Context. The Galactic center is the closest region where we can study star formation under extreme physical conditions like those in high-redshift galaxies. Aims. We measure the temperature of the ...dense gas in the central molecular zone (CMZ) and examine what drives it. Methods. We mapped the inner 300 pc of the CMZ in the temperature-sensitive J = 3–2 para-formaldehyde (p - H2CO) transitions. We used the 32,1−22,0/ 30,3−20,2 line ratio to determine the gas temperature in n ~ 104−105 cm-3 gas. We have produced temperature maps and cubes with 30′′ and 1 km s-1 resolution and published all data in FITS form. Results. Dense gas temperatures in the Galactic center range from ~60 K to >100 K in selected regions. The highest gas temperatures TG> 100 K are observed around the Sgr B2 cores, in the extended Sgr B2 cloud, the 20 km s-1 and 50 km s-1 clouds, and in “The Brick” (G0.253+0.016). We infer an upper limit on the cosmic ray ionization rate ζCR< 10-14s-1. Conclusions. The dense molecular gas temperature of the region around our Galactic center is similar to values found in the central regions of other galaxies, in particular starburst systems. The gas temperature is uniformly higher than the dust temperature, confirming that dust is a coolant in the dense gas. Turbulent heating can readily explain the observed temperatures given the observed line widths. Cosmic rays cannot explain the observed variation in gas temperatures, so CMZ dense gas temperatures are not dominated by cosmic ray heating. The gas temperatures previously observed to be high in the inner ~75 pc are confirmed to be high in the entire CMZ.
Significance
The detection of ethanolamine (
N
H
2
C
H
2
C
H
2
OH) in a molecular cloud in the interstellar medium confirms that a precursor of phospholipids is efficiently formed by interstellar ...chemistry. Hence, ethanolamine could have been transferred from the proto-Solar nebula to planetesimals and minor bodies of the Solar System and thereafter to our planet. The prebiotic availability of ethanolamine on early Earth could have triggered the formation of efficient and permeable amphiphilic molecules such as phospholipids, thus playing a relevant role in the evolution of the first cellular membranes needed for the emergence of life.
Cell membranes are a key element of life because they keep the genetic material and metabolic machinery together. All present cell membranes are made of phospholipids, yet the nature of the first membranes and the origin of phospholipids are still under debate. We report here the presence of ethanolamine in space,
N
H
2
C
H
2
C
H
2
OH, which forms the hydrophilic head of the simplest and second-most-abundant phospholipid in membranes. The molecular column density of ethanolamine in interstellar space is
N
= (1.51
±
0.07)
×
10
13
c
m
−
2
, implying a molecular abundance with respect to
H
2
of
(
0.9
−
1.4
)
×
10
−
10
. Previous studies reported its presence in meteoritic material, but they suggested that it is synthesized in the meteorite itself by decomposition of amino acids. However, we find that the proportion of the molecule with respect to water in the interstellar medium is similar to the one found in the meteorite (
10
−
6
). These results indicate that ethanolamine forms efficiently in space and, if delivered onto early Earth, could have contributed to the assembling and early evolution of primitive membranes.
One of the proposed scenarios for the origin of life is the primordial RNA world, which considers that RNA molecules were likely responsible for the storage of genetic information and the catalysis ...of biochemical reactions in primitive cells, before the advent of proteins and DNA. In the last decade, experiments in the field of prebiotic chemistry have shown that RNA nucleotides can be synthesized from relatively simple molecular precursors, most of which have been found in space. An important exception is hydroxylamine, NH2OH, which, despite several observational attempts, it has not been detected in space yet. Here we present the first detection of NH2OH in the interstellar medium toward the quiescent molecular cloud G+0.693-0.027 located in the Galactic Center. We have targeted the three groups of transitions from the J = 2−1, 3−2, and 4−3 rotational lines, detecting five transitions that are unblended or only slightly blended. The derived molecular abundance of NH2OH is (2.1 0.9) × 10−10. From the comparison of the derived abundance of NH2OH and chemically related species, with those predicted by chemical models and measured in laboratory experiments, we favor the formation of NH2OH in the interstellar medium via hydrogenation of NO on dust grain surfaces, with possibly a contribution of ice-mantle NH3 oxidation processes. Further laboratory studies and quantum chemical calculations are needed to completely rule out the formation of NH2OH in the gas phase.
The chemical compounds carrying the thiol group (-SH) have been considered essential in recent prebiotic studies regarding the polymerization of amino acids. We have searched for this kind of ...compound toward the Galactic Center quiescent cloud G+0.693–0.027. We report the first detection in the interstellar space of the trans-isomer of monothioformic acid (t-HC(O)SH) with an abundance of ∼1 נ10−10. Additionally, we provide a solid confirmation of the gauche isomer of ethyl mercaptan (g-C2H5SH) with an abundance of ∼3 נ10−10, and we also detect methyl mercaptan (CH3SH) with an abundance of ∼5 נ10−9. Abundance ratios were calculated for the three SH-bearing species and their OH analogs, revealing similar trends between alcohols and thiols with increasing complexity. Possible chemical routes for the interstellar synthesis of t-HC(O)SH, CH3SH, and C2H5SH are discussed, as well as the relevance of these compounds in the synthesis of prebiotic proteins in the primitive Earth.
Abstract
A quarter century after the detection of the last interstellar carboxylic acid, acetic acid (CH
3
COOH), we report the discovery of a new one, the
cis-trans
form of carbonic acid (HOCOOH), ...toward the Galactic center molecular cloud G+0.693–0.027. HOCOOH stands as the first interstellar molecule containing three oxygen atoms and the third carboxylic acid detected so far in the interstellar medium. Albeit the limited available laboratory measurements (up to 65 GHz), we have also directly identified several pairs of unblended lines in the astronomical data (between 75 and 120 GHz), which allowed us to slightly improve the set of spectroscopic constants. We derive a column density for
cis-trans
HOCOOH of
N
= (6.4 ± 0.4) × 10
12
cm
−2
, which yields an abundance with respect to molecular H
2
of 4.7 × 10
−11
. Meanwhile, the extremely low dipole moment (about 15 times lower) of the lower-energy conformer,
cis-cis
HOCOOH, precludes its detection. We obtain an upper limit to its abundance with respect to H
2
of ≤1.2 × 10
−9
, which suggests that
cis-cis
HOCOOH might be fairly abundant in interstellar space, although it is nearly undetectable by radio astronomical observations. We derive a
cis-cis
/
cis-trans
ratio of ≤25, consistent with the smaller energy difference between both conformers compared with the relative stability of
trans-
and
cis
-formic acid. Finally, we compare the abundance of these acids in different astronomical environments, further suggesting a relationship between the chemical content found in the interstellar medium and the chemical composition of the minor bodies of the solar system, which could be inherited during the star formation process.
We present 1″-resolution ALMA observations of the circumnuclear disk (CND) and the interstellar environment around Sgr A*. The images unveil the presence of small spatial scale 12CO (J = 3–2) ...molecular “cloudlets” (≲20 000 AU size) within the central parsec of the Milky Way, in other words, inside the cavity of the CND, and moving at high speeds, up to 300 km s−1 along the line-of-sight. The 12CO-emitting structures show intricate morphologies: extended and filamentary at high negative-velocities (vLSR ≲−150 km s−1), more localized and clumpy at extreme positive-velocities (vLSR ≳+200 km s−1). Based on the pencil-beam 12CO absorption spectrum toward Sgr A* synchrotron emission, we also present evidence for a diffuse molecular gas component producing absorption features at more extreme negative-velocities (vLSR < −200 km s−1). The CND shows a clumpy spatial distribution traced by the optically thin H13CN (J = 4–3) emission. Its motion requires a bundle of non-uniformly rotating streams of slightly different inclinations. The inferred gas density peaks, molecular cores of several 105 cm−3, are lower than the local Roche limit. This supports that CND cores are transient. We apply the two standard orbit models, spirals vs. ellipses, invoked to explain the kinematics of the ionized gas streamers around Sgr A*. The location and velocities of the 12CO cloudlets inside the cavity are inconsistent with the spiral model, and only two of them are consistent with the Keplerian ellipse model. Most cloudlets, however, show similar velocities that are incompatible with the motions of the ionized streamers or with gas bounded to the central gravity. We speculate that they are leftovers of more massive molecular clouds that fall into the cavity and are tidally disrupted, or that they originate from instabilities in the inner rim of the CND that lead to fragmentation and infall from there. In either case, we show that molecular cloudlets, all together with a mass of several 10 M⊙, exist around Sgr A*. Most of them must be short-lived, ≲104 yr: photoevaporated by the intense stellar radiation field, G0 ≃ 105.3–104.3, blown away by winds from massive stars in the central cluster, or disrupted by strong gravitational shears.
We report the first detection in the interstellar medium (ISM) of a C2H5O2N isomer: syn-glycolamide (NH2C(O)CH2OH). The exquisite sensitivity at sub-mK levels of an ultradeep spectral survey carried ...out with the Yebes 40 m and IRAM 30 m telescopes toward the G+0.693–0.027 molecular cloud has allowed us to unambiguously identify multiple transitions of this species. We derived a column density of (7.4 ± 0.7) × 1012 cm−2, which implies a molecular abundance with respect to H2 of 5.5 × 10−11. The other C2H5O2N isomers, including the higher-energy anti conformer of glycolamide and two conformers of glycine, were not detected. The upper limit derived for the abundance of glycine indicates that this amino acid is surely less abundant than its isomer glycolamide in the ISM. The abundances of the C2H5O2N isomers cannot be explained in terms of thermodynamic equilibrium; thus, chemical kinetics need to be invoked. While the low abundance of glycine might not be surprising, based on the relative low abundances of acids in the ISM compared to other compounds (e.g., alcohols, aldehydes, or amines), several chemical pathways can favor the formation of its isomer glycolamide. It can be formed through radical–radical reactions on the surface of dust grains. The abundances of these radicals can be significantly boosted in an environment affected by a strong ultraviolet field induced by cosmic rays, such as that expected in G+0.693–0.027. Therefore, as shown by several recent molecular detections toward this molecular cloud, it stands out as the best target to discover new species with carbon, oxygen, and nitrogen with increasing chemical complexity.
Abstract
We present the first detection in space of O-protonated carbonyl sulfide (HOCS
+
), in the midst of an ultradeep molecular line survey toward the G+0.693-0.027 molecular cloud. From the ...observation of all
K
a
= 0 transitions ranging from
J
lo
= 2 to
J
lo
= 13 of HOCS
+
covered by our survey, we derive a column density of
N
= (9 ± 2) × 10
12
cm
−2
, translating into a fractional abundance relative to H
2
of ∼7 × 10
−11
. Conversely, the S-protonated HSCO
+
isomer remains undetected, and we derive an upper limit to its abundance with respect to H
2
of ≤3 × 10
−11
, a factor of ≥2.3 less abundant than HOCS
+
. We obtain an HOCS
+
/OCS ratio of ∼2.5 × 10
−3
, in good agreement with the prediction of astrochemical models. These models show that one of the main chemical routes to the interstellar formation of HOCS
+
is likely the protonation of OCS, which appears to be more efficient at the oxygen end. Also, we find that high values of cosmic-ray ionization rates (10
−15
–10
−14
s
−1
) are needed to reproduce the observed abundance of HOCS
+
. In addition, we compare the O/S ratio across different interstellar environments. G+0.693-0.027 appears as the source with the lowest O/S ratio. We find an HOCO
+
/HOCS
+
ratio of ∼31, in accordance with other O/S molecular pairs detected toward this region and also close to the O/S solar value (∼37). This fact indicates that S is not significantly depleted within this cloud due to the action of large-scale shocks, unlike in other sources where S-bearing species remain trapped on icy dust grains.
We report serendipitous detections of line emission with the Atacama Large Millimeter/submillimeter Array (ALMA) in bands 3, 6, and 7 in the central parsec down to within 1′′ around Sgr A* at an up ...to now highest resolution (<0.5′′) view of the Galactic center (GC) in the submillimeter (sub-mm) domain. From the 100 GHz continuum and the H39α emission we obtain a uniform electron temperature around Te ~ 6000 K for the minispiral. The spectral index (S ∝ να) of Sagittarius A* (Sgr A*) is ~0.5 at 100–250 GHz and ~0.0 at 230–340 GHz. The bright sources in the center show spectral indices around –0.1 implying Bremsstrahlung emission, while dust emission is emerging in the minispiral exterior. Apart from CS, which is most widespread in the center, H13CO+, HC3N, SiO, SO, C2H, CH3OH, 13CS and N2H+ are also detected. The bulk of the clumpy emission regions is at positive velocities and in a region confined by the minispiral northern arm (NA), bar, and the sources IRS 3 and 7. Although partly spatially overlapping with the radio recombination line (RRL) emission at same negative velocities, the relation to the minispiral remains unclear. A likely explanation is an infalling clump consisting of denser cloud cores embedded in diffuse gas. This central association (CA) of clouds shows three times higher CS/X (X: any other observed molecule) ratios than the circumnuclear disk (CND) suggesting a combination of higher excitation, by a temperature gradient and/or infrared (IR) pumping, and abundance enhancement due to UV and/or X-ray emission. Hence, we conclude that this CA is closer to the center than the CND is to the center. Moreover, we find molecular line emission at velocities up to 200 km s-1. Apart from the CA, we identified two intriguing regions in the CND. One region shows emission in all molecular species and higher energy levels tested in this and previous observations and contains a methanol class I maser. The other region shows similar behavior of the line ratios such as the CA. Outside the CND, we find the traditionally quiescent gas tracer N2H+ coinciding with the largest IR dark clouds in the field. Methanol emission is found at and around previously detected methanol class I masers in the same region. We propose to make these particular regions subject to further studies in the scope of hot core, cold core, and extreme photon and/or X-ray dominated region (PDR/XDR) chemistry and consequent star formation in the central few parsecs.
Abstract
We present the first detection of (
Z
)-1,2-ethenediol, (CHOH)
2
, the enol form of glycolaldehyde, in the interstellar medium toward the G+0.693−0.027 molecular cloud located in the ...Galactic Center. We have derived a column density of (1.8 ± 0.1) × 10
13
cm
−2
, which translates into a molecular abundance with respect to molecular hydrogen of 1.3 × 10
−10
. The abundance ratio between glycolaldehyde and (
Z
)-1,2-ethenediol is ∼5.2. We discuss several viable formation routes through chemical reactions from precursors such as HCO, H
2
CO, CHOH, or CH
2
CHOH. We also propose that this species might be an important precursor in the formation of glyceraldehyde (HOCH
2
CHOHCHO) in the interstellar medium through combination with the hydroxymethylene (CHOH) radical.
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