Olivine-rich troctolites (>70% olivine) reveal that extensive melt impregnation of pre-existing olivine-rich lithologies participate to the building of slow spread oceanic crust. To constrain their ...origin and their impact on the structure and geochemistry of oceanic crust, we realized a multi-scale petro-structural, geochemical, and numerical modeling study of olivine-rich troctolites drilled at IODP Hole U1309D (Atlantis Massif, Mid-Atlantic Ridge 30°N). Discrete intervals of olivine-rich troctolites display sharp to diffuse contacts with neighboring troctolites or gabbros. Their texture is characterized by plastically deformed (high temperature imprint), corroded coarse-grained to undeformed fine-grained olivine embayed in poikilitic clinopyroxene and plagioclase. Olivine crystallographic preferred orientations show weak 001 clusters. Olivine has variable major and minor element compositions, but similar fractionated REE (DyN/YbN = 0.04–0.11). We distinguished three types of olivine-rich troctolites based on microstructure, texture and mineral composition. Olivine-rich troctolites 1 and 2 display sharp contacts with adjacent lithologies. Type 1 has modal olivine <75%, occurring mainly as single rounded grains with primitive compositions (Mg# = 85–86), and associated with high Mg# clinopyroxene. Type 2 has higher olivine modes (>75%), dominantly forming aggregates, showing more evolved compositions (Mg# = 83–84) and associated with slightly lower Mg# clinopyroxene. These variations of olivine modes and compositions are in contrast to common trends of magmatic crystallization that predicts decreasing modal olivine with melt differentiation towards evolved compositions. Type 3 has diffuse contacts with gabbroic veins and modal olivine overlapping those of types 1 and 2. Chemical traverses along principal crystallographic axes of olivine are flat, suggesting local equilibrium between olivine and neighboring phases. Mineral modes and compositions, together with textures and microstructures, suggest that olivine-rich troctolites formed after melt-rock interactions in a reactive porous flow process. Their compositions are best modeled by percolation of primitive MORBs into Hole U1309D impregnated and compositionally heterogeneous harzburgites, triggering orthopyroxene dissolution, followed by olivine assimilation and concomitant crystallization of clinopyroxene and plagioclase. Modeling shows that Ni variations in olivine at constant Mg# are mantle inherited. Compositions of olivine-rich troctolite 1 are fitted assuming higher olivine assimilation (Ma = 0.06–0.13) in contrast to olivine-rich troctolites 2 and 3 (Ma = 0.01–0.02). Olivine-rich troctolite 3 was ‘buffered’ by crystallizing reacted melts, progressively more evolved as temperature decreased during a late stage process. We interpret olivine-rich troctolites from the Atlantis Massif as marking local assimilation of harzburgitic mantle into the gabbroic sequence during a period of enhanced magmatism at depth. Our study shows that the distribution and variable compositions of olivine-rich troctolites result from the incipient stages of this process when local spatial variations in mantle rock permeability, probably related to pyroxene distribution, controlled in turn melt transport and mantle-melt interactions.
•Multi-scale, petro-structural and geochemical study, and numerical modeling of olivine-rich troctolites from Atlantis Massif.•Clinopyroxene-olivine geochemical profiles suggest local melt-rock interactions and re-equilibration processes.•Modeling shows that olivine in reactive olivine-rich troctolites is mantle inherited.•Formation of reactive olivine-rich troctolites is controlled by mantle permeability.•This study provide the principle microstructural and petro-geochemical characteristics of reactive olivine-rich troctolites.
Recent studies investigate the replacive formation of hybrid troctolites from mantle peridotites after multiple stages of melt-rock reaction. However, these studies are not conducted in a ...field-controlled geological setting displaying the clear evolution from the protolith to the end-product of the reactions. The Mt. Maggiore peridotitic body exposes a clear evolution from spinel lherzolite to plagioclase-bearing lithotypes (plagioclase peridotites, olivine-rich troctolites and troctolites) during two continuous episodes of melt-rock interaction. In the spinel facies, the reactive percolation of a LREE-depleted melt leads to the dissolution of mantle pyroxenes and the growth of olivine crystals, forming replacive spinel dunites. The progressive evolution from spinel lherzolite to harzburgite to replacive dunite is accompanied by a change of olivine Crystallographic Preferred Orientation (CPO), from axial-100 in the lherzolite to axial-010 olivine CPO in the dunites, indicative of deformation in presence of melt. The initial percolating melt composition is consistent with single melt increments after 6% partial melting of a depleted mantle source. Reactive melt percolation leads to a progressive enrichment in the melt M-HREE absolute concentrations, while preserving its LREE depletion, consistent with the enriched analyzed HREE composition of olivine in the spinel dunite.
In the shallower plagioclase facies, the melts modified by reactive melt percolation impregnate the spinel-facies lithotypes, leading to the dissolution of olivine and crystallization of plagioclase and orthopyroxene in the peridotites. This impregnation stage is also observed in the spinel dunites, forming hybrid olivine-rich troctolites and troctolites. The dissolution-precipitation reactions forming hybrid troctolites cause a progressive textural evolution of the olivine matrix, with the disruption of deformed coarse grains into undeformed small rounded grains. This textural evolution is not accompanied by clear changes in the olivine CPO, indicating low instantaneous melt/rock ratios during the impregnation process. Olivine, plagioclase and clinopyroxene REE compositions analyzed in troctolite fit a process of impregnation with a progressive closure of the porosity (at decreasing melt mass), leading to the crystallization of trapped melt and REE enrichments during the last crystallization increments.
•Hybrid troctolites form during multi-stage melt-rock interaction history.•Structural/chemical features can be inherited from the mantle or dunitic protolith.•Inheritance depends on the melt/rock ratio involved in each melt-rock interaction.•The structure and composition of the olivine matrix represent the whole evolution during melt-rock interaction history.•Olivine trace elements are a powerful tool to investigate melt-rock interactions.
Abstract
Many recent studies have investigated the replacive formation of troctolites from mantle protoliths and the compositional evolution of the percolating melt during melt–rock interaction ...processes. However, strong structural and geochemical constraints for a replacive origin have not yet been established. The Erro–Tobbio impregnated mantle peridotites are primarily associated with a hectometre-size troctolitic body and crosscutting gabbroic dykes, providing a good field control on melt–rock interaction processes and subsequent magmatic intrusions. The troctolitic body exhibits high inner complexity, with a host troctolite (Troctolite A) crosscut by a second generation of troctolitic metre-size pseudo-tabular bodies (Troctolite B). The host Troctolite A is characterized by two different textural types of olivine, corroded deformed millimetre- to centimetre-size olivine and fine-grained rounded undeformed olivine, both embedded in interstitial to poikilitic plagioclase and clinopyroxene. Troctolite A shows melt–rock reaction microstructures indicative of replacive formation after percolation and impregnation of mantle dunites by a reactive melt. The evolution of the texture and crystallographic preferred orientation (CPO) of olivine are correlated and depend on the melt/rock ratio involved in the impregnation process. A low melt/rock ratio allows the preservation of the protolith structure, whereas a high melt/rock ratio leads to the disaggregation of the pre-existing matrix. The mineral compositions in Troctolite A define reactive trends, indicative of the buffering of the melt composition by assimilation of olivine during impregnation. The magmatic Troctolite B bodies are intruded within the pre-existing Troctolite A and are characterized by extreme textural variations of olivine, from decimetre-size dendritic to fine-grained euhedral crystals embedded in poikilitic plagioclase. This textural variability is the result of olivine assimilation during melt–rock reaction and the correlated increase in the degree of undercooling of the percolating melt. In the late gabbroic intrusions, mineral compositions are consistent with the fractional crystallization of melts modified after the reactive crystallization of Troctolites A and B. The Erro–Tobbio troctolitic body has a multi-stage origin, marked by the transition from reactive to fractional crystallization and diffuse to focused melt percolation and intrusion, related to progressive exhumation. During the formation of the troctolitic body, the melt composition was modified and controlled by assimilation and concomitant crystallization reactions occurring at low melt supply. Similar processes have been described in ultraslow-spreading oceanic settings characterized by scarce magmatic activity.
The exposure of gabbroic sequences at Oceanic Core Complexes (OCC) along ultraslow- to slow-spreading ridges permits the study of the processes forming the lower oceanic crust. On top of the Atlantis ...Bank OCC along the ultraslow-spreading Southwest Indian Ridge, IODP Expedition 360 drilled Hole U1473A, mainly composed of primitive olivine gabbros interspersed with more evolved Ti-Fe oxide-bearing gabbros and minor felsic veins. These rocks record a complex history of protracted magmatism during continuous uplift and deformation of the gabbroic sequence. Extensive crystal-plastic deformation is dominantly recorded in the shallower sections of the drillhole, whereas the deeper sections better preserve primary magmatic features. We focus on microstructures, including intra-crystalline deformation of rock-forming minerals, and plagioclase crystallographic preferred orientations of olivine gabbros lacking evidence for exhumation-related crystal plastic deformation, to gain insights on the relationship between compaction, melt migration and melt accumulation during the early magmatic history of this section of lower oceanic crust. Olivine gabbros are characterized by ubiquitous grain-size variations, from coarse- to fine-grained intervals. Minerals in coarse-grained intervals show intra-crystalline deformation, while fine-grained crystals lack internal strain. Bent coarse-grained plagioclase associated with weak magmatic foliation and lack of lineation suggest that the coarse-grained intervals were deformed under weak compaction. On the other hand, crystallographic preferred orientations of undeformed fine-grained plagioclase show weak lineations, likely indicative of non-coaxial strain. We thereby infer that the coarse-grained intervals underwent ongoing weak compaction from the stage of olivine + plagioclase ± clinopyroxene crystal mush to the melt-poor stage, and that this process likely aided melt extraction and accumulation in discrete melt-rich zones where crystals orientated in the direction of magmatic flow. Crystallization of melts in the melt-rich zones ultimately formed the fine-grained intervals at different depths in Hole U1473A. This indicates that processes of compaction can lead to local chemical and grain-size heterogeneities in a lower crustal section, while had a minor role in the melt movement at larger scales (e.g., the whole crystal mush) within the oceanic crust.
•We document first microstructural constraints of compaction in slow-spread gabbros.•Deformed coarse-grained olivine gabbros developed weak foliation during compaction.•Undeformed fine-grained intervals developed lineation during melt accumulation.•Compaction led to the local but ubiquitous chemical and grain-size heterogeneities.•Large scale melt migration at the Atlantis Bank was mostly driven by melt buoyancy.
The uppermost mantle in back arc regions is the site of complex interactions between partial melting, melt percolation, and fluid migration. To constrain these interactions and evaluate their ...consequences on geochemical cycles, we carried out an in situ trace element and water study of a suite of spinel peridotite xenoliths from two regions of the Japan back arc system, Ichinomegata (NE Japan) and Oki-Dogo (SW Japan), using LA-ICPMS and FTIR spectrometry, respectively. This study provides the first full dataset of trace element and hydrogen compositions in peridotites including analyses of all their main constitutive silicate minerals: olivine, orthopyroxene and clinopyroxene. The Ichinomegata peridotites sample a LREE-depleted refractory mantle (Mg# olivine=0.90; Cr# spinel=0.07–0.23; Yb clinopyroxene=7.8–13.3×C1-chondrite, and La/Yb clinopyroxene=0.003–0.086×C1-chondrite), characterized by Th-U positive anomalies and constant values of Nb/Ta. The composition of the studied Ichinomegata samples is consistent with that of an oceanic mantle lithosphere affected by cryptic metasomatic interactions with hydrous/aqueous fluids (crypto-hydrous metasomatism). In contrast, the Oki-Dogo peridotites have low Mg# olivine (0.86–0.93) and a broad range of compositions with clinopyroxene showing “spoon-shaped” to flat, and LREE-enriched patterns. They are also characterized by their homogeneous compositions in the most incompatible LILE (e.g., Rb clinopyroxene=0.01–0.05×primitive mantle) and HFSE (e.g., Nb clinopyroxene=0.01–2.16×primitive mantle). This characteristic is interpreted as resulting from various degrees of melting and extensive melt-rock interactions. FTIR spectroscopy shows that olivine in both Ichinomegata and Oki-Dogo samples has low water contents ranging from 2 to 7ppm wt. H2O. In contrast, the water contents of pyroxenes from Ichinomegata peridotites (113–271ppm wt. H2O for orthopyroxene, and 292–347ppm wt. H2O for clinopyroxene) are significantly higher than in Oki-Dogo peridotites (9–35ppm wt. H2O for orthopyroxene, and 15–98ppm wt. H2O for clinopyroxene). This indicates a relationship between melt-rock interaction and water concentrations in pyroxenes. Our study suggests that the water content of the Japan mantle wedge is controlled by the late melt/fluid/rock interactions evidenced by trace element geochemistry: a mechanism triggered by magma-rock interactions may have acted as an efficient dehydrating process in the Oki-Dogo region while the Ichinomegata mantle water content is controlled by slab-derived crypto-hydrous metasomatism.
The transition between the small melt lens observed on top of fast spreading ridge magma chambers and the overlying sheeted dike complex marks the interface between magma and the hydrothermal ...convective system. It is therefore critical to our understanding of fast spreading ridge accretion processes. We present maps of two areas of the Oman ophiolite where this transition zone is observed as continuous outcrops. Our observations, which include the base of the sheeted dike being crosscut by gabbros, are consistent with episodic dike injections in a steady state model but also suggest that the root of these dikes is commonly erased by vertical movements of the top of the melt lens. Dike assimilation is a possible mechanism for incorporating hydrated phases, which result from hydrothermal alteration, to the melt lens during upward migrations of its upper boundary. Upward migrations are also responsible for a granoblastic overprint of the root of the dikes that is also observed in the stoped diabase xenoliths. This granoblastic overprint attests to reheating of previously hydrothermally altered lithologies which can even trigger hydrous partial melting due to the lowering of the solidus of mafic lithologies by the presence of a water activity. Clinopyroxenes present in these granoblastic lithologies are typically low in Ti and Al content, thus strongly contrasting with corresponding magmatic clinopyroxene. This may attest to the recrystallization of clinopyroxenes after amphiboles under the peculiar conditions present at the root zone of the sheeted dike complex. Downward migrations of the top of the melt lens result in the crystallization of the isotropic gabbros at its roof, which represent the partly fossilized melt lens. Melt lens fossilization eventually occurs when magma supply is stopped or at the melt lens margins where the thermal conditions become cooler. Melt lens migration, recrystallization of hydrothermally altered sheeted dikes during reheating stages, and assimilation processes observed in the Oman ophiolite are consistent with the observations made in IODP Hole 1256D. We propose a general dynamic model in which the melt lens at fast spreading ridges undergoes upward and downward movements as a result of either eruption/replenishment stages or variations in the hydrothermal/magmatic fluxes.
The results of detailed textural, mineral chemical, and petrophysical studies shed new light on the poorly constrained fluid‐rock reaction pathways during retrograde serpentinization at mid‐ocean ...ridges. Uniformly depleted harzburgites and dunites from the Mid‐Atlantic Ridge at 15°N show variable extents of static serpentinization. They reveal a simple sequence of reactions: serpentinization of olivine and development of a typical mesh texture with serpentine‐brucite mesh rims, followed by replacement of olivine mesh centers by serpentine and brucite. The serpentine mesh rims on relic olivine are devoid of magnetite. Conversely, domains in the rock that are completely serpentinized show abundant magnetite. We propose that low‐fluid‐flux serpentinization of olivine to serpentine and ferroan brucite is followed by later stages of serpentinization under more open‐system conditions and formation of magnetite by the breakdown of ferroan brucite. Modeling of this sequence of reactions can account for covariations in magnetic susceptibility and grain density of the rocks.
Sampling the upper mantle via scientific ocean drilling remains elusive. Although the technologies required for drilling to the Moho still don’t exist, we have made significant progress over the last ...five decades in piecing together the complex geology of the oceanic crust. Here, we highlight key findings that reveal the architecture of oceanic crust and the thermal, physical, and chemical processes that are responsible for the growth and structure of the oceanic lithosphere. These advances result from enduring efforts to drill and collect downhole geophysical logs of oceanic crust near both slow and fast spreading ridges.
IODP Hole U1309D (Atlantis Massif, Mid-Atlantic Ridge 30°N) is the second deepest hole drilled into slow spread gabbroic lithosphere. It comprises 5.4% of olivine-rich troctolites (~
>
70% olivine), ...possibly the most primitive gabbroic rocks ever drilled at mid-ocean ridges. We present the result of an
in situ trace element study carried out on a series of olivine-rich troctolites, and neighbouring troctolites and gabbros, from olivine-rich intervals in Hole U1309D. Olivine-rich troctolites display poikilitic textures; coarse-grained subhedral to medium-grained rounded olivine crystals are included into large undeformed clinopyroxene and plagioclase poikiloblasts. In contrast, gabbros and troctolites have irregularly seriate textures, with highly variable grain sizes, and locally poikilitic clinopyroxene oikocrysts in troctolites. Clinopyroxene is high Mg# augite (Mg# 87 in olivine-rich troctolites to 82 in gabbros), and plagioclase has anorthite contents ranging from 77 in olivine-rich troctolites to 68 in gabbros. Olivine has high forsterite contents (82–88 in olivine-rich troctolites, to 78–83 in gabbros) and is in Mg–Fe equilibrium with clinopyroxene. Clinopyroxene cores and plagioclase are depleted in trace elements (e.g., Yb
cpx ~
5–11
×
Chondrite), they are in equilibrium with the same MORB-type melt in all studied rock-types. These compositions are not consistent with the progressively more trace element enriched (evolved) compositions expected from olivine rich primitive products to gabbros in a MORB cumulate sequence. They indicate that clinopyroxene and plagioclase crystallized concurrently, after melts having the same trace element composition, consistent with crystallization in an open system with a buffered magma composition. The slight trace element enrichments and lower Cr contents observed in clinopyroxene rims and interstitial grains results from crystallization of late-stage differentiated melts, probably indicating the closure of the magmatic system. In contrast to clinopyroxene and plagioclase, olivine is not in equilibrium with MORB, but with a highly fractionated depleted melt, similar to that in equilibrium with refractory oceanic peridotites, thus possibly indicating a mantle origin. In addition, textural relationships suggest that olivine was in part assimilated by the basaltic melts after which clinopyroxene and plagioclase crystallized (impregnation). These observations suggest a complex crystallization history in an open system involving impregnation by MORB-type melt(s) of an olivine-rich rock or mush. The documented magmatic processes suggest that olivine-rich troctolites were formed in a zone with large magmatic transfer and accumulation, similar to the mantle-crust transition zone documented in ophiolites and at fast spreading ridges.
Rainbow is a dome‐shaped massif at the 36°14′N nontransform offset along the Mid‐Atlantic Ridge. It hosts three ultramafic‐hosted hydrothermal sites: Rainbow is active and high temperature; Clamstone ...and Ghost City are fossil and low temperature. The MoMARDREAM cruises (2007, 2008) presented here provided extensive rock sampling throughout the massif that constrains the geological setting of hydrothermal activity. The lithology is heterogeneous with abundant serpentinites surrounding gabbros, troctolites, chromitites, plagiogranites, and basalts. We propose that a W dipping detachment fault, now inactive, uplifted the massif and exhumed these deep‐seated rocks. Present‐day deformation is accommodated by SSW‐NNE faults and fissures, consistent with oblique teleseismic focal mechanisms and stress rotation across the discontinuity. Faults localize fluid flow and control the location of fossil and active hydrothermal fields that appear to be ephemeral and lacking in spatiotemporal progression. Markers of high‐temperature hydrothermal activity (∼350°C) are restricted to some samples from the active field while a more diffuse, lower temperature hydrothermal activity (<220°C) is inferred at various locations through anomalously high As, Sb, and Pb contents, attributed to element incorporation in serpentines or microscale‐sulfide precipitation. Petrographic and geochemical analyses show that the dominant basement alteration is pervasive peridotite serpentinization at ∼160–260°C, attributed to fluids chemically similar to those venting at Rainbow, and controlled by concomitant alteration of mafic‐ultramafic units at depth. Rainbow provides a model for fluid circulation, possibly applicable to hydrothermalism at oceanic detachments elsewhere, where both low‐temperature serpentinization and magmatic‐driven high‐temperature outflow develop contemporaneously, channeled by faults in the footwall and not along the detachment fault.
Key Points
Rainbow massif uplifted by now inactive west dipping detachment
Oblique faults dissect the massif and localize hydrothermalism for last 100 kyr
Petrography and geochemistry unravel high and low‐T fluid‐rock reaction history
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