{1,6}-Transannular Catalytic Asymmetric Gosteli–Claisen Rearrangement

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{1,6}-Transannular Catalytic Asymmetric Gosteli–Claisen Rearrangement

Jaschinski, Tobias; Hiersemann, Martin

Organic letters, 08/2012, Volume: 14, Issue: 16

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The first uncatalyzed and Cu(R-box)L2(SbF6)2-catalyzed {1,6}-transannular Gosteli–Claisen rearrangement of cyclic 2-alkoxycarbonyl-substituted allyl vinyl ethers to afford medium- and large-sized carbacycles is disclosed.

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