E-resources
Peer reviewed
-
Ou‐Yang, He; Xu, Hou‐Ming; Zhang, Xiao‐Long; Liu, Yu‐Qing; He, Yu‐Qing; Shi, Lei; Gu, Chao; Han, Shi‐Kui
Small (Weinheim an der Bergstrasse, Germany), 09/2022, Volume: 18, Issue: 38Journal Article
The design and synthesis of advanced semiconductors is crucial for the full utilization of solar energy. Herein, colloidal selective‐epitaxial hybrid of tripartite semiconducting sulfides CuInS2Cd(In)SMoS2 heteronanostructures (HNs) via lateral‐ and vertical‐epitaxial growths, followed by cation exchange reactions, are reported. The lateral‐epitaxial CuInS2 and Cd(In)S enable effective visible to near‐infrared (NIR) solar spectrum absorption, and the vertical‐epitaxial ultrathin MoS2 offer sufficient edge sulfur sites for the hydrogen evolution reaction (HER). Furthermore, the integrated structures exhibit unique epitaxial‐staggered type II band alignments for continuous charge separation. They achieve the H2 evolution rate up to 8 mmol h−1 g−1, which is ≈35 times higher than bare CdS and show no deactivation after long‐term cycling, representing one of the most efficient and robust noble‐metal‐free photocatalysts. This design principle and transformation protocol open a new way for creating all‐in‐one multifunctional catalysts in a predictable manner. A wet‐chemical strategy for the selective‐epitaxial hybrid of unique tripartite semiconducting sulfide heteronanostructures CuInS2Cd(In)SMoS2 is reported. The stepwise integrated structures demonstrate superior solar‐to‐hydrogen conversion performance due to the enhanced capabilities for solar absorption and charge separation, together with sufficient catalytically active sites.
Author
Shelf entry
Permalink
- URL:
Impact factor
Access to the JCR database is permitted only to users from Slovenia. Your current IP address is not on the list of IP addresses with access permission, and authentication with the relevant AAI accout is required.
Year | Impact factor | Edition | Category | Classification | ||||
---|---|---|---|---|---|---|---|---|
JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
Select the library membership card:
If the library membership card is not in the list,
add a new one.
DRS, in which the journal is indexed
Database name | Field | Year |
---|
Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
---|
Source: Personal bibliographies
and: SICRIS
The material is available in full text. If you wish to order the material anyway, click the Continue button.