In the Slovenian part of the Gulf of Trieste/Trst, submarine springs occur as funnel-shaped depressions in the Holocene sandy-silt marine sediment that forms the seafoor. These springs exhibit both ...elevated temperatures (up to 29.6 °C) and sulphur content. Based on their location, they are divided into three groups: the Izola group (three springs), the Bele skale group (two springs), and the Ronek group (seven springs). Previous investigations linked these springs to the Izola anticline, characterized by its limestone core and fysch limbs, but no detailed explanation was provided. We propose that: A) sulphur groundwater springs from the limestone (karstic aquifer) at the stratigraphic boundary with the fysch and B) springs occur in the nearshore area, where the sedimentary cover of Quaternary deposits is thin enough to be penetrated by spring waters and washed out. According to existing data, the anticline axis is NW-SE directed, and the Izola group lies approximately on the seaward extension of the axis. Therefore, this interpretation fts perfectly for the Izola group, while the Ronek and Bele skale groups are of-axis extensions and require reinterpretation. In order to resolve the micro-locations of the Ronek and Bele skale groups, we conducted a sedimentological logging of the fysch deposits and detailed geological mapping. The investigations revealed that: A) limestone outcrops occur only in the town of Izola, B) two prominent calciturbidite megabeds that occur in the fysch enable very detailed geological mapping, and C) the axis of the Izola anticline is oriented in the WNW-ESE direction, and this moderate anti-clockwise rotation of the anticline axis explains the micro-locations of all springs. The Ronek and Bele skale groups are located on the southern side, and the Izola group is on the northern side of the limestone core of the Izola anticline.
The study area is located in cental Slovenia, and geologically located at the junction between the Alps and the Dinarides. The Middle Triassic of this region is characterised by intense rifting ...manifested by differential subsidence and volcanism. This led to a major paleogeographic reorganisation of the region, where three paleogeographic domains formed in the Upper Triassic: The Julian Carbonate Platform in the north, the intermediate Slovenian Basin, both parts of the Southern Alps, and the Dinaric (Adriatic, Friuli) Carbonate Platform in the south, which today is a part of the External Dinarides that host the area of investigation. Prior to the installation of the Dinaric Carbonate Platfrom, i.e. in the Ladinian, the entire area of the preset-day External Dinarides broke up into numerous tectonic blocks that were exposed to either erosion or continental, shallow-marine, and deep-marine sedimentation. In this study, we analyse at small scale a complex transitional area between a local carbonate platform and the Kobilji curek basin (depositional area dominated by deeper marine sediments), located in the Rute Plateau in central Slovenia south of Ljubljana. During enhanced subsidence, the basin was filled with volcanic material (tuffs and volcanogenic clays and subordinate extrusive material), while the adjacent platform aggraded. The slope was positioned above active paleofaults. During relative sea level lowstand, the platform prograded across the basin. The study area is divided into four major tectonic paleoblocks. The NW paleoblock experienced the most enhanced subsidence, and the platform prograded twice in this area and was submerged again by the rejuvenated subsidence and/or sea-level rise. The second and third paleoblocks subsided only during discrete major subsidence events, and the carbonates of the platform and slope were soon reinstated therein. In the fourth paleoblock to the east the platform persisted during the Ladinian. In the Carnian, the entire study area became emerged, and continental clastics were deposited. These were then replaced by a uniform shallow marine/intertidal Hauptdolomit (Dolomia Principale) formation at the onset of the Norian. This study provides the first detailed reconstruction of the sedimentary evolution of small-scale Ladinian basin and platforms system in the northern External Dinarides.
The Bay of Koper is influenced by agricultural, urban, and port activities, therefore pollution from trace metals is a concern. A total of 20 sediment samples obtained from four 10-cm sediment cores ...were analyzed. Element concentration in the sediment of the bay was determined spatially and temporally from the recent surface to depth. The results were correlated with the composition and diversity of the benthic foraminiferal assemblages. Major element concentrations indicate natural lithogenic origin (which is also confirmed by mineralogical features). The benthic foraminiferal assemblages in sediment samples, although mainly composed of representatives of the Rotaliida, show moderate to high species diversity and are dominated by the pollution tolerant species
Ammonia pakinsoniana
,
Haynesina
sp.,
Valvulineria bradyana
and the non-keel
Elphidium
sp. and subordinated by
Ammonia tepida
and
Haynesina depressula
. Canonical correspondence analysis (CCA) on foraminiferal species and trace element concentrations shows a possible control of some potential toxic elements (i.e., Cu, Ni, Pb, Zr, Cr, As) on the diversity and taxonomic composition of foraminiferal assemblages. Nevertheless, foraminiferal diversity and dominance in the bay are related to sediment characteristics such as sediment grain size, and the amount of terrigenous inflow rather than to the element concentrations of sediments. This study evaluated ecological conditions by using the Foram-AMBi and EcoQS indices. The values of the Foram-AMBI index reflect the good to moderate quality of ecological conditions, whereas high to poor ecological statuses were interpreted by calculating EcoQS.
The Julian Alps are composed almost exclusively of Triassic to Lower Jurassic carbonates, which results in a karstified high-alpine landscape. In such settings, large water accumulations are not ...expected and precipitated water drains vertically, gathers in deep, large-scale aquifers, and outflows in large karstic springs located in deeply incised valleys. Some small lakes, however, exist in high alpine areas. Most commonly, they formed above impermeable glacial sediments and are generally characterized by stagnant waters. Jezero v Ledvicah lake, which is one of the seven lakes in the Triglav Lakes Valley, is an exception, because it shows high subaqueous water inflow and outflow and occurs among highly karstified and permeable carbonates. Combining previous research with our new, detailed geological mapping of the lake surroundings and sedimentary research on the Lower Jurassic strata, we propose a hydrogeological model with the aim of explaining the extraordinary behaviour of the lake. We propose that Jezero v Ledvicah lake: A) is part of the "guttershaped" aquifer with perched groundwater that is situated below the floor of the Triglav Lakes Valley; B) barriers of the aquifer are structural (faults and thrust) and stratigraphic (clay interlayers in Lower Jurassic limestone); C) the lake formed in a structural, hydrogeological and morphological depression within this aquifer; D) the groundwater of the aquifer is recharged not solely from the surface directly above the aquifer but additionally by subterraneous inflow from the overlying Slatna Nappe aquifer; and E) groundwater outflows from the aquifer at the southern end of the Triglav Lakes Valley, where the Lower Jurassic limestone pinches out.
In this study, the role of aquaculture activity as a source of selected metals was analyzed. Significant differences in element content between cultured (
Dicentrarchus labrax
,
Sparus aurata
) and ...wild fishes as well as between fish muscle and their feed were detected. Higher concentrations of trace elements (i.e., As, Cu, Hg, Se) in wild fish tissues in comparison with cultured ones indicate additional sources of metals beside fish feed as natural and/or anthropogenic sources. Generally, mean Cd, Cu, Pb, Se, and Zn concentrations in cultured (0.016, 1.79, 0.14, 0.87, and 34.32 μg/g, respectively) and wild (0.011, 1.97, 0.10, 1.78, and 23,54 μg/g, respectively) fish samples were below the permissible levels, while mean As (2.57 μg/g in cultured, 4.77 μg/g in wild) and Cr (5.25 μg/g in cultured, 2.92 μg/g in wild) values exceeded those limits. Hg values were lower in cultured (0.17 μg/g) and higher in wild (1.04 μg/g) fish specimens. The highest elemental concentrations were observed in almost all fish samples from Korčula sampling site. The smallest cultured sea basses showed As (4.01 μg/g), Cr (49.10 μg/g), Pb (0.65 μg/g), and Zn (136 μg/g) concentrations above the recommended limits; however, values decreased as fish size increased. Therefore, the majority of metal concentrations in commercial fishes showed no problems for human consumption. Also calculated Se:Hg molar ratios (all >1) and selenium health benefit values (Se-HBVs) (all positive) showed that consumption of all observed fishes in human nutrition is not risk.
The Marof archaeological site, which dates back to the 1st–5th centuries ce, lies 10 km SE of the Roman settlement of Emona of Regio X (Venetia and Histria). In addition to other artefacts, several ...stone blocks were recovered. The blocks include worked (shaped) and unworked (natural forms) objects. The provenance of these stones was determined based on their lithological characteristics. The analysis shows that the stone is of Early Jurassic age. While the worked blocks are lithologically diverse and extracted from several sources located within a 10 km radius, the unworked blocks are lithologically homogeneous and originate from the site.
We present an integrated approach to characterizing the Žvepovnik sulphur spring, comprising detailed basic geological (mapping), geochemical (physico-chemical, elementary), isotopic (δ2H, δ18O, ...δ13CDIC, δ34S and 3H), and microbiological analyses. We used a multi-parameter approach to determine the origin of the water (meteoric or deeper infiltration), the origin of the carbon and sulphur, and water retention times. Our special research interest is the origin of the sulphur, as sulphur springs are rare and insufficiently investigated. Our results show that the Žvepovnik spring occurs along the fault near the contact between the dolomite aquifer and overlying shales and volcanoclastic beds. The spring water is the result of the mixing of (1) deeper waters in contact with gypsum and anhydrite and (2) shallow waters originating from precipitation and flowing through the surface carbonate aquifer. The results of δ2H and δ18O confirm local modern precipitation as the main source of the spring. δ13CDIC originates from the degradation of organic matter and the dissolution of carbonates. We therefore propose four possible sources of sulphur: (1) the most probable is the dissolution of gypsum/anhydrite; (2) barite may be a minor source of sulphur; (3) the microbial dissimilatory sulfate reduction; and (4) the oxidation of pyrite as the least probable option.
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