The Interdecadal Pacific Oscillation (IPO) is a 40–60 year quasi-oscillation seen mostly in the Pacific basin, but its impacts on surface temperature (T) and precipitation (P) have been found over ...Australia, the Southwest U.S. and other regions. Here, a global analysis of IPO’s impacts on T and P and its modulation of ENSO’s influence on T and P over the globe is performed using observational and reanalysis data and model simulations. Since 1920, there are two warm (1924–1944 and 1977–1998) and two cold (1945–1976 and 1999–present) IPO phases, whose change is associated with abrupt shifts in North Pacific sea level pressure (SLP) and contrasting anomaly patterns in T and P and atmospheric circulation over the eastern and western Pacific. The IPO explains more than half of the interdecadal variations in T and P over many regions, such as northeastern Australia, western Canada and northern India. Significant correlations between the IPO and local P are observed over eastern Australia, southern Africa and the Southwest U.S. The IPO also modulates ENSO’s influence on local T and P over most of these regions. T over northern India is positively correlated with Niño3.4 ENSO index during cold IPO phases but the correlation turns negative or insignificant during IPO warm phases. Over northeastern Australia, the T versus ENSO and P versus ENSO correlations are stronger during the IPO cold phases than during the warm phases. The P versus ENSO correlation over southern Africa tends to be negative during IPO warm phases but becomes weaker or insignificant during IPO cold phases. The IPO-induced P anomalies can be explained by the associated anomaly circulation, which is characterized by a high SLP center and anti-cyclonic flows over the North Pacific, and negative SLP anomalies and increased wind convergence over the Indonesia and western Pacific region during IPO cold phases. These observed influences of the IPO on regional T and P are generally reproduced by an atmospheric model forced by observed sea surface temperatures.
Enhancing the pooling of basic medical insurance plays a vital role in strengthening the resilience to risk and co-payment capacity of medical insurance funds. In China, there is a concerted effort ...to shift from municipal to provincial pooling of medical insurance. While existing research suggests that provincial pooling of basic health insurance affects the health of participants, the findings are not yet consistent, and there is limited research on the specific pathways of impact between the two. Therefore, this study aims to explore the influence of provincial pooling of basic medical insurance on participants' health and analyze the mediating role of medical cost burden and medical service utilization.
Using data from the 2012-2018 China Labor Dynamics Survey (CLDS), this study focuses on a sample of urban workers enrolled in basic medical insurance. After excluding samples with missing information, a total of 5,684 participants were included in the analysis. The effects of the provincial pooling policy of basic medical insurance on participants' medical cost burden, medical service utilization, and health were analyzed using double difference modeling. Furthermore, structural equation modeling was employed to explore the mediating paths between provincial pooling and health.
The findings reveal that provincial pooling of basic medical insurance significantly impacts participants' medical cost burden, medical service utilization, and health. Specifically, provincial pooling helps reduce the participants' medical cost burden (β = -0.1205; P < 0.001), improves the level of medical institutions visited (β = 1.7962; P < 0.001), and promotes health improvement (β = 1.8370; P < 0.001). The mediating effect analysis demonstrates that the direct effect of provincial pooling on health is 1.073 (P < 0.001), with a mediating effect of medical cost burden between provincial pooling and health measuring 0.129 (P < 0.001). Heterogeneity analysis indicates that provincial pooling is more effective in reducing the burden of medical costs for low-income (β = -0.2273; P < 0.001) and high-age participants (β = -0.2710; P < 0.001), and it also helps increase the burden of medical costs for low-income (β = 4.0875; P < 0.001) and high-age participants (β = 1.9010; P < 0.001) based on provider ranking. Moreover, it is found that provincial pooling is more beneficial in improving the health of high-income (β = 1.7984; P < 0.001) and middle- and high-age enrollees (β = 1.9220; P < 0.001; β = 0.5900; P < 0.001). Further analysis reveals that the provincial unified income and expenditure mode has a more positive effect than the provincial risk adjustment fund mode in reducing the medical expense burden of the insured (-0.2053 < -0.0775), improving the grade of medical institutions (1.8552 > 0.8878), and enhancing the health level (2.8406 > 0.6812).
The study concludes that provincial pooling of basic medical insurance has a direct positive impact on participants' health and indirectly promotes health improvement by reducing the burden of medical costs. The effects of provincial pooling on participants' medical cost burden, medical service utilization, and health vary based on income and age. Additionally, the provincial-level unified collection and payment model proves to be more advantageous in optimizing the functioning of health insurance funds through the "law of large numbers" principle.
Li‐CO2 batteries are regarded as next‐generation high‐energy‐density electrochemical devices. However, the greatest challenge arises from the formation of the discharge product, Li2CO3, which would ...accumulate and deactivate heterogenous catalysts to cause huge polarization. Herein, Ru(bpy)3Cl2 was employed as a solution‐phase catalyst for Li‐CO2 batteries and proved to be the most effective one screened so far. Spectroscopy and electrochemical analyses elucidate that the RuII center could interact with both CO2 and amorphous Li2C2O4 intermediate, thus promoting electroreduction process and delaying carbonate transformation. As a result, the charge potential is reduced to 3.86 V and over 60 discharge/charge cycles are achieved with a fixed capacity of 1000 mAh g−1 at a current density of 300 mA g−1. Our work provides a new avenue to improve the electrochemical performance of Li‐CO2 batteries with efficient mobile catalysts.
Ru(bpy)3Cl2 was applied as the first ruthenium‐based mobile catalyst to enhance the electrochemical performance of Li‐CO2 batteries. The RuII catalyst was discovered to interact with both CO2 molecules and amorphous Li2C2O4 intermediate, thus promoting CO2RR and delaying carbonate formation and consequently leading to lowered overpotential, enlarged capacity, and prolonged cyclability of the batteries.
This paper studies the global (in time) regularity and large time behavior of solutions to the 2D micropolar equations with only angular viscosity dissipation. Micropolar equations model a class of ...fluids with nonsymmetric stress tensor such as fluids consisting of particles suspended in a viscous medium. When there is no kinematic viscosity in the momentum equation, the global regularity problem is not easy due to the lack of suitable bounds on the derivatives. The idea here is to fully exploit the structure of the system and control the vorticity via the evolution equation of a combined quantity of the vorticity and the micro-rotation angular velocity. To understand the large time behavior, we overcome two main difficulties, the lack of kinematic viscosity and the presence of linear terms. Classical tools such as the Fourier splitting method of Schonbek and Kato's approach for the decay of small solutions do not apply here. We introduce a diagonalization process to eliminate the linear terms and rely on the uniform bounds for the first derivatives of the solutions to generate suitable decay rates.
China has the world's largest mobile population. As mobility increases, ensuring the health protection of this population is receiving more attention. Strengthening public health education is a ...crucial measure to improve their health and achieve equal access to basic public health services in China. Previous research has demonstrated that public health education has an impact on the health of mobile populations. However, there has been limited investigation into the mediating pathways through which health education influences the health of mobile populations, and few studies have examined the heterogeneity of this effect.
The aim of this study was to analyze the impact of public health education on the health of the mobile population and its mechanism of action. Additionally, we aimed to explore the differences in this impact among different subdivided groups.
This paper analyses the impact of public health education on the health of the mobile population using the 2018 China Migrant Dynamic Survey (CMDS) Data,. The data was cleaned and 4,034 people were included in the analysis. The study employed ordered logistic regression modeling to analyze the mediating pathways through which health education affects health. Additionally, binary logistic regression model, probit model, propensity score matching method and instrumental variables were used to verify the robustness of the results.
The self-assessed health status of the mobile population was good, and 82.10% of them accepted public health education. However, 17.89% of the mobile population did not receive any health education. Acceptance of health education can help improve the health status of the mobile population (OR = 1.178, 95% CI = 0.979-1.418). The study found that public health education can positively impact the health of mobile populations by influencing their health and hospitalization behaviors, as well as their social support. The analysis of heterogeneity revealed that the impact of public health education is more significant among rural, middle-aged, low-education, and low-income groups of the mobile population.
Public health education can have a positive impact on the health of the migrant populations. To further improve health education for this group, it is necessary to actively promote the establishment of health records for the migrant population, to facilitate the contracting of family doctors by the migrant population, to improve the accessibility to hospitalization services, reduce the burden of hospitalization costs, and enhance social support. Simultaneously, it is essential to offer precise and varied health education to the migrant population based on their characteristics, to promote equity among diverse groups of individuals. These findings not only help to enrich theoretical research on health education for migrant populations and the health of migrant populations but also help to improve the level of public health education for migrant populations and improve the health protection of migrant populations.
It is a pivotal element of China's health system reform to improve the health security of health insurance for the mobile population. Achieving this objective is integral to the success of the ...reform. The aim of this study was to analyze the impact of different enrollment characteristics of basic health insurance on the health of the mobile population and to investigate the mediating role of health service utilization behavior.
This cross-sectional study included 135,372 migrants who participated in the 2018 China Migrants Dynamic Survey (CMDS). Two indicators were employed in this study to assess the characteristics of the mobile population's involvement in basic health insurance-namely, whether or not they participated in local health insurance and the type of health insurance in which they participated. The health status of the mobile population was measured using self-assessed health. Health service utilization behavior was divided into public health service utilization and medical service utilization. Multivariate ordered logistic regression was employed to examine the effect of health insurance on the health of the mobile population. Subsequently, the Bootstrap method was applied to analyze the mediating effect of health service utilization behavior in the relationship between health insurance and the health of the mobile population.
Health insurance had a positive impact on health, public health services, and health service utilization among the mobile population. However, enrollment in local health insurance (OR = 1.088, 95% CI = 1.043-1.134) and enrollment in Basic Medical Insurance for Urban Employees (OR = 1.178, 95% CI = 1.090-1.273) were more likely to be associated with higher levels of health and a greater likelihood of receiving health service utilization. The results of the mediating mechanism analysis indicated that health education, health records, family doctor contracting, receiving inpatient services, and being hospitalized locally all played a partially mediating role in the impact of the place of enrollment on health. Regarding the effect of the type of enrollment on health, three types of services-namely, health education, health records, and contracting with a family doctor-played a partially mediating role, while receiving inpatient services and being hospitalized locally did not exhibit a mediating effect. The effect of the type of participation on health is partially mediated.
Based on the impact of the different enrolment characteristics of basic health insurance on the health of the mobile population and the mediating role of health service utilization in this impact, furthermore, improvement of health insurance coverage for the mobile population should focus on improving the accessibility of health services, increasing the level of health insurance coverage, mitigating differences in treatment between the different insurance systems, and simplifying the process of transferring the health insurance relationships.
Enhancing the technical methods of teaching physical instruction in the information age and building an ideal guarantee system for teaching physical instruction reform and innovation are essential ...components of higher education development. The construction path of the physical literacy teaching reform guarantee system is presented in this paper, along with the development of an evaluation model for the effects of physical instruction reform teaching. This model serves as the basis for evaluating the impact following the implementation of the physical instruction teaching reform. The assessment model relies on the hierarchy analysis approach, which also establishes the second-level fuzzy complete judgment matrix, creates the rubric set for the assessment of the teaching reform effect, and demonstrates the weight value of each indicator in the evaluation model. With respect to the research object in the case analysis of the CA University physical instruction teaching reformation effect, the evaluation’s overall rating is 0.693, and it receives a “good” grade. The 50-meter run, seated forward bending test, and BMI endurance test items showed significant differences (P<0.05). Significant differences (P<0.05) were also presented in the dimensions of athletic ability, athletic participation, athletic awareness, athletic character, and learning interest in physical instruction learning outcomes, except for the dimension of athletic participation interest.
Low n‐doping efficiency and inferior stability restrict the thermoelectric performance of n‐type conjugated polymers, making their performance lag far behind of their p‐type counterparts. Reported ...here are two rigid coplanar poly(p‐phenylene vinylene) (PPV) derivatives, LPPV‐1 and LPPV‐2, which show nearly torsion‐free backbones. The fused electron‐deficient rigid structures endow the derivatives with less conformational disorder and low‐lying lowest unoccupied molecular orbital (LUMO) levels, down to −4.49 eV. After doping, two polymers exhibited high n‐doping efficiency and significantly improved air stability. LPPV‐1 exhibited a high conductivity of up to 1.1 S cm−1 and a power factor as high as 1.96 μW m−1 K−2. Importantly, the power factor of the doped LPPV‐1 thick film degraded only 2 % after 7 day exposure to air. This work demonstrates a new strategy for designing conjugated polymers, with planar backbones and low LUMO levels, towards high‐performance and potentially air‐stable n‐type polymer thermoelectrics.
Stability: A new rigid coplanar poly(p‐phenylene vinylene) (PPV) derivative, LPPV‐1, is synthesized with a rigid planar backbone and low‐lying LUMO, which lead to reduced conformational disorder and high n‐type doping efficiency. The conductivity of LPPV‐1 is up to 1.1 S cm−1, and the power factor is only 2 % after a 7 day exposure to air. This work represents an effective strategy towards high‐performance and potentially air‐stable n‐type polymer thermoelectrics.
A new, complete sample of 14,584 broad-line active galactic nuclei (AGNs) at z < 0.35 is presented, which are uncovered homogeneously from the complete database of galaxies and quasars observed ...spectroscopically in the Sloan Digital Sky Survey Seventh Data Release. The stellar continuum is properly removed for each spectrum with significant host absorption line features, and careful analyses of the emission line spectra, particularly in the H and Hβ wavebands, are carried out. The broad Balmer emission line, particularly H , is used to indicate the presence of an AGN. The broad H lines have luminosities in a range of 1038.5- 1044.3 , and line widths (FWHMs) of 500-34,000 . The virial black hole masses, estimated from the broad-line measurements, span a range of 105.1- 1010.3 , and the Eddington ratios vary from −3.3 to 1.3 in logarithmic scale. Other quantities such as multiwavelength photometric properties and flags denoting peculiar line profiles are also included in this catalog. We describe the construction of this catalog and briefly discuss its properties. The catalog is publicly available online. This homogeneously selected AGN catalog, along with the accurately measured spectral parameters, provides the most updated, largest AGN sample data, which will enable further comprehensive investigations of the properties of the AGN population in the low-redshift universe.
Solution‐processable highly conductive polymers are of great interest in emerging electronic applications. For p‐doped polymers, conductivities as high a nearly 105 S cm−1 have been reported. In the ...case of n‐doped polymers, they often fall well short of the high values noted above, which might be achievable, if much higher charge‐carrier mobilities determined could be realized in combination with high charge‐carrier densities. This is in part due to inefficient doping and dopant ions disturbing the ordering of polymers, limiting efficient charge transport and ultimately the achievable conductivities. Here, n‐doped polymers that achieve a high conductivity of more than 90 S cm−1 by a simple solution‐based co‐deposition method are reported. Two conjugated polymers with rigid planar backbones, but with disordered crystalline structures, exhibit surprising structural tolerance to, and excellent miscibility with, commonly used n‐dopants. These properties allow both high concentrations and high mobility of the charge carriers to be realized simultaneously in n‐doped polymers, resulting in excellent electrical conductivity and thermoelectric performance.
Two conjugated polymers with rigid planar backbones, but with disordered crystalline structures, exhibit surprising structural tolerance to commonly used n‐dopants. These properties allow both high concentrations and high mobility of the charge carriers to be realized simultaneously in n‐doped polymers, resulting in excellent electrical conductivity of over 90 S cm−1 and thermoelectric performance up to 106 µW m−1 K−2.
PDF
