Large electron yields, compared to theoretical predictions, have often been observed in the high-energy part of the electron spectra in collisions of energetic ions with atomic, molecular or solid targets. The relative enhancement of the electron emission yield at high energies can be especially strong in ion–solid collisions. In this work, following a brief overview, recent experimental evidences are presented for Fermi-shuttle type accelerating electron scattering sequences in ion–atom collisions. Signatures for double (projectile–target, P–T), triple (projectile–target–projectile, P–T–P) and quadruple (P–T–P–T) scattering sequences have been found in different collision systems. Our new results indicate the presence of even higher-order scattering contributions in the collisions of few keV energy N + ions with inert gas atoms. The observations support that high-energy electrons produced by accelerating scattering sequences may play a significant role in ion–solid collisions.