Methoxy-substituted benzo[b]naphtho[2,1-d]thiophenes and their properties relevant for optoelectronic applications

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Methoxy-substituted benzo[b]naphtho[2,1-d]thiophenes and their properties relevant for optoelectronic applications

Yaltseva, Polina A.; Khoroshutin, Andrey V.; Moiseeva, Anna A.; Tokarev, Sergei D.; Eliseev, Vladislav M.; Aleksandrov, Alexey E.; Tameev, Alexey R.; Anisimov, Alexander V.; Fedorov, Yury V.; Fedorova, Olga A.

Mendeleev communications, September-October 2023, 2023-09-00, Volume: 33, Issue: 5

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Display omitted Two novel aromatic thiophene-containing annulated compounds, viz. 2-methoxybnaphtho2,1-dthiophene and 1,3-dimethoxybnaphtho2,1-dthiophene, were synthesized via the Mallory-type photocyclization. Their optical, redox and photophysical properties have been studied along with phosphorescence spectra and lifetimes at 77 K. The first compound exhibited much higher charge mobility in thin films than the second one suggesting the former being prospective for molecular electronics applications

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