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Crystal structure and Mössbauer studies of ▫$Li_1.746Nd_4.494Fe)_9.493$▫Drofenik, Mihael ...The ▫$Li_1.746Nd_4.494FeO_9.493$▫ (LNF) ternary phase, located in the ▫$Li_2O$▫-rich part of the ▫$Li_2O-Nd_2O_3-Fe_2O_3$▫ system, crystallizes with a cubic unit cell of dimension and the space group ... Im3m. Refinement on F resulted in R=1.9%. The structure is comprised of a network of corners, edges and faces sharing the coordination polyhedra of neodymium. In between this skeleton the regular octahedra of oxygen-coordinated iron and trigonal prisms of lithium are located. The Mössbauer spectra revealed the presence of ▫$Fe^3+$▫, ▫$Fe^4+$▫ and ▫$Fe^5+$▫ ions distributed on two symmetry-independent lattice positions.Source: Journal of solid state chemistry. - ISSN 0022-4596 (Vol. 180, 2007, str. 1-6)Type of material - e-articlePublish date - 2007Language - englishCOBISS.SI-ID - 10850838
Author
Drofenik, Mihael |
Ban, Irena |
Makovec, Darko |
Hanžel, Darko |
Golobič, Amalija |
Golič, Ljubo
Topics
crystal structure |
ternary compounds |
single-crystal X-ray diffraction |
Mössbauer spectroscopy |
iron oxidation state |
kristalna struktura |
ternarne spojine |
rentgenska difrakcija |
Mössbauerjeva spektroskopija |
rentgenska strukturna analiza
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Database name | Field | Year |
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Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
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Drofenik, Mihael | 01360 |
Ban, Irena | 08761 |
Makovec, Darko | 10372 |
Hanžel, Darko | 05958 |
Golobič, Amalija | 12624 |
Golič, Ljubo | 00842 |
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