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Electrocatalytic activity and anodic stability of electrodeposited ruthenium-rhodium coatings on titaniumVuković, M... ...The stabilizing effect of rhodium addition to ruthenium coatings on titanium under anodic polarization in acidis solutions is described. The addition of rhodium to the coating leads to both an ... overall improved stability of the electrode, and an increase of the electrochemically active surface area. The service-life of a Rh-Ru coating polarized at 0.12 A cm$^-2$ in 0.5 mol dm$^-3$ sulphuric acid is improved by at least two orders of magnitude, while deterioration of the electroactive surface area never exceeds 30 %. The rotating ring-disc electrode measurements show the dissolution of the coating at potentials above the onset of the oxygen evolution reaction at 1.1 V versus SCE.Source: Journal of Materials Science. - ISSN 0022-2461 (Vol. 34, 1999, str. 869-874)Type of material - article, component part ; adult, seriousPublish date - 1999Language - englishCOBISS.SI-ID - 237663
Author
Vuković, M... |
Marijan, D... |
Čukman, D... |
Pervan, P... |
Milun, Milorad
Topics
electrocatalytic activity |
surface |
rhodium |
ruthenium |
titanium |
titanium |
elektrokatalitično delovanje |
površina |
rodij |
rutenij |
titan
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