Inside Cover: Suppressed Mobility of Negative Charges in Polymer Electrolytes with an Ether‐Functionalized Anion (Angew. Chem. Int. Ed. 35/2019)

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Inside Cover: Suppressed Mobility of Negative Charges in Polymer Electrolytes with an Ether‐Functionalized Anion (Angew. Chem. Int. Ed. 35/2019)

Zhang, Heng; Chen, Fangfang; Lakuntza, Oier; Oteo, Uxue; Qiao, Lixin; Martinez‐Ibañez, Maria; Zhu, Haijin; Carrasco, Javier; Forsyth, Maria; Armand, Michel

Angewandte Chemie International Edition, August 26, 2019, 2019-08-26, Volume: 58, Issue: 35

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Trapping negative charges in polymer electrolytes using a frog‐shaped, ether‐functionalized anion (EFA) is presented by H. Zhang, J. Carrasco, M. Armand, and co‐workers in their Communication on page 12070 ff. The bis(trifluoromethanesulfonyl)imide anion (TFSI), shown as a slippery tadpole, is highly mobile in poly(ethylene oxide) (PEO) matrix. In contrast, the ethylene oxide legs in EFA endow trapping interactions between the anion and PEO, which suppresses mobility (Artwork: Scixel, J. Carrasco, H. Zhang, M. Armand).

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