Redox-Neutral 1,4-Dicarbonfunctionalization of 1,3-Butadiene by Merging Photoredox and Nickel Catalysis

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Redox-Neutral 1,4-Dicarbonfunctionalization of 1,3-Butadiene by Merging Photoredox and Nickel Catalysis

Ding, Du; Fan, Lian-Feng; Han, Zhi-Yong; Wang, Pu-Sheng

Organic letters, 01/2023, Volume: 25, Issue: 1

Journal Article

The diverse functionalization of 1,3-butadiene provides wide applicability toward the synthesis of abundant and useful allylic compounds. Here, we describe a three-component and redox-neutral assembly of readily available CX compounds, 1,3-butadiene, and various nucleophiles by merging photoredox and nickel catalysis, enabling the rapid synthesis of structurally diverse homoallyl amines and homoallylic alcohols.

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Ding, Du | Fan, Lian-Feng | Han, Zhi-Yong | Wang, Pu-Sheng

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