E-resources
Peer reviewed
Open access
-
Lavrova, M. A.; Lunev, A. M.; Goncharenko, V. E.; Taidakov, I. V.; Dolzhenko, V. D.; Belousov, Yu. A.
Russian journal of coordination chemistry, 06/2022, Volume: 48, Issue: 6Journal Article
New complex RuL(Dmdcbp) 2 PF 6 ( I ) is synthesized by the consecutive reactions of Ru- p -cymene 2 Cl 4 with 3,3',5,5'-tetramethyl-1,1'-biphenyl-4,4'-bipyrazole (L) and 4,4'-dicarboxy-2,2'-bipyridine in a methanol–chloroform medium. The composition of complex I is confirmed by NMR and elemental analysis, and the optical and luminescence properties of the complex are studied. Ligand L is characterized for the first time by X-ray diffraction (CIF file CCDC no. 2118676). Quantum chemical calculations in terms of the density functional theory are performed for the interpretation of the absorption and emission spectra. Complex I is promising for using as a photosensitizer.
