(N-Phosphinoamidinate)cobalt-Catalyzed Hydroboration: Alkene Isomerization Affords Terminal Selectivity

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(N-Phosphinoamidinate)cobalt-Catalyzed Hydroboration: Alkene Isomerization Affords Terminal Selectivity

Ruddy, Adam J.; Sydora, Orson L.; Small, Brooke L.; Stradiotto, Mark; Turculet, Laura

Chemistry : a European journal, October 20, 2014, Volume: 20, Issue: 43

Journal Article

Herein we establish the utility of a three‐coordinate (N‐phosphinoamidinate)cobalt(amido) pre‐catalyst that is capable of effecting challenging alkene isomerization/hydroboration processes at room temperature, leading to the selective terminal addition of the boron group. Chain‐walking hydroborations: A three‐coordinate (N‐phosphinoamidinate)cobalt(amido) pre‐catalyst is capable of effecting challenging alkene isomerization/hydroboration processes at room temperature, leading to the selective terminal addition of the boron group.

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Ruddy, Adam J. | Sydora, Orson L. | Small, Brooke L. | Stradiotto, Mark | Turculet, Laura

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