E-resources
Peer reviewed
-
Orphal, J.; Flaud, J.-M.; Kou, Q.; Tchana, F. Kwabia; Pirali, O.
Journal of molecular structure, 05/2005, Volume: 742, Issue: 1Journal Article
The far infrared absorption spectrum of HOBr has been measured at high resolution between 100 and 400 cm −1 using high-resolution Fourier transform spectroscopy. It was possible to identify not only 1403 pure rotation lines within the vibrational ground state involving levels with rather high K a quantum numbers (up to K a=9) but also 457 pure rotation lines within the first excited vibrational state 3 1 up to K a=7. The ground state lines, combined with 32 microwave transitions available in the literature, were used for a new determination of the rotational constants up to higher orders for both isotopomers HO 79Br and HO 81Br, by least squares fitting of the observed line positions using a Watson-type Hamiltonian for the calculation of rotational energy levels. In the same way the 3 1 rotational lines were fitted together with the few existing microwave transitions and the energy levels derived from the study of the ν 3 band ( J. Orphal, Q. Kou, F. Kwabia Tchana, O. Pirali, and J.-M. Flaud, J. Mol. Spectrosc. 221 (2003), 239–243) leading to an improved set of Hamiltonian constants. Finally relative line intensities were measured and used for the determination of rotational corrections to the b-component of the permanent dipole moment.
![loading ... loading ...](themes/default/img/ajax-loading.gif)
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.