRACT The study of the planet-debris disk connection can shed light on the formation and evolution of planetary systems and may help "predict" the presence of planets around stars with certain ...disk characteristics. In preliminary analyses of subsamples of the Herschel DEBRIS and DUNES surveys, Wyatt et al. and Marshall et al. identified a tentative correlation between debris and the presence of low-mass planets. Here we use the cleanest possible sample out of these Herschel surveys to assess the presence of such a correlation, discarding stars without known ages, with ages Gyr, and with binary companions AU to rule out possible correlations due to effects other than planet presence. In our resulting subsample of 204 FGK stars, we do not find evidence that debris disks are more common or more dusty around stars harboring high-mass or low-mass planets compared to a control sample without identified planets. There is no evidence either that the characteristic dust temperature of the debris disks around planet-bearing stars is any different from that in debris disks without identified planets, nor that debris disks are more or less common (or more or less dusty) around stars harboring multiple planets compared to single-planet systems. Diverse dynamical histories may account for the lack of correlations. The data show a correlation between the presence of high-mass planets and stellar metallicity, but no correlation between the presence of low-mass planets or debris and stellar metallicity. Comparing the observed cumulative distribution of fractional luminosity to those expected from a Gaussian distribution in logarithmic scale, we find that a distribution centered on the solar system's value fits the data well, while one centered at 10 times this value can be rejected. This is of interest in the context of future terrestrial planet detection and characterization because it indicates that there are good prospects for finding a large number of debris disk systems (i.e., with evidence of harboring planetesimals, the building blocks of planets) with exozodiacal emission low enough to be appropriate targets for an ATLAST-type mission to search for biosignatures.
Several exoplanets have recently been imaged at wide separations of >10 AU from their parent stars. These span a limited range of ages (<50 Myr) and atmospheric properties, with temperatures of ...800-1800 K and very red colors (J - H > 0.5 mag), implying thick cloud covers. Furthermore, substantial model uncertainties exist at these young ages due to the unknown initial conditions at formation, which can lead to an order of magnitude of uncertainty in the modeled planet mass. Here, we report the direct-imaging discovery of a Jovian exoplanet around the Sun-like star GJ 504, detected as part of the SEEDS survey. The system is older than all other known directly imaged planets; as a result, its estimated mass remains in the planetary regime independent of uncertainties related to choices of initial conditions in the exoplanet modeling. Using the most common exoplanet cooling model, and given the system age of 160160 super(+350) sub(-60) Myr, GJ 504b has an estimated mass of 4 super(+45) sub(-1.0) Jupiter masses, among the lowest of directly imaged planets. Its projected separation of 43.5 AU exceeds the typical outer boundary of ~30 AU predicted for the core accretion mechanism. GJ 504b is also significantly cooler (510 super(+30) sub(-20) K) and has a bluer color (J - H = -0.23 mag) than previously imaged exoplanets, suggesting a largely cloud-free atmosphere accessible to spectroscopic characterization. Thus, it has the potential of providing novel insights into the origins of giant planets as well as their atmospheric properties.
Abstract
We present the development of an electrochemical sensor towards melatonin determination based on the synergistic effect between MoS
2
nanosheets and cucurbit8uril. For the sensor ...construction cucurbit8uril suspensions were prepared in water, and MoS
2
nanosheets were obtained by liquid exfoliation in ethanol:water. The sensing platform was topographically characterized by Atomic Force Microscopy. Electrochemical Impedance Spectroscopy experiments allowed us to study the charge transfer process during melatonin oxidation. Moreover, stoichiometry of the resulting complex has also been determined. After the optimization of the sensor construction and the experimental variables involved in the Differential Pulse Voltammetric response of melatonin, detection limit of 3.80 × 10
−7
M, relative errors minor than 3.8% and relative standard deviation lower than 4.4% were obtained. The proposed sensor has been successfully applied to melatonin determination in pharmaceutical and biological samples as human urine and serum, with very good recoveries ranging from 90 to 102%.
We present models for the formation of terrestrial planets, and the collisional evolution of debris disks, in planetary systems that contain multiple unstable gas giants. We previously showed that ...the dynamics of the giant planets introduces a correlation between the presence of terrestrial planets and debris disks. Here we present new simulations that show that this connection is qualitatively robust to changes in: the mass distribution of the giant planets, the width and mass distribution of the outer planetesimal disk, and the presence of gas in the disk. We discuss how variations in these parameters affect the evolution. Systems with equal-mass giant planets undergo the most violent instabilities, and these destroy both terrestrial planets and the outer planetesimal disks that produce debris disks. In contrast, systems with low-mass giant planets efficiently produce both terrestrial planets and debris disks. A large fraction of systems with low-mass outermost giant planets have stable gaps between these planets that are frequently populated by planetesimals. Planetesimal belts between outer giant planets may affect debris disk SEDs. If Earth-mass seeds are present in outer planetesimal disks, the disks radially spread to colder temperatures. We argue that this may explain the very low frequency of > 1 Gyr-old solar-type stars with observed 24 micron excesses. Among the (limited) set of configurations explored, the best candidates for hosting terrestrial planets at ~1 AU are stars older than 0.1-1 Gyr with bright debris disks at 70 micron but with no currently-known giant planets. These systems combine evidence for rocky building blocks, with giant planet properties least likely to undergo destructive dynamical evolution. We predict an anti-correlation between debris disks and eccentric giant planets, and a positive correlation between debris disks and terrestrial planets.
We present the first near-IR scattered light detection of the transitional disk associated with the Herbig Ae star MWC 758 using data obtained as part of the Strategic Exploration of Exoplanets and ...Disks with Subaru, and 1.1 mum Hubble Space Telescope/NICMOS data. While submillimeter studies suggested there is a dust-depleted cavity with r = 0."35, we find scattered light as close as 0."1 (20-28 AU) from the star, with no visible cavity at H, K', or K sub(s). We find two small-scaled spiral structures that asymmetrically shadow the outer disk. We model one of the spirals using spiral density wave theory, and derive a disk aspect ratio of h ~ 0.18, indicating a dynamically warm disk. If the spiral pattern is excited by a perturber, we estimate its mass to be 5 super(+3) sub(-4) M sub(J), in the range where planet filtration models predict accretion continuing onto the star. Using a combination of non-redundant aperture masking data at L' and angular differential imaging with Locally Optimized Combination of Images at K' and K sub(s), we exclude stellar or massive brown dwarf companions within 300 mas of the Herbig Ae star, and all but planetary mass companions exterior to 0."5. We reach 5sigma contrasts limiting companions to planetary masses, 3-4 M sub(J) at 1."0 and 2 M sub(J) at 1."55, using the COND models. Collectively, these data strengthen the case for MWC 758 already being a young planetary system.
Context. Stars form surrounded by gas- and dust-rich protoplanetary discs. Generally, these discs dissipate over a few (3–10) Myr, leaving a faint tenuous debris disc composed of second-generation ...dust produced by the attrition of larger bodies formed in the protoplanetary disc. Giant planets detected in radial velocity and transit surveys of main-sequence stars also form within the protoplanetary disc, whilst super-Earths now detectable may form once the gas has dissipated. Our own solar system, with its eight planets and two debris belts, is a prime example of an end state of this process. Aims. The Herschel DEBRIS, DUNES, and GT programmes observed 37 exoplanet host stars within 25 pc at 70, 100, and 160 μm with the sensitivity to detect far-infrared excess emission at flux density levels only an order of magnitude greater than that of the solar system’s Edgeworth-Kuiper belt. Here we present an analysis of that sample, using it to more accurately determine the (possible) level of dust emission from these exoplanet host stars and thereafter determine the links between the various components of these exoplanetary systems through statistical analysis. Methods. We have fitted the flux densities measured from recent Herschel observations with a simple two parameter (Td, LIR/L⋆) black-body model (or to the 3σ upper limits at 100 μm). From this uniform approach we calculated the fractional luminosity, radial extent and dust temperature. We then plotted the calculated dust luminosity or upper limits against the stellar properties, e.g. effective temperature, metallicity, and age, and identified correlations between these parameters. Results. A total of eleven debris discs are identified around the 37 stars in the sample. An incidence of ten cool debris discs around the Sun-like exoplanet host stars (29 ± 9%) is consistent with the detection rate found by DUNES (20.2 ± 2.0%). For the debris disc systems, the dust temperatures range from 20 to 80 K, and fractional luminosities (LIR/L⋆) between 2.4 ×10-6 and 4.1 ×10-4. In the case of non-detections, we calculated typical 3σ upper limits to the dust fractional luminosities of a few ×10-6. Conclusions. We recover the previously identified correlation between stellar metallicity and hot-Jupiter planets in our data set. We find a correlation between the increased presence of dust, lower planet masses, and lower stellar metallicities. This confirms the recently identified correlation between cold debris discs and low-mass planets in the context of planet formation by core accretion.
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