Synthesis of an acyltrifluoroborate and its fusion with azides to form amides

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Synthesis of an acyltrifluoroborate and its fusion with azides to form amides

Molander, Gary A; Raushel, Jessica; Ellis, Noel M

Journal of organic chemistry, 2010-Jun-18, Volume: 75, Issue: 12

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A uniquely stable acyl potassium trifluoroborate, potassium (2-phenylacetyl)trifluoroborate, has been synthesized and isolated. In the presence of an activating Lewis acid, this reagent reacts with azides to form amides in good yields.

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Molander, Gary A | Raushel, Jessica | Ellis, Noel M

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