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Sustainable processing of materials using supercritical fluids : doktorska disertacijaBorjan, DraganaSupercritical fluids (SCFs) are powerful solvents with many unique properties. They have great potential for many processes, from extraction to chemical reactions and recycling. Accordingly, phase ... equilibrium data and thermodynamic and transport properties measurements in systems with a supercritical phase, as well as reliable and versatile mathematical models of the phase equilibrium thermodynamics, are needed for the process design and economic feasibility studies. The dissertation focuses on the benefits of supercritical fluid technology and consists of three main sections. The first section includes studies of the phase equilibria of the binary gas-alcohol and gas-urea derivatives. The influence of pressure and temperature on the system behaviour (solubility, viscosity, density, interfacial tension, melting point curve) was investigated. Most of the experiments were carried out with a high-pressure optical view cell, with minor modifications of the apparatus and measurement principle to determine mentioned thermodynamic and transport properties. The second part of the dissertation deals with the recovery of extracts from natural materials. Special interest is oriented towards supercritical fluid extracts, characterised by strong biological activities, especially antimicrobial and antioxidant properties. Supercritical fluid extraction has been performed on a semi-continuous apparatus (at pressures of 150 bar and 250 bar and temperatures of 313.15 K and 333.15 K for oregano extraction; and at pressures of 100 bar and 300 bar and temperatures of 313.15 K and 333.15 K for red beetroot extraction) and various methods such as the microdilution method and the DPPH method were used to determine antimicrobial and antioxidant activity. In the third part, an overview of different methods for recycling carbon fibre reinforced composites is given, including chemical recycling with supercritical fluids. This field has not been well explored, and the approach is relatively new but very interesting from a sustainable point of view. For an economically feasible process design, the thermodynamic and mass transfer data have to be determined. The principles of the future lab- and pilot-scale operations demand these supporting data be known. The results obtained in the frame of this study represent the high added value in the scientific field. They are essential to design and modify processes that yield products that cannot be achieved with conventional production processes.Type of material - dissertation ; adult, seriousPublication and manufacture - Maribor : [D. Borjan], 2022Language - englishCOBISS.SI-ID - 125176835
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Digital Library of the University of Maribor – DLUM
Digitalna knjižnica Slovenije - dLib.siDostop z namenskih računalnikov v prostorih NUK
Author
Borjan, Dragana
Other authors
Knez Marevci, Maša |
Žižović, Irena T.
Topics
Topila |
Univerzitetna in visokošolska dela |
superkritični fluidi |
alkoholi |
fazna ravnotežja |
viskoznost |
gostota |
površinska napetost |
modificirana kapilarna metoda |
metode izolacije |
superkritična ekstrakcija |
farmakološko delovanje |
kompoziti utrjeni z ogljikovimi vlakni |
tehnike recikliranja |
doktorske disertacije |
supercritical fluids |
alcohols |
urea |
phase equilibria |
viscosity |
density |
interfacial tension |
modified capillary method |
isolation methods |
supercritical fluid extraction |
pharmacological activity |
carbon fiber reinforced composites |
recycling techniques
Library | Call number – location, accession no. ... | Copy status |
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Library of Technical Faculties, Maribor | pisarna A-003 (FERI) DD B BORJAN D. Sustainable | available - reading room |
University of Maribor Library | Skladišče II 106394 | available - reading room |
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Database name | Field | Year |
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Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
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Borjan, Dragana | 52081 |
Knez Marevci, Maša | 30021 |
Žižović, Irena T. |
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