From petroleum to bioleum: Since biomass is a limited resource, it is necessary to consider its best use. The production of select chemicals from biomass, rather than its use as fuel, could ...effectively replace the use of petroleum in the chemical industry, but the inherent functionality of biomass must be exploited (see picture).
Chlorides commonly precipitate during the evaporation of surface water or groundwater and during volcanic outgassing. Spectrally distinct surface deposits consistent with chloride-bearing materials ...have been identified and mapped using data from the 2001 Mars Odyssey Thermal Emission Imaging System. These deposits are found throughout regions of low albedo in the southern highlands of Mars. Geomorphologic evidence from orbiting imagery reveals these deposits to be light-toned relative to their surroundings and to be polygonally fractured. The deposits are small (< ~25 km²) but globally widespread, occurring in middle to late Noachian terrains with a few occurrences in early Hesperian terrains. The identification of chlorides in the ancient southern highlands suggests that near-surface water was available and widespread in early Martian history.
In May of 2011, NASA selected the
O
rigins,
S
pectral
I
nterpretation,
R
esource
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dentification, and
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ecurity–
R
egolith
Ex
plorer (OSIRIS-REx) asteroid sample return mission as the third mission ...in the New Frontiers program. The other two New Frontiers missions are
New Horizons
, which explored Pluto during a flyby in July 2015 and is on its way for a flyby of Kuiper Belt object 2014 MU69 on January 1, 2019, and
Juno
, an orbiting mission that is studying the origin, evolution, and internal structure of Jupiter. The spacecraft departed for near-Earth asteroid (101955) Bennu aboard an United Launch Alliance Atlas V 411 evolved expendable launch vehicle at 7:05 p.m. EDT on September 8, 2016, on a seven-year journey to return samples from Bennu. The spacecraft is on an outbound-cruise trajectory that will result in a rendezvous with Bennu in November 2018. The science instruments on the spacecraft will survey Bennu to measure its physical, geological, and chemical properties, and the team will use these data to select a site on the surface to collect at least 60 g of asteroid regolith. The team will also analyze the remote-sensing data to perform a detailed study of the sample site for context, assess Bennu’s resource potential, refine estimates of its impact probability with Earth, and provide ground-truth data for the extensive astronomical data set collected on this asteroid. The spacecraft will leave Bennu in 2021 and return the sample to the Utah Test and Training Range (UTTR) on September 24, 2023.
The deuterium-to-hydrogen (D/H) ratio in strongly bound water or hydroxyl groups in ancient martian clays retains the imprint of the water of formation of these minerals. Curiosity's Sample Analysis ...at Mars (SAM) experiment measured thermally evolved water and hydrogen gas released between 550° and 950°C from samples of Hesperian-era Gale crater smectite to determine this isotope ratio. The D/H value is 3.0 (±0.2) times the ratio in standard mean ocean water. The D/H ratio in this ∼3-billion-year-old mudstone, which is half that of the present martian atmosphere but substantially higher than that expected in very early Mars, indicates an extended history of hydrogen escape and desiccation of the planet.
A numerical model of heat conduction through particulate media made of spherical grains cemented by various bonding agents is presented. The pore‐filling gas conductivity, volume fraction, and ...thermal conductivity of the cementing phase are tunable parameters. Cement fractions <0.001–0.01% in volume have small effects on the soil bulk thermal conductivity. A significant conductivity increase (factor 3–8) is observed for bond fractions of 0.01 to 1% in volume. In the 1 to 15% bond fraction domain, the conductivity increases continuously but less intensely (25–100% conductivity increase compared to a 1% bond system). Beyond 15% of cements, the conductivity increases vigorously and the bulk conductivity rapidly approaches that of bedrock. The composition of the cements (i.e. conductivity) has little influence on the bulk thermal inertia of the soil, especially if the volume of bond <10%. These results indicate that temperature measurements are sufficient to detect cemented soils and quantify the amount of cementing phase, but the mineralogical nature of the bonds and the typical grain size are unlikely to be determined from orbit. On Mars, a widespread surface unit characterized by a medium albedo (0.19–0.26) and medium/high thermal inertia (200–600 J s−0.5 m−2 K−1) has long been hypothesized to be associated with a duricrust. The fraction of cement required to fit the thermal data is less than ∼1–5% by volume. This small amount of material is consistent with orbital observations, confirming that soil cementation is an important factor controlling the thermal inertia of the Martian surface.
Context.
Asteroid (101955) Bennu is the target of NASA’s Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission. The spacecraft’s instruments ...have characterized Bennu at global and local scales to select a sampling site and provide context for the sample that will be returned to Earth. These observations include thermal infrared spectral characterization by the OSIRIS-REx Thermal Emission Spectrometer (OTES).
Aims.
To understand the degree of compositional and particle size variation on Bennu, and thereby predict the nature of the returned sample, we studied OTES spectra, which are diagnostic of these properties.
Methods.
We created and mapped spectral indices and compared them with the distribution of geomorphic features. Comparison to laboratory spectra of aqueously altered carbonaceous chondrites constrains the amount of compositional variability that is observable.
Results.
The OTES spectra exhibit two end-member shapes (or types), and compositional variability appears limited at the spatial resolution of the observations. The global distribution of these spectral types corresponds with the locations of regions composed of (i) large, dark, relatively rough boulders and (ii) relatively smooth regions lacking large boulders.
Conclusions.
The two spectral types appear to be diagnostic primarily of particle size variations, with contributions from other properties. The spectra resemble experimental data of solid substrates with very thin accumulations (a few to tens of microns) of fine particles (<~65–100 μm). The dustier surfaces commonly correspond with rougher rocks that may produce and/or act as traps for the particles. Anhydrous silicates are limited in abundance, and the bulk mineralogy is consistent with the most aqueously altered carbonaceous chondrites. We expect the returned samples to include these physical and mineralogical characteristics.
The glucagon-like peptide-1 (GLP-1) is a multifaceted hormone with broad pharmacological potential. Among the numerous metabolic effects of GLP-1 are the glucose-dependent stimulation of insulin ...secretion, decrease of gastric emptying, inhibition of food intake, increase of natriuresis and diuresis, and modulation of rodent β-cell proliferation. GLP-1 also has cardio- and neuroprotective effects, decreases inflammation and apoptosis, and has implications for learning and memory, reward behavior, and palatability. Biochemically modified for enhanced potency and sustained action, GLP-1 receptor agonists are successfully in clinical use for the treatment of type-2 diabetes, and several GLP-1-based pharmacotherapies are in clinical evaluation for the treatment of obesity.
In this review, we provide a detailed overview on the multifaceted nature of GLP-1 and its pharmacology and discuss its therapeutic implications on various diseases.
Since its discovery, GLP-1 has emerged as a pleiotropic hormone with a myriad of metabolic functions that go well beyond its classical identification as an incretin hormone. The numerous beneficial effects of GLP-1 render this hormone an interesting candidate for the development of pharmacotherapies to treat obesity, diabetes, and neurodegenerative disorders
Selective, robust and cost-effective chemical sensors for detecting small volatile-organic compounds (VOCs) have widespread applications in industry, healthcare and environmental monitoring. Here we ...design a Pt(II) pincer-type material with selective absorptive and emissive responses to methanol and water. The yellow anhydrous form converts reversibly on a subsecond timescale to a red hydrate in the presence of parts-per-thousand levels of atmospheric water vapour. Exposure to methanol induces a similarly-rapid and reversible colour change to a blue methanol solvate. Stable smart coatings on glass demonstrate robust switching over 10
cycles, and flexible microporous polymer membranes incorporating microcrystals of the complex show identical vapochromic behaviour. The rapid vapochromic response can be rationalised from the crystal structure, and in combination with quantum-chemical modelling, we provide a complete microscopic picture of the switching mechanism. We discuss how this multiscale design approach can be used to obtain new compounds with tailored VOC selectivity and spectral responses.
We present tensor-to-scalar ratio forecasts for GreenPol, a hypothetical ground-based B -mode experiment aiming to survey the cleanest regions of the Northern Galactic Hemisphere at five frequencies ...between 10 and 44 GHz. Its primary science goal would be to measure large-scale cosmic microwave background (CMB) polarization fluctuations at multipoles ℓ ≲ 500, and thereby constrain the primordial tensor-to-scalar ratio r . The observations for the suggested experiment would take place at the Summit Station (72 ° 34N, 38 ° 27W) on Greenland, at an altitude of 3216 m above sea level. For this paper we simulated various experimental setups, and derived limits on the tensor-to-scalar ratio after CMB component separation using a Bayesian component separation implementation called Commander. When combining the proposed experiment with Planck HFI observations for constraining polarized thermal dust emission, we found a projected limit of r < 0.02 at 95% confidence for the baseline configuration. This limit is very robust with respect to a range of important experimental parameters, including sky coverage, detector weighting, foreground priors, among others. Overall, GreenPol would have the possibility to provide deep CMB polarization measurements of the Northern Galactic Hemisphere at low frequencies.
The observation of gullies on Mars indicates the presence of liquid water near the surface in recent times, which is difficult to reconcile with the current cold climate. Gullies have been proposed ...to form through surface runoff from subsurface aquifers or through melting of near-surface ice under warmer conditions. But these gullies are observed to occur preferentially in cold mid-latitudes, where the presence of liquid water is less likely, and on isolated surfaces where groundwater seepage would not be expected, making both potential explanations unsatisfactory. Here I show that gullies can form by the melting of water-rich snow that has been transported from the poles to mid-latitudes during periods of high obliquity within the past 105 to 106 years (refs 5, 6). Melting within this snow can generate sufficient water to erode gullies in about 5,000 years. My proposed model for gully formation is consistent with the age and location of the gullies, and it explains the occurrence of liquid water in the cold mid-latitudes as well as on isolated surfaces. Remnants of the snowpacks are still present on mid-latitude, pole-facing slopes, and the recent or current occurrence of liquid water within them provides a potential abode for life.
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