The compression of argon is measured between 10 K and 296 K up to 20 GPa and and up to 114 GPa at 296 K in diamond anvil cells. Three samples conditioning are used: (1) single crystal sample directly ...compressed between the anvils, (2) powder sample directly compressed between the anvils, (3) single crystal sample compressed in a pressure medium. A partial transformation of the face-centered cubic (fcc) phase to a hexagonal close-packed (hcp) structure is observed above 4.2-13 GPa. Hcp phase forms through stacking faults in fcc-Ar and its amount depends on pressurizing conditions and starting fcc-Ar microstructure. The quasi-hydrostatic equation of state of the fcc phase is well described by a quasi-harmonic Mie-Grüneisen-Debye formalism, with the following 0 K parameters for Rydberg-Vinet equation: Formula: see text = 38.0 ÅFormula: see text/at, Formula: see text = 2.65 GPa, Formula: see text = 7.423. Under the current experimental conditions, non-hydrostaticity affects measured P-V points mostly at moderate pressure (Formula: see text 20 GPa).
Nowadays, with the large-scale penetration of distributed and renewable energy resources, ES (energy storage) stands out for its ability of adding flexibility, controlling intermittence and providing ...back-up generation to electrical networks. It represents the critical link between the energy supply and demand chains, being a key element for increasing the role and attractiveness of renewable generation into the power grid, providing also numerous technical and economic benefits to the power system stakeholders. On islanded systems and micro-grids, being updated about the state-of-the-art of ES systems and their benefits becomes even more relevant. Hence, in the present paper a comprehensive study and analysis of ES leading technologies' main assets, research issues, global market figures, economic benefits and technical applications is provided. Special emphasis is given to ES on islands, as a new contribution to earlier studies, addressing their particular requirements, the most appropriate technologies and existing operating projects throughout the world.
•Energy storage is a key element for increasing the role and attractiveness of renewable generation.•Numerous technical and economic benefits to the power system stakeholders can be provided.•A comprehensive study and analysis of energy storage leading technologies' is presented.•Special emphasis is given to energy storage on islands, as a new contribution to earlier studies.
ABSTRACT
Fast radio bursts are transient radio pulses from presumably compact stellar sources of extragalactic origin. With new telescopes detecting multiple events per day, statistical methods are ...required in order to interpret observations and make inferences regarding astrophysical and cosmological questions. We present a method that uses probability estimates of fast radio burst observables to obtain likelihood estimates for the underlying models. Considering models for all regions along the line of sight, including intervening galaxies, we perform Monte Carlo simulations to estimate the distribution of the dispersion measure (DM), rotation measure (RM), and temporal broadening. Using Bayesian statistics, we compare these predictions to observations of fast radio bursts. By applying Bayes theorem, we obtain lower limits on the redshift of fast radio bursts with extragalactic DM ≳ 400 pc cm−3. We find that intervening galaxies cannot account for all highly scattered fast radio bursts in FRBcat, thus requiring a denser and more turbulent environment than an SGR 1935+2154-like magnetar. We show that a sample of ≳103 unlocalized fast radio bursts with associated extragalactic RM ≥ 1 rad m−2 can improve current upper limits on the strength of intergalactic magnetic fields.
In this review, we describe different families of metastable materials, some of them with relevant technological applications, which can be stabilized at moderate pressures 2-3.5 GPa in a ...piston-cylinder press. The synthesis of some of these systems had been previously reported under higher hydrostatic pressures (6-10 GPa), but can be accessed under milder conditions in combination with reactive precursors prepared by soft-chemistry techniques. These systems include perovskites with transition metals in unusual oxidation states (e.g., RNiO
with Ni
, R = rare earths); double perovskites such as RCu
Mn
O
with Jahn-Teller Cu
ions at A sites, pyrochlores derived from Tl
Mn
O
with colossal magnetoresistance, pnictide skutterudites M
Co
Sb
(M = La, Yb, Ce, Sr, K) with thermoelectric properties, or metal hydrides Mg
MH
(M = Fe, Co, Ni) and AMgH
(A: alkali metals) with applications in hydrogen storage. The availability of substantial amounts of sample (0.5-1.5 g) allows a complete characterization of the properties of interest, including magnetic, transport, thermoelectric properties and so on, and the structural characterization by neutron or synchrotron X-ray diffraction techniques.
In this work, Gd-filled skutterudite GdxCo4Sb12 was prepared using one step method under high pressure in a piston-cylinder-based press at 3.5 GPa and moderate temperature of 800 °C. A detailed ...structural characterization was performed using synchrotron X-ray diffraction (SXRD), revealing a filling fraction of x = 0.033(2) and an average <Gd–Sb> bond length of 3.3499(3) Å. The lattice thermal expansion accessed via temperature-dependent SXRD led to a precise determination of a Debye temperature of 322(3) K, from the fitting of the unit-cell volume expansion using the second order Grüneisen approximation. This parameter, when evaluated through the mean square displacements of Co and Sb, displayed a value of 265(2) K, meaning that the application of the harmonic Debye theory underestimates the Debye temperature in skutterudites. Regarding the Gd atom, its intrinsic disorder value was ~5× and ~25× higher than those of the Co and Sb, respectively, denoting that Gd has a strong rattling behavior with an Einstein temperature of θE = 67(2) K. As a result, an ultra-low thermal conductivity of 0.89 W/m·K at 773 K was obtained, leading to a thermoelectric efficiency zT of 0.5 at 673 K.
Autophagy is a highly regulated process that has an important role in the control of a wide range of cellular functions, such as organelle recycling, nutrient availability and tissue differentiation. ...A recent study has shown an increased autophagic activity in the adipose tissue of obese subjects, and a role for autophagy in obesity-associated insulin resistance was proposed. Body mass reduction is the most efficient approach to tackle insulin resistance in over-weight subjects; however, the impact of weight loss in adipose tissue autophagy is unknown.
Adipose tissue autophagy was evaluated in mice and humans.
First, a mouse model of diet-induced obesity and diabetes was maintained on a 15-day, 40% caloric restriction. At baseline, markers of autophagy were increased in obese mice as compared with lean controls. Upon caloric restriction, autophagy increased in the lean mice, whereas it decreased in the obese mice. The reintroduction of ad libitum feeding was sufficient to rapidly reduce autophagy in the lean mice and increase autophagy in the obese mice. In the second part of the study, autophagy was evaluated in the subcutaneous adipose tissue of nine obese-non-diabetic and six obese-diabetic subjects undergoing bariatric surgery for body mass reduction. Specimens were collected during the surgery and approximately 1 year later. Markers of systemic inflammation, such as tumor necrosis factor-1α, interleukin (IL)-6 and IL-1β were evaluated. As in the mouse model, human obesity was associated with increased autophagy, and body mass reduction led to an attenuation of autophagy in the adipose tissue.
Obesity and caloric overfeeding are associated with the defective regulation of autophagy in the adipose tissue. The studies in obese-diabetic subjects undergoing improved metabolic control following calorie restriction suggest that autophagy and inflammation are regulated independently.
The propagation of charged particles, including cosmic rays, in a partially ordered magnetic field is characterized by a diffusion tensor whose components depend on the particle's Larmor radius R
L ...and the degree of order in the magnetic field. Most studies of the particle diffusion presuppose a scale separation between the mean and random magnetic fields (e.g. there being a pronounced minimum in the magnetic power spectrum at intermediate scales). Scale separation is often a good approximation in laboratory plasmas, but not in most astrophysical environments such as the interstellar medium (ISM). Modern simulations of the ISM have numerical resolution of the order of 1 pc, so the Larmor radius of the cosmic rays that dominate in energy density is at least 106 times smaller than the resolved scales. Large-scale simulations of cosmic ray propagation in the ISM thus rely on oversimplified forms of the diffusion tensor. We take the first steps towards a more realistic description of cosmic ray diffusion for such simulations, obtaining direct estimates of the diffusion tensor from test particle simulations in random magnetic fields (with the Larmor radius scale being fully resolved), for a range of particle energies corresponding to 10−2 ≲ R
L/l
c ≲ 103, where l
c is the magnetic correlation length. We obtain explicit expressions for the cosmic ray diffusion tensor for R
L/l
c ≪ 1, that might be used in a sub-grid model of cosmic ray diffusion. The diffusion coefficients obtained are closely connected with existing transport theories that include the random walk of magnetic lines.
Evolution of galactic magnetic fields Rodrigues, L F S; Chamandy, L; Shukurov, A ...
Monthly notices of the Royal Astronomical Society,
02/2019, Volume:
483, Issue:
2
Journal Article
Peer reviewed
Open access
ABSTRACT
We study the cosmic evolution of the magnetic fields of a large sample of spiral galaxies in a cosmologically representative volume by employing a semi-analytic galaxy formation model and ...numerical dynamo solver in tandem. We start by deriving time- and radius-dependent galaxy properties using the galform galaxy formation model, which are then fed into the non-linear mean-field dynamo equations. These are solved to give the large-scale (mean) field as a function of time and galactocentric radius for a thin disc, assuming axial symmetry. A simple prescription for the evolution of the small-scale (random) magnetic field component is also adopted. We find that, while most massive galaxies are predicted to have large-scale magnetic fields at redshift $z$ = 0, a significant fraction of them is expected to contain negligible large-scale field. Our model indicates that, for most of the galaxies containing large-scale magnetic fields today, the mean-field dynamo becomes active at $z$ < 3. Moreover, the typical magnetic field strength at any given galactic stellar mass is predicted to decline with time up until the present epoch, in agreement with our earlier results. We compute the radial profiles of pitch angle, and find broad agreement with observational data for nearby galaxies.
The development of new magnetic refrigerants demands an effective investigation of materials with a large magnetocaloric effect in a wide temperature range. Herein, we report on the structural, ...magnetic, and magnetocaloric properties of the two-site disordered double perovskite GdSrCoFeO6 prepared by the modified solid-state synthesis method. Temperature-dependent synchrotron X-ray diffraction analysis revealed that GdSrCoFeO6 crystallizes in the orthorhombic phase (Pnma), with Gd3+/Sr2+ and Co2+/3+/Fe3+/4+ ions randomly distributed on the A- and B-sites, respectively. An observed lattice parameter anomaly around 60 K indicates the occurrence of the magnetoelastic coupling, which coincides with the presence of ferro/ferrimagnetic (FM/FiM) ordering below T C ≈ 65 K from the magnetic measurements. These results match well with our first-principles calculation prediction of low-temperature magnetic (FM/FiM) and electronic (insulating/metal) transitions related to a combined effect of Co and Fe short- and long-range competitions, crossings of spin state at Co ions, and the hybridization degree between Gd-4f and Co-3d states. Additionally, a modified Arrott plot and Kouvel–Fisher analysis were used to establish the nature of the magnetic phase transition in GdSrCoFeO6, yielding the critical exponent β = 1.46(6)/1.45(6), γ = 1.48(5)/1.17(2), and δ = 2.01(3)/1.80(5), respectively. The specific heat analysis reveals two well-defined broad peaks (∼10 and ∼70 K), which match well with a Schottky anomaly (Gd-4f) and the magnetic transition of FM/FiM to paramagnetic order, respectively. The magnetocaloric effect (MCE) analysis reveals a maximum magnetic entropy change ΔS M max ≈ 13 J kg–1 K–1 (at ∼8 K) under a field of 0–7 T. These results evidence that the Schottky anomaly and the magnetoelastic coupling seem to be key factors for driving further enhancements to the MCE in GdSrCoFeO6, making it a possible candidate for cryogenic applications.
Skutterudite-type compounds based on □Co4Sb12 pnictide are promising for thermoelectric application due to their good Seebeck values and high carrier mobility. Filling the 8a voids (in the cubic ...space group Im3̅) with different elements (alkali, alkali earth, and rare earth) helps to reduce the thermal conductivity and thus increases the thermoelectric performance. A systematic characterization by synchrotron X-ray powder diffraction of different M-filled Co4Sb12 (M = K, Sr, La, Ce, and Yb) skutterudites was carried out under high pressure in the range ∼0–12 GPa. The isothermal equations of state (EOS) were obtained in this pressure range and the Bulk moduli (B 0) were calculated for all the filled skutterudites, yielding unexpected results. A lattice expansion due to the filler elements fails in the description of the Bulk moduli. Topochemical studies of the filler site environment exhibited a slight disturbance and an increased ionic character when the filler is incorporated. The mechanical properties by means of Bulk moduli resulted in being sensitive to the presence of filler atoms inside the skutterudite voids, being affected by the covalent/ionic exchange of the Co–Sb and Sb–Sb bonds.
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