► This review highlights the phytoremediation of arsenic using aquatic floating macrophytes. ►
Eichhornia,
Lemna, Spirodela,
Azolla, and Hydrilla are promising phytoremediating plants. ► Aquatic ...plants take up As(V) by phosphate transporters, and As(III), DMAA, MMAA by aquaglyceroporins. ► Upon uptake, aquatic plants reduce As(V) to As(III) as a detoxification mechanism. ► Biogas and biofuel production would be good options for the treatment of phytoremediating plants.
Phytoremediation, a plant based green technology, has received increasing attention after the discovery of hyperaccumulating plants which are able to accumulate, translocate, and concentrate high amount of certain toxic elements in their above-ground/harvestable parts. Phytoremediation includes several processes namely, phytoextraction, phytodegradation, rhizofiltration, phytostabilization and phytovolatilization. Both terrestrial and aquatic plants have been tested to remediate contaminated soils and waters, respectively. A number of aquatic plant species have been investigated for the remediation of toxic contaminants such as As, Zn, Cd, Cu, Pb, Cr, Hg, etc. Arsenic, one of the deadly toxic elements, is widely distributed in the aquatic systems as a result of mineral dissolution from volcanic or sedimentary rocks as well as from the dilution of geothermal waters. In addition, the agricultural and industrial effluent discharges are also considered for arsenic contamination in natural waters. Some aquatic plants have been reported to accumulate high level of arsenic from contaminated water. Water hyacinth (
Eichhornia crassipes), duckweeds (
Lemna gibba,
Lemna minor,
Spirodela polyrhiza), water spinach (
Ipomoea aquatica), water ferns (
Azolla caroliniana,
Azolla filiculoides, and
Azolla pinnata), water cabbage (
Pistia stratiotes), hydrilla (
Hydrilla verticillata) and watercress (
Lepidium sativum) have been studied to investigate their arsenic uptake ability and mechanisms, and to evaluate their potential in phytoremediation technology. It has been suggested that the aquatic macrophytes would be potential for arsenic phytoremediation, and this paper reviews up to date knowledge on arsenic phytoremediation by common aquatic macrophytes.
Rice is the staple food for the people of arsenic endemic South (S) and South-East (SE) Asian countries. In this region, arsenic contaminated groundwater has been used not only for drinking and ...cooking purposes but also for rice cultivation during dry season. Irrigation of arsenic-contaminated groundwater for rice cultivation has resulted high deposition of arsenic in topsoil and uptake in rice grain posing a serious threat to the sustainable agriculture in this region. In addition, cooking rice with arsenic-contaminated water also increases arsenic burden in cooked rice. Inorganic arsenic is the main species of S and SE Asian rice (80 to 91% of the total arsenic), and the concentration of this toxic species is increased in cooked rice from inorganic arsenic-rich cooking water. The people of Bangladesh and West Bengal (India), the arsenic hot spots in the world, eat an average of 450
g rice a day. Therefore, in addition to drinking water, dietary intake of arsenic from rice is supposed to be another potential source of exposure, and to be a new disaster for the population of S and SE Asian countries. Arsenic speciation in raw and cooked rice, its bioavailability and the possible health hazard of inorganic arsenic in rice for the population of S and SE Asia have been discussed in this review.
► Arsenic (As) deposition in paddy soil from irrigation water is a threat to the sustainable rice cultivation in South Asia. ► Cooking rice with arsenic-contaminated water increases its burden in cooked rice. ► Toxic inorganic As is the main species in Asian rice, and its content is increased in cooked rice from cooking water. ► As in rice is a potential source of exposure, and is supposed to be a new disaster for South Asia.
The maximum work formulation of the second law of thermodynamics is generalized for a transition between nonequilibrium states. The relative entropy, the Kullback–Leibler divergence between the ...nonequilibrium states and the canonical distribution, determines the maximum ability to work. The difference between the final and the initial relative entropies with an effective temperature gives the maximum dissipative work for both adiabatic and isothermal processes. Our formulation reduces to both the Vaikuntanathan–Jarzynski relation and the nonequilibrium Clausius relation in certain situations. By applying our formulation to a heat engine the Carnot cycle is generalized to a circulation among nonequilibrium states.
Magnetic reconnection is believed to be the main driver to transport solar wind into the Earth's magnetosphere when the magnetopause features a large magnetic shear. However, even when the magnetic ...shear is too small for spontaneous reconnection, the Kelvin-Helmholtz instability driven by a super-Alfvénic velocity shear is expected to facilitate the transport. Although previous kinetic simulations have demonstrated that the non-linear vortex flows from the Kelvin-Helmholtz instability gives rise to vortex-induced reconnection and resulting plasma transport, the system sizes of these simulations were too small to allow the reconnection to evolve much beyond the electron scale as recently observed by the Magnetospheric Multiscale (MMS) spacecraft. Here, based on a large-scale kinetic simulation and its comparison with MMS observations, we show for the first time that ion-scale jets from vortex-induced reconnection rapidly decay through self-generated turbulence, leading to a mass transfer rate nearly one order higher than previous expectations for the Kelvin-Helmholtz instability.
The adsorption of Au(III), Pt(IV) and Pd(II) onto glycine modified crosslinked chitosan resin (GMCCR) has been investigated. The parameters studied include the effects of pH, contact time, ionic ...strength and the initial metal ion concentrations by batch method. The optimal pH for the adsorption of Au(III), Pt(IV) and Pd(II) was found to range from 1.0 to 4.0 and the maximum uptake was obtained at pH 2.0 for Au(III), Pt(IV) and Pd(II). The results obtained from equilibrium adsorption studies are fitted in various adsorption models such as Langmuir and Freundlich and the model parameters have been evaluated. The maximum adsorption capacity of GMCCR for Au(III), Pt(IV) and Pd(II) was found to be 169.98, 122.47 and 120.39
mg/g, respectively. The kinetic data was tested using pseudo-first-order and pseudo-second-order kinetic models and an intraparticle diffusion model. The correlation results suggested that the pseudo-second-order model was the best choice among all the kinetic models to describe the adsorption behavior of Au(III), Pt(IV) and Pd(II) onto GMCCR. Various concentrations of HCl, thiourea and thiourea–HCl solutions were used to desorb the adsorbed precious metal ions from GMCCR. It was found that 0.7
M thiourea–2
M HCl solution provided effectiveness of the desorption of Au(III), Pt(IV) and Pd(II) from GMCCR. The modification of glycine on crosslinked chitosan resin (CCR) was studied by Fourier transform infrared spectrometry (FTIR) and scanning electron microscopy (SEM).
In the Earth's magnetotail, magnetic reconnection releases stored magnetic energy and drives magnetospheric convection. The rate at which magnetic flux is transferred from the reconnection inflow to ...outflow regions is determined by the reconnection electric field Er, which is often referred to as the unnormalized reconnection rate. To better quantify the efficiency of reconnection, this electric field Er is often normalized by the characteristic Alfvén speed and the reconnecting magnetic field. This parameter is generally called the normalized or dimensionless reconnection rate R. In this paper, we employ a two‐dimensional fully kinetic simulation to model a magnetotail reconnection event with weak geomagnetic activity (<200 nT of the AE index) observed by the Magnetospheric Multiscale (MMS) mission on 11 July 2017. We obtain R and Er from direct measurements in the diffusion region and indirect measurements of the rate at the separatrix using a recently proposed remote sensing technique. The measured normalized rate for this MMS event is R ∼0.15–0.2, consistent with theoretical and simulation models of fast collisionless reconnection. This corresponds to an unnormalized rate of Er ∼2–3 mV/m. Based on quantitative consistencies between the simulation and the MMS observations, we conclude that our estimates of the reconnection rates are reasonably accurate. Given that past studies have found Er of the order ∼10 mV/m during strong geomagnetic substorms, these results indicate that the local Er in magnetotail reconnection may be an important parameter controlling the amplitude of geomagnetic disturbances.
Key Points
Reliable reconnection rates are obtained based on virtual observations in a fully kinetic simulation of an MMS tail reconnection event
The normalized rates obtained from the simulation and MMS data are 0.15–0.2, indicating the occurrence of fast reconnection
The observed unnormalized rate is 2–3 mV/m, while higher rates were observed in other events with stronger geomagnetic activities
We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy ...(H-function) is not just a Lyapunov function but also tells us the maximum work that may be gained from a nonequilibrium initial state. The generalized second law also gives a fundamental relation between work and information. It is valid even for a small Hamiltonian system not in contact with a heat reservoir but with an effective temperature determined by the isentropic condition. Our relation can be tested in the Szilard engine, which will be realized in the laboratory.
To cope with the continuous traffic growth, spectral efficiency needs to be enhanced. Ultra-dense WDM systems, where narrower guard-bands are inserted between wavelength-division-multiplexed (WDM) ...signals than those used in conventional dense WDM (DWDM) systems, are expected to offer higher spectral efficiency. However, such systems are hindered by the spectrum narrowing induced by wavelength selective switches (WSSs) at nodes. As a result, intersymbol interference (ISI) can be excessive. Linear digital filters widely used in typical digital coherent receivers can equalize the ISI. However, ISI equalization yields noise enhancement due to the interaction between ISI and amplifier noise. Sequence estimation can alleviate the impact of this interaction; however, to introduce sequence estimation into real systems, an ISI-imposing filter is needed because the adaptive filter used for polarization recovery automatically equalizes the ISI. Although the optimum ISI-imposing filter can be created with the proper spectrum model, its characteristics change frequently in real optical path networks. Therefore, we need to develop a demodulation framework that does not necessitate any spectrum models. In this letter, we propose a novel demodulation framework that uses a recurrent neural network (RNN) to simultaneously realize the ISI-imposing filter and sequence estimator. Extensive computer simulations show that our proposal increases the transmission distance in ultra-dense WDM networks.
We present in‐depth analysis of three southward‐moving meso‐scale (ion‐to magnetohydrodynamic‐scale) flux transfer events (FTEs) and subsequent crossing of a reconnecting magnetopause current sheet ...(MPCS), which were observed on 8 December 2015 by the Magnetospheric Multiscale spacecraft in the subsolar region under southward and duskward magnetosheath magnetic field conditions. We aim to understand the generation mechanism of ion‐scale magnetic flux ropes (ISFRs) and to reveal causal relationship among magnetic field structures, electromagnetic energy conversion, and kinetic processes in magnetic reconnection layers. Results from magnetic field reconstruction methods are consistent with a flux rope with a length of about one ion inertial length growing from an electron‐scale current sheet (ECS) in the MPCS, supporting the idea that ISFRs can be generated through secondary reconnection in an ECS. Grad‐Shafranov reconstruction applied to the three FTEs shows that the FTEs had axial orientations similar to that of the ISFR. This suggests that these FTEs also formed through the same secondary reconnection process, rather than multiple X‐line reconnection at spatially separated locations. Four‐spacecraft observations of electron pitch‐angle distributions and energy conversion rate j·E′=j·E+ve×B $\mathbf{j}\cdot {\mathbf{E}}^{\prime }=\mathbf{j}\cdot \left(\mathbf{E}+{\mathbf{v}}_{\mathrm{e}}\times \mathbf{B}\right)$ suggest that the ISFR had three‐dimensional magnetic topology and secondary reconnection was patchy or bursty. Previously reported positive and negative values of j·E′ $\mathbf{j}\cdot {\mathbf{E}}^{\prime }$, with magnitudes much larger than expected for typical MP reconnection, were seen in both magnetosheath and magnetospheric separatrix regions of the ISFR. Many of them coexisted with bi‐directional electron beams and intense electric field fluctuations around the electron gyrofrequency, consistent with their origin in separatrix activities.
Plain Language Summary
Magnetic reconnection is a physical process that converts magnetic energy into plasma energy by changing the connectivity of magnetic field lines from one region to another. Magnetic reconnection at the outer boundary of planetary magnetospheres, known as the magnetopause (MP), is key to the entry of solar wind plasma and energy into the magnetospheres that forms the basis for space weather phenomena in the magnetospheres. MP reconnection often occurs in a transient or patchy manner, forming magnetic flux ropes (FRs) with helical field lines of various sizes. They may become an important pathway for fast coupling between the solar wind and magnetosphere. However, the generation mechanism of a subclass of FRs, relatively small “ion‐scale” FRs, is poorly understood. Computer simulations show that they are formed in thin and elongated current sheets of single active reconnection site, but this scenario has not been confirmed by observations. Our observations based on NASA's Magnetospheric Multiscale mission show that ion‐scale FR can form in a thin current sheet of single ongoing reconnection site at Earth's MP. The observed FR showed signatures of complex field line connectivity and localized conversion from electromagnetic to electron energy and vice versa, indicating complex MP dynamics.
Key Points
Ion‐scale magnetic flux rope (ISFR) can be generated from reconnecting electron‐scale current sheet at the subsolar magnetopause (MP)
Preceding mesoscale flux ropes had axial directions akin to that of the ISFR in the MP, suggesting the same generation mechanism
The ISFR had complex magnetic topology with three‐dimensional effects and involved patchy, intense energy conversion in separatrix regions
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