Synthesis of a new HKUST-1 composite based on single-walled carbon nanotubes (SWCNTs) was successfully achieved (SWCNT@HKUST-1). SWCNTs were used as templates to grow rod-like HKUST-1 crystals over ...the surface of the nanotubes. N2 adsorption properties showed an increment on the surface area and pore volume for the SWCNT@HKUST-1 composite. Furthermore, the CO2 capture increased, from 7.92 to 8.75 mmol g–1 at 196 K up to 100 kPa, for the SWCNT@HKUST-1 composite. This enhancement was directly associated with the increase of the surface area of the composite. Additionally, an increase in the CO2 heat of adsorption was estimated, from 30 to 39.1 kJ mol–1 for the SWCNT@HKUST-1 composite. In situ Raman experiments corroborated the favored CO2 adsorption for the composite and provided an insight into the augmented hydrophobicity of the SWCNT@HKUST-1. Ethanol adsorption isotherms corroborated an increase in the hydrophobicity of the material upon the incorporation of carbon nanotubes.
In this study, the concentrations of Cd and Hg were measured in muscle of juvenile individuals at an importan fishing ground in southeastern Gulf of California to assess the health risk to human ...consumers considering elemental levels and rate of shark consumption in NW Mexico. Twenty-eight individuals were sampled in September 2019. Quantification of Hg was made by cold vapor-atomic absorption spectrophotometry, analyses of Cd were made by graphite furnace atomic absorption spectrophotometry. In general, average Hg (1.27 µg g
−1
dry weight) concentrations were higher than Cd (0.059). In comparison to results of Cd and Hg in muscle of several species of genus
Rhizoprionodon
sp., our reported concentrations were comparable. Maximum permissible limits (Cd 0.5 and Hg 0.5 µg g
−1
wet weight) in fish products for human consumption were not exceeded. Health risk assessment to shark consumers indicated that Hg is of more concern than Cd but no hazards exist.
In recent years, concerns about Chagas disease in the United States have increased. Triatomine bug (Hemiptera: Reduviidae) populations are the vectors of the parasite Trypanosoma cruzi Chagas ...(Trypanosomatida: Trypanosomatidae), which causes Chagas disease, although the route of transmission is considered inefficient in United States. However, more studies on triatomine feeding and defecation behavior are needed. In this study, six related biological parameters from two populations of Triatoma protracta protracta (Uhler) and T. p. woodi (Uhler) from Mexican locations near the U.S. border were evaluated. The four population life cycles were less than 6 mo (161–171 d), with 9–10 blood meals needed to molt. Mortality rates were similar (31–38%) among the four populations. Triatoma p. woodi from Hidalgo, Coahuila was the most aggressive one. Feeding times were over 10 min, increasing with instar in all populations. Defecation behaviors varied among populations. High percentages of male and female fourth- and fifth-instar nymphs of T. p. protracta from Imuris and both populations of T. p. woodi defecated immediately after or <1 min of feeding. Lower percentages were observed for T. p. protracta from Jacumé. Because most parameters were similar among the four populations, independent of their subspecies and their geographic origin, we considered that T. p. protracta and T. p. woodi are efficient vectors of T. cruzi. In contrast, defecation patterns were noticeably different among some of the four triatomine populations studied. Our results highlight the importance of studying the biological parameters of local triatomine populations. They also contribute to increasing the knowledge of North American triatomine behavior and defecation patterns. Graphical Abstract
The Iberoamerican Cochrane Network is currently developing an extensive project to identify Spanish-language journals that publish original clinical research in Spain and Latin America. The project ...is called BADERI (Database of Iberoamerican Essays and Journal) and feeds the research articles, mainly randomised clinical trials (RCTs), into CENTRAL (Cochrane Collaboration Central Register of Controlled Trials). This study aims to assess the quality of reporting of RCTs published in Spanish and Latin American journals for three clinical fields and assess changes over time.
We did a systematic survey with time trend analysis of RCTs for dentistry, geriatrics, and neurology. These fields were chosen for pragmatic reasons as they had not yet been completed in BADERI. After screening RCTs from 1990 to 2018 for randomised or quasi-randomised clinical trials, we extracted data for 23 CONSORT items. The primary outcome was the total score of the 23 predefined CONSORT 2010 items for each RCT (score range from 0 to 34). The secondary outcome measure was the score for each one of these 23 items.
A total of 392 articles from 1990 to 2018 were included as follows: dentistry (282), neurology (80), and geriatrics (30). We found that the overall compliance score for the CONSORT items included in this study for all 392 RCTs analysed was 12.6 on a scale with a maximum score of 34. With time, the quality of reporting improved slightly for all RCTs. None of the articles achieved the complete individual CONSORT item compliance score. The lowest overall compliance percentage was for item 10 (Randomisation implementation) and item 24 (Protocol registration), with a dismal 1% compliance across all included RCTs, regardless of country.
CONSORT compliance is very poor in the 392 analysed RCTs. The impact of the CONSORT statement on improving the completeness of RCT reporting in Latin America and Spain is not clear. Iberoamerican journals should become more involved in endorsing and enforcing adherence to the CONSORT guidelines.
Dairy product safety is a global public health issue that demands new approaches and technologies to control foodborne pathogenic microorganisms. Natural antimicrobial agents such as nisin can be ...added to control the growth of pathogens of concern in dairy foods, namely Listeria monocytogenes and Staphylococcus aureus. However, several factors affect the antimicrobial efficacy of nisin when directly added into the food matrix such as lack of stability at neutral pH, interaction with fat globules, casein, and divalent cations. To overcome these limitations, new and advanced strategies are discussed including nisin encapsulation technology, addition to active packaging, bioengineering, and combination with other antimicrobials. This review highlights advanced technologies with potential to expand and improve the use of nisin as a dairy preservative.
Biochar is a carbonaceous and porous material with limited adsorption capacity, which increases by modifying its surface. Many of the biochars modified with magnetic nanoparticles reported previously ...were obtained in two steps: first, the biomass was pyrolyzed, and then the modification was performed. In this research, a biochar with Fe
O
particles was obtained during the pyrolysis process. Corn cob residues were used to obtain the biochar (i.e., BCM) and the magnetic one (i.e., BCM
). The BCM
biochar was synthesized by a chemical coprecipitation technique prior to the pyrolysis process. The biochars obtained were characterized to determine their physicochemical, surface, and structural properties. The characterization revealed a porous surface with a 1013.52 m
/g area for BCM and 903.67 m
/g for BCM
. The pores were uniformly distributed, as observed in SEM images. BCM
showed Fe
O
particles on the surface with a spherical shape and a uniform distribution. According to FTIR analysis, the functional groups formed on the surface were aliphatic and carbonyl functional groups. Ash content in the biochar was 4.0% in BCM and 8.0% in BCM
; the difference corresponded to the presence of inorganic elements. The TGA showed that BCM lost 93.8 wt% while BCM
was more thermally stable due to the inorganic species on the biochar surface, with a weight loss of 78.6%. Both biochars were tested as adsorbent materials for methylene blue. BCM and BCM
obtained a maximum adsorption capacity (q
) of 23.17 mg/g and 39.66 mg/g, respectively. The obtained biochars are promising materials for the efficient removal of organic pollutants.
MAXI J1659−152 is a bright X-ray transient black-hole candidate binary system discovered in September 2010. We report here on MAXI, RXTE, Swift, and XMM-Newton observations during its 2010/2011 ...outburst. We find that during the first one and a half week of the outburst the X-ray light curves display drops in intensity at regular intervals, which we interpret as absorption dips. About three weeks into the outbursts, again drops in intensity are seen. These dips have, however, a spectral behaviour opposite to that of the absorption dips, and are related to fast spectral state changes (hence referred to as transition dips). The absorption dips recur with a period of 2.414 ± 0.005 h, which we interpret as the orbital period of the system. This implies that MAXI J1659−152 is the shortest period black-hole candidate binary known to date. The inclination of the accretion disk with respect to the line of sight is estimated to be 65–80°. We propose the companion to the black-hole candidate to be close to an M5 dwarf star, with a mass and radius of about 0.15–0.25 M⊙ and 0.2–0.25 R⊙, respectively. We derive that the companion had an initial mass of about 1.5 M⊙, which evolved to its current mass in about 5–6 billion years. The system is rather compact (orbital separation of ≳1.33 R⊙), and is located at a distance of 8.6 ± 3.7 kpc, with a height above the Galactic plane of 2.4 ± 1.0 kpc. The characteristics of short orbital period and high Galactic scale height are shared with two other transient black-hole candidate X-ray binaries, i.e., XTE J1118+480 and Swift J1735.5−0127. We suggest that all three are kicked out of the Galactic plane into the halo, rather than being formed in a globular cluster.
The need of a neutron source for the qualification of materials to be used in future fusion power reactors has been recognized in the European Union (EU) fusion programme for many years. The ...construction and exploitation of this facility is presently considered to be critical to the construction of the DEMOnstration Power Plant (DEMO). This issue has prompted the EU to launch activities for the design and engineering of the International Fusion Materials Irradiation Facility-DEMO Oriented Neutron Source (IFMIF-DONES) facility based on and taking profit of the results obtained in the Engineering Validation and Engineering Design Activities (IFMIF/EVEDA) project, presently conducted in the framework of the EU-Japan Bilateral Agreement on the Broader Approach to Fusion. These activities and research and development work for the IFMIF-DONES plant are presently taking place in the framework of a work package of the EUROfusion Consortium, in direct collaboration with the Fusion for Energy organization. The main objective of these activities is to consolidate the design and underlying technology basis in order to be ready for the start of the IFMIF-DONES construction as early as possible. In this paper, an overview and the present status of the IFMIF-DONES engineering design is presented for a generic site, making emphasis on the recent design evolution from previous phases.
Motor imagery is a complex mental task that represents muscular movement without the execution of muscular action, involving cognitive processes of motor planning and sensorimotor proprioception of ...the body. Since the mental task has similar behavior to that of the motor execution process, it can be used to create rehabilitation routines for patients with some motor skill impairment. However, due to the nature of this mental task, its execution is complicated. Hence, the classification of these signals in scenarios such as brain–computer interface systems tends to have a poor performance. In this work, we study in depth different forms of data representation of motor imagery EEG signals for distinct CNN-based models as well as novel EEG data representations including spectrograms and multidimensional raw data. With the aid of transfer learning, we achieve results up to 93% accuracy, exceeding the current state of the art. However, although these results are strong, they entail the use of high computational resources to generate the samples, since they are based on spectrograms. Thus, we searched further for alternative forms of EEG representations, based on 1D, 2D, and 3D variations of the raw data, leading to promising results for motor imagery classification that still exceed the state of the art. Hence, in this work, we focus on exploring alternative methods to process and improve the classification of motor imagery features with few preprocessing techniques.
In this study, magnetic and power absorption properties of a series of iron oxide nanoparticles with average sizes 〈
d
〉 ranging from 3 to 23 nm were reported. The nanoparticles were prepared by ...thermal decomposition of Iron(III) acetylacetonate in organic media. From the careful characterization of the magnetic and physicochemical properties of these samples, the specific power absorption (SPA) values experimentally found were numerically reproduced, as well as their dependence with particle size, using a simple model of Brownian and Néel relaxation at room temperature. SPA experiments in ac magnetic fields (
H
0
= 13 kA/m and
f
= 250 kHz) indicated that the magnetic and rheological properties played a crucial role determining the heating efficiency at different conditions. A maximum SPA value of 344 W/g was obtained for a sample containing nanoparticles with 〈
d
〉 = 12 nm and dispersion
σ
= 0.25. The observed SPA dependence with particle diameter and their magnetic parameters indicated that, for the size range and experimental conditions of
f
and
H
studied in this study, both Néel and Brown relaxation mechanisms are important to the heat generation observed.
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