A lattice Boltzmann model with a multiple-relaxation-time (MRT) collision operator for the convection–diffusion equation is presented. The model uses seven discrete velocities in three dimensions ...(D3Q7 model). The off-diagonal components of the relaxation-time matrix, which originate from the rotation of the principal axes, enable us to take into account full anisotropy of diffusion. An asymptotic analysis of the model equation with boundary rules for the Dirichlet and Neumann-type (specified flux) conditions is carried out to show that the model is first- and second-order accurate in time and space, respectively. The results of the analysis are verified by several numerical examples. It is also shown numerically that the error of the MRT model is less sensitive to the variation of the relaxation-time coefficients than that of the classical BGK model. In addition, an alternative treatment for the Neumann-type boundary condition that improves the accuracy on a curved boundary is presented along with a numerical example of a spherical boundary.
We introduce the free analogue of the classical beta prime distribution by the multiplicative free convolution of the free Poisson and the reciprocal of free Poisson distributions, and related free ...analogues of the classical
F
,
T
, and beta distributions. We show the rationales of our free analogues via the score functions and the potentials. We calculate the moments of the free beta prime distribution explicitly in combinatorial fashion by using non-crossing linked partitions and demonstrate that the free beta prime distribution belongs to the class of the free negative binomials in the free Meixner family.
O3-type NaFeO2 is a promising candidate as positive electrode materials for rechargeable Na batteries. However, its reversible range of sodium extraction is relatively narrow (x=ca. 0.4 in Na1−xFeO2) ...because of the irreversible structural change, presumably associated with the iron migration into the adjacent tetrahedral sites in Na layers as we recently reported. Herein, we report that cobalt-substituted NaFeO2 demonstrates excellent electrode performance in a non-aqueous Na cell at room temperature. NaFe0.5Co0.5O2 delivers approximately 160mAhg−1 of reversible capacity with relatively good capacity retention and excellent rate-capability in a voltage range of 2.5–4.0V, resulting in reversible formation of Na0.3Fe0.5Co0.5O2. The partial substitution of metal element for Fe in O3-type NaFeO2-based materials is proved to be the important strategy to suppress the irreversible phase transition, and thus improving the reversibility of sodium removal/insertion as the electrode materials.
•Synthesis and characterizations of layered NaFe0.5Co0.5O2.•Its electrode performance in Na cell was compared with those of NaFeO2 and NaCoO2.•NaxFe0.5Co0.5O2 is one of the highest power positive electrodes among layered oxides.
Single phase, well-crystallized O3-type NaFeO2 (alpha NaFeO2) is prepared by a solid-state method. Electrode performance of O3-type NaFeO2 is examined as positive electrode materials for rechargeable ...sodium batteries. O3-type NaFeO2 can deliver 80–100 mAh g−1 of reversible capacity with a nearly flat voltage profile at approximately 3.3 V vs. Na metal. The electrode performance is significantly deteriorated by oxidation beyond x > 0.5 in Na1−xFeO2. X-ray diffraction study reveals that loss of electrode reversibility originates from irreversible structural change, possibly accompanied by iron ion migration in layered host structures. The sodium ion insertion into the host structures would be disturbed by the irreversible structural change when charged beyond x > 0.5 in Na1−xFeO2. Acceptable cyclability is, therefore, achieved for O3-type NaFeO2 as the positive electrode materials in the limited composition of x = 0–0.45 in Na1−xFeO2.
The spread of intelligent transportation systems in urban cities has caused heavy computational loads, requiring a novel architecture for managing large-scale traffic. In this study, we develop a ...method for globally controlling traffic signals arranged on a square lattice by means of a quantum annealing machine, namely the D-Wave quantum annealer. We first formulate a signal optimization problem that minimizes the imbalance of traffic flows in two orthogonal directions. Then we reformulate this problem as an Ising Hamiltonian, which is compatible with quantum annealers. The new control method is compared with a conventional local control method for a large 50-by-50 city, and the results exhibit the superiority of our global control method in suppressing traffic imbalance over wide parameter ranges. Furthermore, the solutions to the global control method obtained with the quantum annealing machine are better than those obtained with conventional simulated annealing. In addition, we prove analytically that the local and the global control methods converge at the limit where cars have equal probabilities for turning and going straight. These results are verified with numerical experiments.
The D-Wave quantum annealer has emerged as a novel computational architecture that is attracting significant interest, but there have been only a few practical algorithms exploiting the power of ...quantum annealers. Here we present a model predictive control (MPC) algorithm using a quantum annealer for a system allowing a finite number of input values. Such an MPC problem is classified as a non-deterministic polynomial-time-hard combinatorial problem, and thus real-time sequential optimization is difficult to obtain with conventional computational systems. We circumvent this difficulty by converting the original MPC problem into a quadratic unconstrained binary optimization problem, which is then solved by the D-Wave quantum annealer. Two practical applications, namely stabilization of a spring-mass-damper system and dynamic audio quantization, are demonstrated. For both, the D-Wave method exhibits better performance than the classical simulated annealing method. Our results suggest new applications of quantum annealers in the direction of dynamic control problems.
Carbon materials have unveiled outstanding properties as membranes for water transport, both in 1D carbon nanotube and between 2D graphene layers. In the ultimate confinement, water properties ...however strongly deviate from the continuum, showing exotic properties with numerous counterparts in fields ranging from nanotribology to biology. Here, by means of molecular dynamics, we show a self-organized inhomogeneous structure of water confined between graphene sheets, whereby the very strong localization of water defeats the energy cost for bending the graphene sheets. This leads to a two-dimensional water droplet accompanied by localized graphene ripples, which we call "dripplon." Additional osmotic effects originating in dissolved impurities are shown to further stabilize the dripplon. Our analysis also reveals a counterintuitive superfast dynamics of the dripplons, comparable to that of individual water molecules. They move like a (nano-) ruck in a rug, with water molecules and carbon atoms exchanging rapidly across the dripplon interface.
Microgels are soft, adaptive materials exhibiting various properties not only like hydrogels and microparticles but also like macromolecules, colloids, and surfactants. To widen the range of their ...biomedical and environmental applications, the exploration of an alternative for poly(N-alkylacrylamide)s without potential safety risks is of great importance. In this article, thermoresponsive poly(N-vinylisobutyramide) (PNVIBA) microgels of uniform size were synthesized with NVIBA as a monomer and N,N′-5-oxanonamethyene-bis-N-vinylacetamide as a cross-linker in the presence of sodium dodecyl sulfate by aqueous free radical precipitation polymerization. The introduction of cationic groups into PNVIBA microgels was also accomplished using N-vinylformamide (NVF) as a comonomer and the subsequent conversion of NVF into vinylamine by hydrolysis.
DNA methylation is globally reprogrammed during mammalian preimplantation development, which is critical for normal development. Recent reduced representation bisulfite sequencing (RRBS) studies ...suggest that the methylome dynamics are essentially conserved between human and mouse early embryos. RRBS is known to cover 5-10% of all genomic CpGs, favoring those contained within CpG-rich regions. To obtain an unbiased and more complete representation of the methylome during early human development, we performed whole genome bisulfite sequencing of human gametes and blastocysts that covered>70% of all genomic CpGs. We found that the maternal genome was demethylated to a much lesser extent in human blastocysts than in mouse blastocysts, which could contribute to an increased number of imprinted differentially methylated regions in the human genome. Global demethylation of the paternal genome was confirmed, but SINE-VNTR-Alu elements and some other tandem repeat-containing regions were found to be specifically protected from this global demethylation. Furthermore, centromeric satellite repeats were hypermethylated in human oocytes but not in mouse oocytes, which might be explained by differential expression of de novo DNA methyltransferases. These data highlight both conserved and species-specific regulation of DNA methylation during early mammalian development. Our work provides further information critical for understanding the epigenetic processes underlying differentiation and pluripotency during early human development.