The Vibrational Signature of the Aluminum/Polythiophene Interface

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The Vibrational Signature of the Aluminum/Polythiophene Interface

Parente, Vincent; Pourtois, Geoffrey; Lazzaroni, Roberto; Brédas, Jean-Luc; Ruani, Gianpiero; Murgia, Mauro; Zamboni, Roberto

Advanced materials (Weinheim), March, 1998, Volume: 10, Issue: 4

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An understanding and control of metal–polymer interfaces is important for the development of conjugated polymer–based light‐emitting diodes. For example, do interactions at the interface modify the geometric structure and electronic properties of the conjugated system? This question is addressed here by a combined theoretical and experimental approach that has allowed the vibrational properties—which are intimately related to molecular structure and bonding—of interfaces between aluminum and oligothiophenes to be determined.

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