Increasing exploration interest in oil and gas hosted by early Cambrian strata has focused research efforts on early Cambrian sandstones. The origin of phosphorus and the paleoenvironment of ...phosphorus-bearing sandstones from the Xinji Formation are discussed in this paper. X-ray diffraction, optical microscopy, grain size analysis, total organic carbon, and the concentrations of major, trace, and rare earth elements (REEs) are analyzed in this work. The sandstones are mostly sublitharenite with calcareous cement. The content of the sandstone samples is quartz (39.8%-73.9%), with illite (7.9%-27.6%) and calcite (4.5%-29%). The mineral particles of sandstone samples are mainly well sorted with a fine particle size, suggesting strong paleohydrodynamic force. The value of SiO2 is 37.69%-78.19%, followed by Al2O3 (6.11%-13.67%). Compared with upper continental crust, the boron in the sandstone samples is relatively enriched, whereas Sc, Sr, and Ba are relatively depleted. The ΣREE content is 124.46-323.99 ppm. Phosphorus is of biogenic origin and enriched by upwelling current. The source of the Xinji Formation sandstone samples was mainly a mixture of sedimentary rock, granite, and alkali basalt, with the provenance of terrestrial clastic materials. The sandstone was deposited under oxic conditions and a warm and humid paleoclimate with saline to brackish features on a passive continental margin. Phosphorus occurring in sandstones is sensitive to paleoclimate and can be used as an indicator to judge paleoclimate, as it is more enriched in warm and humid weather.
Individuals' knowledge hiding behavior may lead to massive economic losses to organizations, and exploring the antecedents of it has crucial relevance for mitigating its negative influences. This ...research aims to investigate the impact of perceived overqualification on knowledge hiding by testing the mediating effect of psychological capital and the moderating effect of person-organization fit. Empirical analyses were conducted on 249 employee dataset using versions SPSS 26 and AMOS 26. Results illustrate an inverse correlation between perceived overqualification and knowledge hiding behavior which is partly mediated by psychological capital and moderated by person-organization fit, implying that good organizational atmosphere that builds up individual psychological capital with better person-organization fit will allow employees to work positively to reduce knowledge hiding behavior when perceived overqualified. This study complements a small quantity of discussions on the positive impact of perceived overqualification on knowledge management and fills omissions in previous studies on the negative effect of perceived overqualification on knowledge hiding behavior in changing surroundings.
The southwestern margin of the North China Craton (NCC) is located between the Alxa Terrane to the northwest, the North Qilian Orogen to the west and the North Qinling Orogen to the south. However, ...the paleogeographic and tectonic evolution for the southwestern part of the NCC in the Late Paleozoic is still poorly constrained. In order to constrain the Late Paleozoic tectonic evolution of the southwestern NCC, we carried out detailed field work and detrital zircon U-Pb geochronological research on Middle–Late Permian sedimentary rocks at the southwestern margin of the NCC. The U-Pb age spectra of detrital zircons from six samples are similar, showing four populations of 2.6–2.4 Ga, 2.0–1.7 Ga, 500–360 Ma and 350–250 Ma. Moreover, on the basis of the weighted-mean age of the youngest detrital zircons (257 ± 4 Ma), combined with the published results and volcanic interlayers, we propose that the Shangshihezi Formation formed during the Middle–Late Permian. Our results and published data indicate that the detrital zircons with age groups of 2.6–2.4 Ga and 2.0–1.7 Ga were likely derived from the Khondalite Belt and Yinshan Block in the northwestern NCC. The junction part between the North Qinling and North Qilian Orogen may provide the 500–360 Ma detrital zircons for the study area. The 350–250 Ma detrital zircons were probably derived from the northwestern part of the NCC. The majority of materials from Shangshihezi Formation within the study area were derived from the northwestern part of the NCC, indicating that the northwestern part of the NCC was strongly uplifted possibly resulting from the progressive subduction and closure of the Paleo-Asian Ocean. A small amount of materials were sourced from southwestern part of the NCC, indicating that the North Qinling Orogen experienced a minor uplift resulting from the northward subduction of the South Qinling terrane.
•Limiting the maximum depositional timing of the Shangshihezi Fm (~257 Ma)•Determining the well mixed sources of the Shangshihezi Fm•Northwestern NCC experienced strong uplift during the Middle–Late Permian.
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The evaluation of sustainable land use is the key issue in the field of studying the sustainable land utilization. In general analysis, the sustainable land use is evaluated respectively from its ...ecological sustainability, economic sustainability and social sustainability in China and other countries in recent years. Although this evaluation is an important work, it seems insufficient and hard to comprehensively reflect the whole degree of land use sustainability. Thus, to make up this deficiency, this paper brings forward the evaluation indexes, which make it possible to quantitatively reflect the whole degree of land use sustainability, namely, the concept of ＂degrees of overall land use sustainability＂ （Dos）, and research and measurement development of the method of and calculation in Dos. Taking the evaluation of the degree of land use sustainability in county regions of Yunnan Province as the actual example for analysis, results are basically as follows：
1） The degree of land use sustainability （Dos） is the ration index to organically and systematically integrate the degree of ecological friendliness （DeF）, the degree of economic viability （Dev） and the degree of social acceptability （Dsa）, able to comprehensively reflect the whole sustainability degree of regional land use
2） Based on the value of Dos, the grading system and standard for the sustainability of land use may be established and totally divided into five grades, namely, the high-degree sustainability, middle-degree sustainability, low-degree sustainability, conditional sustainability and non-sustainability. Meanwhile, the standard for distinguishing sustainability grades has also been confirmed so as to determine the nature of sustainability degrees in different grades. This makes the possibility for the combination of nature determination with ration in research result and provides with the scientific guideline and decision-making gist for better implementation of sustainable land use strategy.
3） The practice in evaluation of sustainability degree in county regional land use in Yunnan shows that the value of the degree of land use sustainability （Dos） of whole Yunnan Province is only 58.39, belonging to the grade of low-degree sustainability. Two thirds of counties in the whole province represent the grade of ＂conditional sustainability＂ and ＂non-sustainability＂ in the sustainability of land use. Among these counties, 11.11 % shows ＂non- sustainability＇. The lowest degree of land use sustainability appears especially in the middle plateau mountain region of Northeast Yunnan, where the value of Dos in most counties （districts） is below 40 %, belonging to the grade of ＂non-sustainability＂. The sustainability degree in the karst mountainous region in lower-middle plateau mountain region in Southeast Yunnan is generally low and the value of sustainability degree （Dos） in most of the counties （cities and districts） is below 55. The value of sustainability degree （Dos） in most of the counties （cities and districts） in the north, west, northwest and southwest parts of Yunnan is below 55. This article also analyzes the reasons of low degree of sustainability in land use in Yunnan and puts forward the countermeasures to increase the degree of sustainability in land use in the whole province.
The Chang 7 oil layer in Yanhe Profile develops comprehensive fine-grained sediments, showing great significance to hydrocarbon exploration. Based on nineteen samples, organic elements, maceral ...identification, vitrinite reflectance (Ro), biomarkers and inorganic elements were tested. The results show that the fine-grain sediments have relatively high clay minerals and are mainly silicate and clay source rocks, showing good-excellent source rock quality at the bottom with the decreasing quality towards the top. The rock pyrolysis, maceral identification and Ro imply that the organic matter (OM) type is Type II with plankton and bacterials as the main organic origin, entering maturity stage. Biomarkers, major and trace elements manifest that the fine-grain sediments deposited in weak oxidizing-weak reducing environment with fresh water. The diagrams of OEP-CPI and C29steraneββ(ββ+αα)-αααC29sterane 20S(20R + 20S) also reflect the maturity stage of organic matter. The Al/Si ratios are relatively big, implying the clay minerals content is high. This is in accordance with XRD analyses. Trace elements results demonstrate the high paleoproductivity, fresh water, and cold and dry weather. The increasing salinity, anoxic condition, and warm and humid climate are in favor of OM enrichment and preservation. This contribution provides systematic geologic foundation for hydrocarbon exploration and development of fine-grained sediments in Ordos Basin.
•The fine-grain sediments are mainly silicate and clay source rock type.•The organic matter origin is dominated by plankton and bacterials.•The sedimentary water is fresh water without thermal fluid activities.•The redox shows an increasing trend of oxidation intensity from anoxic at the bottom.•The paleo-climate tending warm and hot facilitates organic matter enrichment.
Particle number size distribution from 10 to 10,000 nm was measured by a wide-range particle spectrometer （WPS-1000XP） at a downwind site north of downtown Lanzhou, western China, from 25 june to 19 ...July 2006. We first report the pollution level, diurnal variation of particle concentration in different size ranges and then introduce the characteristics of the particle formation processes, to show that the number concentration of ultrafine particles was lower than the values measured in other urban or suburban areas in previous studies, However, the fraction of ultrafine particles in total aerosol number concentration was found to be much higher. Furthermore, sharp increase of ultrafine particle concentration was frequently observed at noon. An examination of the diurnal pattern suggests that the burst of the ultrafine particles was mainly due to nucleation process. During the 25-day observation, new particle formation （NPF） from homogeneous nucleation was observed during 33% of the study period. The average growth rate of the newly formed particles was 4.4 nm/h, varying from 1.3 to 16,9 nm/h. The needed concentration of condensable vapor was 6.1 × 10^7 cm-3, and its source rate was 1.1× 10^6 cm-3 s 1. Further calculation on the source rate of sulphuric acid vapor indicated that the average participation of sulphuric acid to particle growth rate was 68.3%.
An observational study on trace gases and PM2.5 was conducted at three sites in and around Beijing, during the Olympic season from 2007 to 2009. Air quality improved significantly during the Olympic ...Games due to the special emission control measures. However, concentrations of the primary pollutants and PM were found to have risen significantly after the Games. Although the major O3 precursors （NOx and VOCs） were well controlled during the Olympic season, O3 was still found to be the highest in 2008, based on the data of ground-based observation. All this information suggests that while control of regional emissions for the Beijing Olympic Games did improved the air quality in Beijing, more efforts will be needed for the continuous improvement of regional air quality, especially for significant reductions of O3 and fine particulate pollution, and not only in Beijing, but also in the B eijing-Tianjin-Hebei region.
Toxic elements in the atmosphere can enter and accumulate in the human body, seriously impacting human health. In this study, we analyzed a 14-year （1995-2008） measurement of three toxic elements ...（As, Cd and Cr） in PMlo in Hong Kong, China. The pollution of these toxic elements in Hong Kong was not serious. The trend analysis showed that As and Cr in PM10 increased at a statistically significant level （p〈0.05） during the 14-year period, while the Cd in PM10 did not change significantly. Typical seasonal variations were observed for all three toxic elements, largely in relation to the Asian monsoon. Hourly 10-day backward trajectories were computed and cate- gorised into four groups. The continental air masses showed much higher concentrations of the three toxic elements than the marine air masses. The abundances of As and Cd in the PM10 were much higher in the continental air masses than those in the marine air masses, while the abundances of Cr showed an opposite pattern. The trends of the three toxic elements in East China＇s air mass were consistent with those in the overall data set ofHong Kong. Examination of the toxic element data recorded at urban sites and a roadside site also indicated a large contribution of external air masses to particulate As and Cd in Hong Kong. These results suggest that the long-range transport from the mainland of China is the dominant contributor to particulate As and Cd, while both local and long-distance sources determine the particulate Cr in Hong Kong.
Cannabinoid receptor type 2 (CB
2
) activation is recently reported to promote proliferation of some types of resident stem cells (e.g., hematopoietic stem/progenitor cell or neural progenitor cell). ...Resident cardiac progenitor cell (CPC) activation and proliferation are crucial for endogenous cardiac regeneration and cardiac repair after myocardial infarction (MI). This study aims to explore the role and possible mechanisms of CB
2
receptor activation in enhancing myocardial repair. Our results revealed that CB2 receptor agonist AM1241 can significantly increase CPCs by c-kit and Runx1 staining in ischemic myocardium as well as improve cardiomyocyte proliferation. AM1241 also decreased serum levels of MDA, TNF-α and IL-6 after MI. In addition, AM1241 can ameliorate left ventricular ejection fraction and fractional shortening, and reduce fibrosis. Moreover, AM1241 treatment markedly increased p-Akt and HO-1 expression, and promoted Nrf-2 nuclear translocation. However, PI3K inhibitor wortmannin eliminated these cardioprotective roles of AM1241. In conclusion, AM1241 could induce myocardial regeneration and improve cardiac function, which might be associated with PI3K/Akt/Nrf2 signaling pathway activation. Our findings may provide a promising strategy for cardiac endogenous regeneration after MI.
Peroxyacetyl nitrate （PAN） is an important indicator of photochemical smog and has adverse effects on human health and vegetation growth. A rapid and h!ghly selective technique of thermal ...dissociation chemical ionization mass spectrometry （TD-CIMS） was recently developed to measure the abundance of PAN in real time; however, it may be subject to artifact in the presence of nitric oxide （NO）. In this study, we tested the interference of the PAN signal induced by NO, evaluated the performance of TD- CIMS in an urban environment, and investigated the concentration and formation of PAN in urban Hong Kong. NO caused a significant underestimation of the PAN signal in TD-CIMS, with the underestimation increasing sharply with NO concentration and decreasing slightly with PAN abundance. A formula was derived to link the loss of PAN signal with the concentrations of NO and PAN, which can be used for data correction in PAN measurements. The corrected PAN data from TD- CIMS were consistent with those from the commonly used gas chromatography with electron capture detection, which confirms the utility of TD-CIMS in an urban environment in which NO is abundant. In autumn of 2010, the hourly average PAN mixing ratio varied from 0.06 ppbv to 5.17 ppbv, indicating the occurrence of photochemical pollution in urban Hong Kong. The tbrmation efficiency of PAN during pollution episodes was as high as 3.9 to 5.9 ppbv per 100 ppbv ozone. The efficiency showed a near-linear increase with NO, concentration, suggesting a control policy of NO,. reduction for PAN pollution.
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