Hybrid inorganic-organic perovskites have proven to be a revolutionary material for low-cost photovoltaic applications. They also exhibit many other interesting properties, including giant Rashba ...splitting, large-radius Wannier excitons, and novel magneto-optical effects. Understanding these properties as well as the detailed mechanism of photovoltaics requires a reliable and accessible electronic structure, on which models of transport, excitonic, and magneto-optical properties can be efficiently developed. Here we construct an effective-mass model for the hybrid perovskites based on the group theory, experiment, and first-principles calculations. Using this model, we relate the Rashba splitting with the inversion-asymmetry parameter in the tetragonal perovskites, evaluate anisotropic g-factors for both conduction and valence bands, and elucidate the magnetic-field effect on photoluminescence and its dependence on the intensity of photoexcitation. The diamagnetic effect of exciton is calculated for an arbitrarily strong magnetic field. The pronounced excitonic peak emerged at intermediate magnetic fields in cyclotron resonance is assigned to the 3D±2 states, whose splitting can be used to estimate the difference in the effective masses of electron and hole.
Abstract The aim of this study was to identify the risk factors for free flap failure after head and neck reconstructive surgery. The data of 881 consecutive patients who underwent free flap surgery ...at the Department of Oral and Maxillofacial Surgery, Peking University School and Hospital of Stomatology, between January 2013 and November 2016, were reviewed retrospectively. All surgeries were performed by a single head and neck surgical team. Patient demographic and surgical data that may have an influence on free flap outcomes were recorded. The χ2 test and multivariate logistic regression analysis were used to identify relevant risk factors. In total, 881 free tissue transfer surgeries were included in this study. Free flap failure occurred in 26 of 881 flaps (2.9%). A history of irradiation (odds ratio 0.205, 95% confidence interval 0.07–0.56; P = 0.002) was a statistically significant risk factor for free flap failure. Age, diabetes mellitus, history of previous neck surgery to the anastomosis side, donor site, choice of recipient vein, use of a coupler device, and postoperative anticoagulation were not associated with free flap outcomes. Thus, it is concluded that when performing head and neck reconstructive surgery, special attention should be paid to patients who have previously undergone irradiation.
We investigated the effect of international collaboration (in the form of international co-authorship) on the impact of publications of young universities (<50 years old), and compared to that of ...renowned old universities (>100 years old). The following impact indicators are used in this study, they are: (1) the 5-year citations per paper (CPP) data, (2) the international co-authorship rate, (3) the CPP differential between publications with and without international co-authorships, and (4) the difference between the percentage of international co-authored publications falling in the global top 10 % highly cited publications and the percentage of overall publications falling in the global top 10 % highly cited publications (Δ%
Top10%
). The increment of 5-year (2010–2014) field weighted citation impact (FWCI) of internationally co-authored papers over the 5-year overall FWCI of the institutions in SciVal
®
is used as another indicator to eliminate the effect of discipline difference in citation rate. The results show that, for most top institutions, the difference between the citations per paper (CPP) for their publications with and without international co-authorship is positive, with increase of up to 5.0 citations per paper over the period 1996–2003. Yet, for some Asian institutions, by attracting a lot of researchers with international background and making these collaborating “external” authors as internal researchers, these institutions have created a special kind of international collaboration that are not expressed in co-authorship, and the CPP gaps between publications with and without international co-authorship are relatively small (around 0–1 citations per paper increment) for these institutions. The top old institutions have higher CPP than young institutions, and higher annual research expenditures; while young universities have a higher relative CPP increment for the current 5-year period over the previous 5-year period. The Δ%
Top10%
for international co-authored publications is generally higher than that for all journal publications of the same institution. With the increase of international co-authorship ratio, the mean geographical collaboration distance (MGCD, an indication of increased international co-authorship) of one institution based on the Leiden Ranking data also increases, and young institutions have relatively higher CPP increment over MGCD increment. International co-authorship has a positive contribution to the FWCI of the institution, yet there are untapped potential to enhance the collaboration among young institutions.
Many layered materials can be cleaved down to individual atomic planes, similar to graphene, but only a small minority of them are stable under ambient conditions. The rest react and decompose in ...air, which has severely hindered their investigation and potential applications. Here we introduce a remedial approach based on cleavage, transfer, alignment, and encapsulation of air-sensitive crystals, all inside a controlled inert atmosphere. To illustrate the technology, we choose two archetypal two-dimensional crystals that are of intense scientific interest but are unstable in air: black phosphorus and niobium diselenide. Our field-effect devices made from their monolayers are conductive and fully stable under ambient conditions, which is in contrast to the counterparts processed in air. NbSe2 remains superconducting down to the monolayer thickness. Starting with a trilayer, phosphorene devices reach sufficiently high mobilities to exhibit Landau quantization. The approach offers a venue to significantly expand the range of experimentally accessible two-dimensional crystals and their heterostructures.
An archetypical layered topological insulator Bi2Se3 becomes superconductive upon doping with Sr, Nb or Cu. Superconducting properties of these materials in the presence of in-plane magnetic field ...demonstrate spontaneous symmetry breaking: 180◦-rotation symmetry of superconductivity versus 120◦-rotation symmetry of the crystal. Such behavior brilliantly confirms nematic topological superconductivity. To what extent this nematicity is due to superconducting pairing in these materials, rather than due to crystal structure distortions? This question remains unanswered, because so far no visible deviations from the 3-fold crystal symmetry were resolved in these materials. To address this question we grow high quality single crystals of SrxBi2Se3, perform detailed x-ray diffraction and magnetotransport studies and reveal that the observed superconducting nematicity direction correlates with the direction of small structural distortions in these samples (∼0.02% elongation in one crystallographic direction). Additional anisotropy comes from orientation of the crystallite axes. 2-fold symmetry of magnetoresistance observed in the most uniform crystals well above the critical temperature demonstrates that these structural distortions are nevertheless strong enough. Our data in combination with strong sample-to-sample variation of the superconductive anisotropy parameter are indicative for significance of the structural factor in the apparent nematic superconductivity in SrxBi2Se3.
The present paper deals with the J‐A concept in two‐parameter elastic–plastic approaches of fracture mechanics. The cumulative damage rule in a solid is employed to construct the quantitative ...elastic–plastic J‐A fracture criterion. As a result, the constraint corrected elastic–plastic fracture toughness
JmatC as a function of the crack‐tip constraint parameter A, the yield stress, the strain hardening exponent and the failure stress has been proposed. The significant effect of the strain hardening exponent on the normalized constraint corrected fracture toughness is observed. The value of the normalized constraint corrected fracture toughness decreases with the increase of the applied failure stress and the decrease of the crack aspect ratio to a certain values, and then it stabilizes.
Highlights
The cumulative damage rule in a solid and the J‐A concept are employed.
Quantitative two‐parameter J‐A fracture criterion is proposed.
The constraint corrected fracture toughness is described as a function of crack‐tip constraint.
The effect of the constraint parameter A is analyzed for some standard specimens.
We develop a systematic approach of quantifying spin-orbit coupling (SOC) and a rigorous theory of carrier spin relaxation caused by the SOC in disordered organic solids. The SOC mixes up and down ...spin in the polaron states and can be characterized by an admixture parameter γ2. This mixing effects spin flips as polarons hop from one molecule to another. The spin relaxation time is τ(sf) = R2/(16γ2 D), and the spin diffusion length is L(s) = R/4|γ|, where R is the mean polaron hopping distance and D the carrier diffusion constant. The SOC in tris-(8-hydroxyquinoline) aluminum (Alq3) is particularly strong due to the orthogonal arrangement of the three ligands. The theory quantitatively explains the temperature-dependent spin diffusion in Alq3 from recent muon measurements.
In land plants the cuticle is the outermost layer interacting with the environment. This lipophilic layer comprises the polyester cutin embedded in cuticular wax; and it forms a physical barrier to ...protect plants from desiccation as well as from diverse biotic and abiotic stresses. However, the cuticle is not merely a passive, mechanical shield. The increasing research on plant leaves has addressed the active roles of the plant cuticle in both local and systemic resistance against a variety of plant pathogens. Moreover, the fruit cuticle also serves as an important determinant of fruit defense and quality. It shares features with those of vegetative organs, but also exhibits specific characteristics, the functions of which gain increasing attention in recent years. This review describes multiple roles of plant cuticle during plant-pathogen interactions and its responses to both leaf and fruit pathogens. These include the dynamic changes of plant cuticle during pathogen infection; the crosstalk of cuticle with plant cell wall and diverse hormone signaling pathways for plant disease resistance; and the major biochemical, molecular, and cellular mechanisms that underlie the roles of cuticle during plant-pathogen interactions. Although research developments in the field have greatly advanced our understanding of the roles of plant cuticle in plant defense, there still remain large gaps in our knowledge. Therefore, the challenges thus presented, and future directions of research also are discussed in this review.
We present a detailed analysis of spin-orbit coupling (SOC) in pie-conjugated organic materials and its effects on spin characteristics including the spin-relaxation time, spin-diffusion length, and ...g factor. While pie electrons are responsible for low-energy electrical and optical processes in pie-conjugated organic solids, sigma electrons must be explicitly included to properly describe the SOC. In particular, the g factor is not sensitive to the molecular geometry fluctuations, where the spin mixing within the same orbital is dominant. The SOCs in tris-(-8-hydroxyquinoline) aluminum (Alqsub 3 ) and in copper phthalocyanine (CuPc) are particularly strong, due to the orthogonal arrangement of the three ligands in the former and Cu 3d orbitals in the latter. The theory quantitatively explains the recent measured spin-diffusion lengths in Alqsub 3 from muon spin rotation and in CuPc from spin-polarized two-photon photo-emission.
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