Many lakes undergo anthropogenically driven eutrophication and pollution leading to decreased water and sediment quality. These effects can enhance seasonally changing lake redox conditions that may ...concentrate potentially toxic elements. Here we report the results of a multi-method geochemical and sediment microfabric analysis applied to reconstruct the history of cultural eutrophication and pollution of the North and South Basins of Windermere, UK. Eutrophication developed from the mid-19th to the earliest 20th centuries. Enhanced lake productivity is indicated by increased sedimentary δ13C, and increased pollution by a higher concentration of metals (Pb, Hg, and As) in the sediment, likely enhanced by incorporation and adsorption to settling diatom aggregates, preserved as sedimentary laminae. In the South Basin, increasing sediment δ15N values occur in step with Zn, Hg, and Cu, linking metal enrichment to isotopically heavy nitrate (N) from anthropogenic sources. From around 1930, decreases in Mn and Fe-rich laminae indicate reduced deep-water ventilation, whereas periods of sediment anoxia increased, being most severe in the deeper North Basin. Strongly reducing sediment conditions promoted Fe and Mn reduction and Pb-bearing barite formation, hitherto only described from toxic mine wastes and contaminated soils. From 1980 there was an increase in indicators of bottom water oxygenation, although not to before 1930. But in the South Basin, the continued impacts of sewage are indicated by elevated sediment δ15N. Imaging and X-ray microanalysis using scanning electron microscopy has shown seasonal-scale redox mineralisation of Mn, Fe, and Ba related to intermittent sediment anoxia. Elevated concentrations of these metals and As also occur in the surficial sediment and provide evidence for dynamic redox mobilisation of potentially toxic elements to the lake water. Concentrations of As (up to 80 ppm), exceed international Sediment Quality Standards. This process may become more prevalent in the future with climate change driving lengthened summer stratification.
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•Geochemistry and sediment fabrics record a 200 year lake eutrophication history.•Seasonally-resolved lake productivity and sediment redox change reconstructed.•Lake eutrophication enhanced incorporation of metals and arsenic into sediment.•Redox mobilisation is leading to surface sediment concentrations of toxic elements.•Climate change is likely to drive mobilisation of toxic elements into lake waters.
A high-resolution record of pollution is preserved in recent sediments from Windermere, the largest lake in the English Lake District. Data derived from X-ray core scanning (validated against ...wavelength dispersive X-ray fluorescence), radiochronological techniques (210Pb and 137Cs) and ultrahigh precision, double-spike mass spectrometry for lead isotopes are combined to decipher the anthropogenic inputs to the lake. The sediment record suggests that while most element concentrations have been stable, there has been a significant increase in lead, zinc, and copper concentrations since the 1930s. Lead isotope down-core variations identify three major contributory sources of anthropogenic (industrial) lead, comprising gasoline lead, coal combustion lead (most likely source is coal-fired steam ships), and lead derived from Carboniferous Pb–Zn mineralization (mining activities). Periods of metal workings do not correlate with peaks in heavy metals due to the trapping efficiency of up-system lakes in the catchment. Heavy metal increases could be due to flood-induced metal inwash after the cessation of mining and the weathering of bedrock in the catchment. The combination of sediment analysis techniques used provides new insights into the pollutant depositional history of Windermere and could be similarly applied to other lake systems to determine the timing and scale of anthropogenic inputs.
High‐resolution shallow sub‐bottom seismic survey data obtained for the Dudgeon windfarm site located 50 km offshore of the north Norfolk coast in the southern North Sea have revealed that the chalk ...bedrock in this area is overlain by sediments deposited during the Elsterian and Weichselian glacial periods. A buried N–S‐trending subglacial drainage channel (tunnel valley) filled with Swarte Bank Formation (MIS 12) sediments indicates that the maximum extent of the Elsterian ice‐sheet margin occurred further to the south. Detailed cross‐sections constructed from the seismic data reveal the presence of buried thrust‐block moraine system composed of deformed (folded and thrusted) Swarte Bank Formation sediments, lying beneath a younger sequence of sediments dominated by the glacigenic Bolders Bank Formation (MIS 2). The geometry of the folds and sense of offset on the thrusts, coupled with the morphology of the ridge‐like landforms within this buried moraine system, are consistent with deformation having occurred in response to ice‐push from the N/NE. The chalk bedrock that underlies the glaciotectonized sequence is thought to have provided an antecedent control on the location and preservation of this moraine system. A three‐phase model is proposed to explain the evolution of this thrust‐moraine complex that formed at the oscillating ice margin during the overall active retreat of the Elsterian ice sheet.
Spawning is a key but often fragile event in the life cycles of fish populations. Nevertheless, it has been relatively little studied for lithophilic lacustrine species requiring hard spawning ...substrates, such as gravels or stones, largely devoid of fine sediments. Twelve demonstrated or putative spawning grounds of Arctic charr (Salvelinus alpinus) in shallow and deep areas of the north and south basins of the eutrophicated lake of Windermere, UK, were described by hydroacoustic, physical and visual surveys. In addition, their current conditions were compared with their original qualitative descriptions made over 50 years ago. Spawning ground characteristics were found to be more complex than originally described, with considerable overlaps in depth ranges and only limited areas of appropriate hard substrates. Moreover, extensive gill netting surveys in recent years have found spawning Arctic charr at only seven of the original 12 demonstrated or putative spawning grounds, although several new spawning areas have also been found. The distribution of unsuitable fine sediments is widespread in the lake, particularly in the more eutrophicated south basin where suitable spawning habitat within the putative spawning areas is limited. Windermere faces a number of environmental problems including climate change and species introductions. However, the temporal and spatial patterns of the lake's eutrophication suggest that associated increases in fine sediments have been a major driver of the observed deterioration of Arctic charr spawning grounds and so may have also contributed to a marked decline recently observed in the local abundance of this species.
Reconstructions of palaeo-ice sheet retreat in response to climate warming using offshore archives can provide vital analogs for future ice-sheet behavior. At the Last Glacial Maximum, Dogger Bank, ...in the southern North Sea, was covered by the Eurasian Ice Sheet. However, the maximum extent and behavior of the ice sheet in the North Sea basin is poorly constrained. We reveal ice-marginal dynamics and maximum ice extent at Dogger Bank through sedimentological and stratigraphic investigation of glacial and proglacial lake sediments. We use a large, integrated subsurface dataset of shallow seismic reflection and geotechnical data collected during windfarm site investigation. For the first time, an ice stream is identified at Dogger Bank, based on preserved subglacial bedforms, eskers and meltwater channels. During ice-sheet advance, a terminal thrust-block moraine complex formed, whose crest runs approximately north-northeast to south-southwest. Subsequent ice stream shutdown caused stagnation of ice, and rapid retreat of the ice-sheet margin. The moraine complex, and outwash head from an adjacent ice-sheet lobe to the west, dammed a large (approximately 750 km2) proglacial lake. Subsequent sedimentation infilled the lake with 30 m of glacial outwash sediments. A lobate subaqueous fan formed at the ice-sheet margin, which thins toward the southeast with iceberg scours and ice-rafted debris at the base, and is onlapped by lake sediments calibrated to core as alternating clay and silt laminae, interpreted to be varves. The lake became isolated from the retreating ice-sheet margin, and ice-sheet retreat slowed. Sediment-laden meltwater was supplied to the ice-distal proglacial lake for c. 1500–2000 years. Subsequent ice-sheet retreat off Dogger Bank was more rapid due to the negative subglacial slope. The stepped retreat of rapid downwasting, slow retreat, and a final rapid phase off Dogger Bank occurred after the LGM at around 27 ka and before formation of a ribbon lake, dated previously to 23 ka and approximately 60 m lower in elevation, formed to the north of Dogger Bank. The complicated stratigraphic architecture revealed through these data improves forecasting of ground conditions for turbine footings at Dogger Bank, an important step in the provision of clean, sustainable energy.
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