Spatially resolved structures in protoplanetary disks hint at unseen planets. Previous imaging observations of the transitional disk around MWC 758 revealed an inner cavity, a ring-like outer disk, ...emission clumps, and spiral arms, all possibly generated by companions. We present ALMA dust continuum observations of MWC 758 at 0.87 mm wavelength with 43 × 39 mas angular resolution (6.9 × 6.2 au) and 20 Jy beam−1 rms. The central submillimeter emission cavity is revealed to be eccentric; once deprojected, its outer edge can be well fitted by an ellipse with an eccentricity of 0.1 and one focus on the star. The broad ring-like outer disk is resolved into three narrow rings with two gaps in between. The outer two rings tentatively show the same eccentricity and orientation as the innermost ring bounding the inner cavity. The two previously known dust emission clumps are resolved in both the radial and azimuthal directions, with radial widths equal to ∼4× the local scale height. Only one of the two spiral arms previously imaged in near-infrared (NIR) scattered light is revealed in ALMA dust emission, at a slightly larger stellocentric distance owing to projection effects. We also submit evidence of disk truncation at ∼100 au based on comparing NIR imaging observations with models. The spirals, the north clump, and the truncated disk edge are all broadly consistent with the presence of one companion exterior to the spirals at roughly 100 au.
Protoplanets can produce structures in protoplanetary disks via gravitational disk-planet interactions. Once detected, such structures serve as signposts of planet formation. Here we investigate the ...kinematic signatures in disks produced by multi-Jupiter mass (MJ) planets using 3D hydrodynamics and radiative transfer simulations. Such a planet opens a deep gap, and drives transonic vertical motions inside. Such motions include both a bulk motion of the entire half-disk column, and turbulence on scales comparable to and smaller than the scale height. They significantly broaden molecular lines from the gap, producing double-peaked line profiles at certain locations, and a kinematic velocity dispersion comparable to thermal after azimuthal averaging. The same planet does not drive fast vertical motions outside the gap, except at the inner spiral arms and the disk surface. Searching for line broadening induced by multi-MJ planets inside gaps requires an angular resolution comparable to the gap width, an assessment of the gap gas temperature to within a factor of 2, and a high sensitivity needed to detect line emission from the gap.
HH 212 is one of the well-studied protostellar systems, showing the first vertically resolved disk with a warm atmosphere around the central protostar. Here we report a detection of nine organic ...molecules (including newly detected ketene, formic acid, deuterated acetonitrile, methyl formate, and ethanol) in the disk atmosphere, confirming that the disk atmosphere is, for HH 212, the chemically rich component, identified before at a lower resolution as a "hot corino." More importantly, we report the first systematic survey and abundance measurement of organic molecules in the disk atmosphere within ∼40 au of the central protostar. The relative abundances of these molecules are similar to those in the hot corinos around other protostars and in Comet Lovejoy. These molecules can be either (i) originally formed on icy grains and then desorbed into gas phase or (ii) quickly formed in the gas phase using simpler species ejected from the dust mantles. The abundances and spatial distributions of the molecules provide strong constraints on models of their formation and transport in star formation. These molecules are expected to form even more complex organic molecules needed for life and deeper observations are needed to find them.
In contrast to the wealth of asymmetric transformations for generating central chirality from alkyl radicals, the enantiocontrol over the allenyl radicals for forging axial chirality represents an ...uncharted domain. The challenge arises from the unique elongated linear configuration of the allenyl radicals that necessitates the stereo‐differentiation of remote motifs away from the radical reaction site. We herein describe a copper‐catalyzed asymmetric radical 1,4‐carboalkynylation of 1,3‐enynes via the coupling of allenyl radicals with terminal alkynes, providing diverse synthetically challenging tetrasubstituted chiral allenes. A chiral N,N,P‐ligand is crucial for both the reaction initiation and the enantiocontrol over the highly reactive allenyl radicals. The reaction features a broad substrate scope, covering a variety of (hetero)aryl and alkyl alkynes and 1,3‐enynes as well as radical precursors with excellent functional group tolerance.
A copper‐catalyzed asymmetric radical 1,4‐carboalkynylation of 1,3‐enynes is realized, providing diverse tetrasubstituted chiral allenes. The utilization of the copper/chiral N,N,P‐ligand is crucial for the enantiocontrol over the allenyl radicals, which is difficult due to their elongated linear configuration that necessitates the stereo‐differentiation of remote motifs away from the reaction site.
The existence of universal quantum computers has been theoretically well established. However, building up a real quantum computer system not only relies on the theory of universality, but also needs ...methods to satisfy requirements on other features, such as programmability, modularity, scalability, etc. To this end, here we study the recently proposed model of quantum von Neumann architecture by putting it in a practical and broader setting, namely, the hierarchical design of a computer system. We analyze the structures of quantum CPU and quantum control units and draw their connections with computational advantages. We also point out that a recent demonstration of our model would require less than 20 qubits.
The morphological properties of the outflowing circumstellar envelopes surrounding mass-losing stars in eccentric binary systems are presented based upon the results from a set of three-dimensional ...hydrodynamical model simulations. Making use of four template models of the envelope viewed for a range of inclination angles of the systems, we implement interpretative tools for observations at high spectral/angular resolutions (as illustrated via velocity-channel maps as well as position-velocity, radius-velocity, and angle-radius diagrams). Within this framework, the image and kinematical structures can be used to place constraints on the orbital parameters of the system. Specifically, three unique characteristic patterns in the envelopes are found that distinguish these systems from those in binary systems in circular orbits. Bifurcation of the spiral pattern, asymmetry in the interarm density depression, and a concurrent spiral/ring appearance all point to a binary system with an eccentric orbit. The methodology presented in this paper is illustrated in an analysis of recent radio observations of several asymptotic giant branch stars.
Abstract
The presence of complex organic molecules (COMs) in the interstellar medium is of great interest since it may link to the origin and prevalence of life in the universe. Aiming to investigate ...the occurrence of COMs and their possible origins, we conducted a chemical census toward a sample of protostellar cores as part of the Atacama Large Millimeter/submillimeter Array Survey of Orion Planck Galactic Cold Clumps project. We report the detection of 11 hot corino sources, which exhibit compact emissions from warm and abundant COMs, among 56 Class 0/I protostellar cores. All of the hot corino sources discovered are likely Class 0, and their sizes of the warm region (>100 K) are comparable to 100 au. The luminosity of the hot corino sources exhibits positive correlations with the total number of methanol and the extent of its emissions. Such correlations are consistent with the thermal desorption picture for the presence of hot corinos and suggest that the lower-luminosity (Class 0) sources likely have a smaller region with COM emissions. With the same sample selection method and detection criteria being applied, the detection rates of the warm methanol in the Orion cloud (15/37) and the Perseus cloud (28/50) are statistically similar when the cloud distances and the limited sample size are considered. Observing the same set of COM transitions will bring a more informative comparison between the cloud properties.
Abstract
Investigating the temperature and density structures of gas in massive protoclusters is crucial for understanding the chemical properties therein. In this study, we present observations of ...the continuum and thioformaldehyde (H
2
CS) lines at 345 GHz of 11 massive protoclusters using the Atacama Large Millimeter/submillimeter Array telescope. High spatial resolution and sensitivity observations have detected 145 continuum cores from the 11 sources. H
2
CS line transitions are observed in 72 out of 145 cores, including line-rich cores, warm cores, and cold cores. The H
2
column densities of the 72 cores are estimated from the continuum emission, which are larger than the density threshold value for star formation, suggesting that H
2
CS can be widely distributed in star-forming cores with different physical environments. The rotation temperature and column density of H
2
CS are derived using the XCLASS software. The results show that the H
2
CS abundances increase as temperature rises and higher gas temperatures are usually associated with higher H
2
CS column densities. The abundances of H
2
CS are positively correlated with its column density, suggesting that the H
2
CS abundances are enhanced from cold cores, warm cores, and line-rich cores in star-forming regions.
Abstract
We present Atacama Large Millimeter/submillimeter Array subarcsecond-resolution observations of both continuum and molecular lines at 345 GHz toward the massive star-forming region IRAS ...16351-4722 (hereafter I16351). A total of 12 dust cores were detected based on high-spatial-resolution observations of the continuum. Among them, a high-mass core (11.6
M
⊙
) and a low-mass core (1.7
M
⊙
) show abundant molecular line emissions. 164 molecular transitions from 29 species and 104 molecular transitions from 25 species are identified in the high-mass and low-mass cores, respectively. Complex organic molecules (COMs) such as CH
3
OH, CH
3
OCHO, CH
3
OCH
3
, C
2
H
5
OH, and C
2
H
5
CN are detected in the two cores. Under the assumption of local thermodynamic equilibrium, the rotational temperatures and column densities of the COMs are derived with the XCLASS software. The maximum rotation temperature values in the low-mass core and the high-mass core were found to be approximately 130 K and 198 K, respectively. Additionally, the line widths in the high-mass core are larger than those in the low-mass one. The abundant COM line transitions, high gas temperatures, and smaller line widths indicate the presence of a low-mass line-rich core in the massive star formation region for the first time, while the high-mass line-rich core shows hot core properties. When comparing the molecular abundances of CH
3
OH, CH
3
OCHO, CH
3
OCH
3
, and C
2
H
5
OH of the two cores with other hot cores and hot corinos reported in the literature, we further confirm that both a hot core and a low-mass line-rich core are simultaneously detected in I16351.
Potassium ion batteries (KIBs) have emerged as a promising energy storage system, but the stability and high rate capability of their electrode materials, particularly carbon as the most investigated ...anode ones, become a primary challenge. Here, it is identified that pitch‐derived soft carbon, a nongraphitic carbonaceous species which is paid less attention in the battery field, holds special advantage in KIB anodes. The structural flexibility of soft carbon makes it convenient to tune its crystallization degree, thereby modulating the storage behavior of large‐sized K+ in the turbostratic carbon lattices to satisfy the need in structural resilience, low‐voltage feature, and high transportation kinetics. It is confirmed that a simple thermal control can produce structurally optimized soft carbon that has much better battery performance than its widely reported carbon counterparts such as graphite and hard carbon. The findings highlight the potential of soft carbon as an interesting category suitable for high‐performance KIB electrode and provide insights for understanding the complicated K+ storage mechanisms in KIBs.
The cycling stability of anode materials in potassium‐ion batteries (KIBs) is challenged by the large size of K+ itself. The findings not only demonstrate the promising potential of soft carbon as a category suitable for high‐performance KIB electrodes, but also provide insights into the complicated K+ storage mechanisms in carbon anodes of KIBs.
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