•CLH sampling is an effective method for DSM, accounting for environmental covariates.•A study on Scotland's Finzean Estate examined the optimal sample size for CLH sampling.•40–50 CLH samples were ...found to be optimal for the Finzean Estate.•This provides both a reduction in sampling locations and precise location identification for optimal DSM.
Soil properties are important because they determine the soil’s suitability for different types of plant growth, ecosystems and biota functioning. Soil properties influence nutrient cycling, carbon sequestration and soil management. Digital Soil Mapping (DSM) is a procedure to map soil properties. Soil sampling for DSM is a foundational step in building prediction accuracy and essential for incorporating variability in terms of environmental covariates (ancillary variables). Conditioned Latin Hypercube (CLH) sampling is a method for generating a sample of points from a multivariate distribution that has been conditioned on one or more covariates. It is an extension of Latin Hypercube sampling, which is a popular technique for generating samples from a multivariate distribution in a way that ensures that each dimension is sampled uniformly. CLH sampling carries the benefit of selecting sampling locations covering the feature space and forming a Hypercube of the original sample. However, determining the optimum sample size is crucial in soil survey exercises constrained by budget and time limits. For this purpose, a study was carried out on Scotland's Finzean Estate (44.8 km2) location. A dataset of 21 independent features (16 continuous and five categorical) and 17,932 sampling locations was created using Digital Elevation Model (DEM) derivatives, soil classes map, land cover map, the peat depth map and parent material map to further generate sub-samples and compare the generated sub-samples with the original population. Two hundred CLH sampling datasets were extracted from the original population (17932 data points) with different sizes (5, 10, 15, 20, …, 100) and each size was given 10 repetitions e.g. (5_1, 5_2, …, 5_10). The sample datasets were analysed by comparing the mean, standard deviation, boxplot and estimates of the probability density function (pdf) for all the 16 continuous independent features. All the mentioned comparisons suggest that the impact of increasing sample size on the distribution of covariates can be observed up to a certain point, beyond which further increases in sample size may not yield noticeable differences. Bhattacharyya distance, a statistical measurement that quantifies the similarity between two probability distributions, was calculated between every quantitative and qualitative element of respective sampling size and for the original population. In contrast, as the CLH sample dataset size increased, the Bhattacharyya distance value decreased and became constant.. The optimum number of samples based on the study was determined for the spatial extent of the Finzean Estate in Scotland and a range of 25–50 CLH samples was suggested based on the study. This work, therefore, achieved both reductions in sampling location numbers compared to classical approaches and identification of the precise location of these sample location to achieve optimal DSM.
Microbial‐induced calcite precipitation (MICP) is regarded as environmentally friendly, partly due to the storage of carbon as carbonates. Although CO2 emissions during MICP have been reported, ...quantification of its environmental impact regarding total greenhouse gas fluxes has not yet been thoroughly investigated. In particular, N2O fluxes could occur in addition to CO2 since MICP involves the microbially mediated nitrogen cycle. This study investigated the greenhouse gas fluxes during biostimulation of MICP in quartz sand in incubation experiments. Soil samples were treated with MICP cementation solution containing calcium concentrations of 0, 20, 100 and 200 mM at a fixed urea concentration of 100 mM to offer a range of carbonation potential and/or mitigation of CO2 emissions. Greenhouse gas (CO2, CH4 and N2O) measurements were determined by gas chromatography during incubations. Soil total inorganic carbon and the isotopic composition of precipitated and emitted CO2 were determined by isotope ratio mass spectrometry. CO2 emissions (0.52 to 4.08 μg of CO2–C h−1 g−1 soil) resulted from MICP, while N2O and CH4 fluxes were not detected. Increasing Ca2+ with respect to urea resulted in lower CO2 emissions, lower solution pH, similar carbonate precipitation and urea hydrolysis inhibition. The highest urea‐to‐calcium ratio (1:0.2) emitted roughly two times the amount of CO2 (112 μg of CO2–C g−1 soil) compared to the 1:1 and 1:2 ratios (47 to 58 μg of CO2–C g−1 soil) and five to six times more than samples that did not receive Ca2+ (1:0) (~18 μg of CO2–C g−1 soil). Precipitated CaCO3–C was tenfold higher than cumulative emitted CO2–C, and isotopic analysis indicated both emitted and precipitated carbon were of urea origin. Both emitted and precipitated carbon accounted for a very low percentage of total carbon applied in the system (<0.35 and <4.5%, respectively), presumably due to limited urea hydrolysis which was negatively affected by increasing the Ca2+ concentration.
Simplified scheme of carbon and nitrogen cycles during Microbial‐Induced Calcite Precipitation.
Microbial Induced Calcite Precipitation (MICP) via biostimulation of urea hydrolysis is a biogeochemical process in which soil indigenous ureolytic microorganisms catalyse the decomposition of urea ...into ammonium and carbonate ions which, in the presence of calcium, precipitate as calcium carbonate minerals. The environmental conditions created by urine in soil resemble those induced by MICP via urea hydrolysis. Thus, this study assesses the suitability of a waste product, cow urine, as a source of nutrients for MICP. Urea stability in fresh and sterilised urine were monitored for a month to cover the length of a potential MICP intervention. An experimental soil column set up was used to compare the soil response to the repeated application of fresh and sterilised cow urine, within pH of 7 and 9, and the chemical-based solution. Urea hydrolysis and the carbonate content in solution were monitored to assess the suitability of the proposed alternative. In addition, the nitrification process was monitored. Key findings indicated i) urea concentration and stability in fresh and sterilised cow urine are suitable for MICP application; ii) the soil response to treatments of cow urine within pH of 7 and 9 are similar to the chemical-based solution; and iii) increasing solution pH results in a faster activation of ureolytic microorganisms and higher carbonate content in solution. These results demonstrate that cow urine is a suitable substitute of the chemical-based MICP application.
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•Cow urine is a urea-containing nutrient source for soil ureolytic microorganisms.•Urea in fresh and pasteurised cow urine is stable at room temperature at least three to four weeks.•Cow urine application to soil produced between 2 and 5.5 mM of carbonate in soil solution.•Cow urine within pH 7 to 9 is a suitable substitute to the chemical-based solution for MICP applications.
The use of crushed basic igneous rock and crushed concrete for enhanced rock weathering and to facilitate pedogenic carbonate precipitation provides a promising method of carbon sequestration. ...However, many of the controls on precipitation and subsequent effects on soil properties remain poorly understood. In this study, engineered soil plots, with different ratios of concrete or dolerite combined with sand, have been used to investigate relationships between sequestered inorganic carbon and geotechnical properties, over a two-year period. Cone penetration tests with porewater pressure measurements (CPTu) were conducted to determine changes in tip resistance and pore pressure. C and O isotope analysis was carried out to confirm the pedogenic origin of carbonate minerals. TIC analysis shows greater precipitation of pedogenic carbonate in plots containing concrete than those with dolerite, with the highest sequestration values of plots containing each material being equivalent to 33.7 t C ha−1 yr−1 and 17.5 t C ha−1 yr−1, respectively, calculated from extrapolation of results derived from the TIC analysis. TIC content showed reduction or remained unchanged for the top 0.1 m of soil; at a depth of 0.2 m however, for dolerite plots, a pattern of seasonal accumulation and loss of TIC emerged. CPTu tip resistance measurements showed that the presence of carbonates had no observable effect on penetration resistance, and in the case of porewater pressure measurements, carbonate precipitation does not change the permeability of the substrate, and so does not affect drainage. The results of this study indicate that both the addition of dolerite and concrete serve to enhance CO2 removal in soils, that soil temperature appears to be a control on TIC precipitation, and that mineral carbonation in constructed soils does not lead to reduced drainage or an increased risk of flooding.
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•This study presents results from the first large scale inorganic carbon capture experiment in the world.•Our research shows precipitation of 33.7 and 17.5 t C ha−1 yr−1 for plots containing concrete and dolerite, respectively.•At a depth of 0.2 m for dolerite plots, a pattern of seasonal accumulation and loss of carbonate is observed.•Geotechnical measurements shows that carbonation has no observable impact on penetration resistance.•Soil pore water analysis shows carbonation does not change permeability of the substrate, and hence does not affect drainage.
Management of urban brownfield land can contribute to significant removal of atmospheric CO2 through the development of soil carbonate minerals. However, the potential magnitude and stability of this ...carbon sink is poorly quantified as previous studies address a limited range of conditions and short durations. Furthermore, the suitability of carbonate-sequestering soils for construction has not been investigated. To address these issues we measured total inorganic carbon, permeability and ground strength in the top 20 cm of soil at 20 brownfield sites in northern England, between 2015 and 2017. Across all sites accumulation occurred at a rate of 1–16 t C ha−1 yr−1, as calcite (CaCO3), corresponding to removal of approximately 4–59 t CO2 ha−1 yr−1, with the highest rate in the first 15 years after demolition. C and O stable isotope analysis of calcite confirms the atmospheric origin of the measured inorganic carbon. Statistical modelling found that pH and the content of fine materials (combined silt and clay content) were the best predictors of the total inorganic carbon content of the samples. Measurement of permeability shows that sites with carbonated soils possess a similar risk of run-off or flooding to sandy soils. Soil strength, measured as in-situ bearing capacity, increased with carbonation. These results demonstrate that the management of urban brownfield land to retain fine material derived from concrete crushing on site following demolition will promote calcite precipitation in soils, and so offers an additional CO2 removal mechanism, with no detrimental effect on drainage and possible improvements in strength. Given the large area of brownfield land that is available for development, the contribution of this process to CO2 removal by urban soils needs to be recognised in CO2 mitigation policies.
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•Soil carbonate in urban brownfield lands contribute to significant removal of CO2.•Study of 20 brownfield lands show removal rate of 4–59 t CO2 ha−1 yr−1.•CO2 sequestration rate is highest in the first 15 years after demolition.•Sites that sequestered CO2 possess a similar risk of flooding to sandy soils.•Substrate strength, measured in-situ, increased with carbonation
Water Treatment Residuals (WTRs) are a by-product of the addition of chemical coagulants to water during the water treatment process and are a mixture of water and organic and inorganic matter that ...coagulates during the treatment process. WTRs often contain metals such as iron, aluminium, and manganese that have been oxidised as part of the process or are constituents of the coagulation chemicals used. The metals within WTRs are of interest with regard to applying these sludges to agricultural land. WTRs can also contain beneficial organic matter and nutrients (primarily nitrogen). The nature of the benefits delivered is largely dependent on the quality of the raw water and these beneficial components are generally found in much smaller quantities in WTRs than are found in sewage sludge produced from wastewater. However, WTRs can still be used to enhance the physical properties of soils. As urban populations increase in size, it is anticipated that the tonnage of WTRs will increase significantly in the future. At present, the majority of WTRs are disposed of in landfills; however, landfill charges are increasing significantly, making disposal of an increasing tonnage of WTRs financially unviable. In terms of a circular economy, the procedure of reusing WTRs for alternative applications satisfies the Scottish Government’s goals in terms of waste prevention and reducing the amount of material being sent to landfill as set out in the Proposals for Legislation in 2019. Given the potential benefits in terms of cost savings and compliance with government legislation, and the complexities of understanding where and when WTRs can be used in land applications, we developed a Decision Support Tool (DST) that uses data obtained from an extensive review of approaches in other countries to assist in decision making. We also conducted a pre-application analysis and provided guidance on when and where WTRs can be used in land applications and when they are not suitable, presented in a simplified format that requires few inputs from the user in order to simplify the process and removes the requirement for a specialist operator during pre-application analyses.
Microbial-Induced Calcite Precipitation (MICP) stimulates soil microbiota to induce a cementation of the soil matrix. Urea, calcium and simple carbon nutrients are supplied to produce carbonates via ...urea hydrolysis and induce the precipitation of the mineral calcite. Calcium chloride (CaCl
2
) is typically used as a source for calcium, but basic silicate rocks and other materials have been investigated as alternatives. Weathering of calcium-rich silicate rocks (e.g., basalt and dolerite) releases calcium, magnesium and iron; this process is associated with sequestration of atmospheric CO
2
and formation of pedogenic carbonates. We investigated atmospheric carbon fluxes of a MICP treated sandy soil using CaCl
2
and dolerite fines applied on the soil surface as sources for calcium. Soil-atmosphere carbon fluxes were monitored over 2 months and determined with an infrared gas analyser connected to a soil chamber. Soil inorganic carbon content and isotopic composition were determined with isotope-ratio mass spectrometry. In addition, soil-atmosphere CO
2
fluxes during chemical weathering of dolerite fines were investigated in incubation experiments with gas chromatography. Larger CO
2
emissions resulted from the application of dolerite fines (116 g CO
2
-C m
–2
) compared to CaCl
2
(79 g CO
2
-C m
–2
) but larger inorganic carbon precipitation also occurred (172.8 and 76.9 g C m
–2
, respectively). Normalising to the emitted carbon to precipitated carbon, the environmental carbon cost was reduced with dolerite fines (0.67) compared to the traditional MICP treatment (1.01). The carbon isotopic signature indicated pedogenic carbonates (δ
13
C
av
= −8.2 ± 5.0‰) formed when dolerite was applied and carbon originating from urea (δ
13
C
av
= −46.4 ± 1.0‰) precipitated when CaCl
2
was used. Dolerite fines had a large but short-lived (<2 d) carbon sequestration potential, and results indicated peak CO
2
emissions during MICP could be balanced optimising the application of dolerite fines.
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