We present a detailed investigation of the synthesis and mechanical properties of Ti-Al-Nb coatings, formed by alloying of Ti substrates with Al and Nb films by selective electron-beam melting (SEBM) via continuous electron beam. A cycling mixing of pre-deposited bilayer Al/Nb films with a Ti substrate is realized, where the maximum number of the cycles is 3. The first one is a SEBM of a bilayer Al/Nb coating deposited on pure Ti substrate. The obtained after the first cycle specimen is further coated with the same bilayer coating and then subjected to a second SEBM cycle; the same procedure is repeated for the third cycle. The alloyed layers are characterized using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDX), and X-ray Diffraction (XRD). The microhardness is also studied. The thickness of the coatings obtained after each cycle is in the range from 20  μm to 24 μm. The specimen obtained after the first cycle exhibits an alloyed zone consisting of pure Ti with a small content of Al and Nb, while those manufactured by the following cycles represent Ti2AlNb based phases. The microhardness increases from 180 HV0.03 for the pure Ti substrate to 570 HV0.03 after the third cycle. •Ti-Al-Nb alloys were obtained by additive electron beam cycling mixing technique, as the number of the cycles is 3.•The 1st cycle is electron beam melting (EBM) of Ti substrate with a bilayer Al/Nb coating.•The 2nd and 3rd cycles are EBM of the samples obtained by the 1st and 2nd processes with the same bilayer Al/Nb coating.•Ti2AlNb based surface alloy was obtained after the third cycle.•The hardness increases from 180 HV for the pure Ti to about 570 H V after the third cycle.