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Vinhal, Jonas O.; Nege, Kassem K.; Lage, Mateus R.; de M. Carneiro, José Walkimar; Lima, Claudio F.; Cassella, Ricardo J.
Ecotoxicology and environmental safety, 11/2017, Volume: 145Journal Article
This work reports a study about the adsorption of the herbicides diquat and difenzoquat from aqueous medium employing polyurethane foam (PUF) as the adsorbent and sodium dodecylsulfate (SDS) as the counter ion. The adsorption efficiency was shown to be dependent on the concentration of SDS in solution, since the formation of an ion-associate between cationic herbicides (diquat and difenzoquat) and anionic dodecylsulfate is a fundamental step of the process. A computational study was carried out to identify the possible structure of the ion-associates that are formed in solution. They are probably formed by three units of dodecylsulfate bound to one unit of diquat, and two units of dodecylsulfate bound to one unit of difenzoquat. The results obtained also showed that 95% of both herbicides present in 45mL of a solution containing 5.5mgL−1 could be retained by 300mg of PUF. The experimental data were well adjusted to the Freundlich isotherm (r2 ≥ 0.95) and to the pseudo-second-order kinetic equation. Also, the application of Morris-Weber and Reichenberg equations indicated that an intraparticle diffusion process is active in the control of adsorption kinetics. •This paper reports the use of low-cost polyurethane foam for the removal of diquat and difenzoquat from water.•Results obtained indicated that dodecylsulfate ion has a fundamental role in the adsorption process.•A possible structure of the ion-associate formed between diquat and difenzoquat and dodecylsulfate is proposed.•The adsorption process followed a pseudo-second-order kinetics.•Quantitative removal of the herbicides by PUF was observed.
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